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In this article we highlight some of the recent developments in the aqueous-phase hydrogenation of alkenes and arenes. The traditional types of water-soluble catalysts applied in aqueous media are outlined together with recent trends towards the developmen ...

Herein we present a detailed study of the hydrogen adsorption properties of Cu‐BTTri, a robust crystalline metal–organic framework containing open metal‐coordination sites. Diffraction techniques, carried out on the activated framework, reveal a structure ...

A large series of ionic liqs. (ILs) based on the weakly coordinating alkoxyaluminate [Al(hfip)4]- (hfip: hexafluoroisopropoxy) with classical as well as functionalized cations were prepd., and their principal phys. properties detd. M.ps. are between 0 ([C4 ...

Metal-organic frameworks are of interest in a number of host-guest applications. However, their weak coordination bonding often leads to instability in aqueous environments, particularly at extreme pH, and hence, is a challenging topic in the field. In thi ...

Transition-metal phosphides have received tremendous attention during the past few years because they are earth-abundant, cost-effective, and show outstanding catalytic performance in several electrochemically driven conversions including hydrogen evolutio ...

Owing to the almost boundless structural tunability, MOF and MOF‐derived catalysts have recently exhibited structures of higher complexity, and hence, have demonstrated activity in a wide array of organic transformations. These reactions have a broad range ...

MOF-derived Co3S4/CN hollow nanoboxes (CN=nitrogen-doped carbon) was used to catalyze the chemoselective reduction of nitroarenes to anilines under mild reaction conditions with H-2 as the reducing agent. The catalyst provides high conversion efficiencies ...

The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium c ...

Safak Bulut

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Aqueous-phase hydrogenation of alkenes and arenes: The growing role of nano scale catalysts

An In-Situ Neutron Diffraction and DFT Study of Hydrogen Adsorption in a Sodalite-Type Metal-Organic Framework, Cu-BTTri

Synthesis of Room-Temperature Ionic Liquids with the Weakly Coordinating [Al(ORF)4]- Anion (RF=C(H)(CF3)2) and the Determination of Their Principal Physical Properties

A new post-synthetic polymerization strategy makes metal-organic frameworks more stable

MOF-Derived Cobalt Phosphide/Carbon Nanocubes for Selective Hydrogenation of Nitroarenes to Anilines

Recent Advances of MOFs and MOF‐Derived Materials in Thermally Driven Organic Transformations

Metal-Organic-Framework-Derived Co3S4 Hollow Nanoboxes for the Selective Reduction of Nitroarenes

Selective CO2 adsorption by a new metal-organic framework: synergy between open metal sites and a charged imidazolinium backbone

Thiazolium carbene catalysts for the fixation of CO2 onto amines