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Ivica Zivkovic

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Publications associées (78)

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Charge multipole correlations and order in Cs2TaCl6

Henrik Moodysson Rønnow, Ivica Zivkovic, Jian Rui Soh, Jana Pásztorová

We examine the role of charge, structural, and spin degrees of freedom in the previously poorly understood phase transition in the 5d1 transition-metal double perovskite Cs2TaCl6 using a combination of computational and experimental techniques. Our heat ca ...

AMER PHYSICAL SOC2023

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Megan Renee Keener, Dieuwertje Katelijn Modder, Keerthi Shivaraam Rangaraj Ananthakumar

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Wiley-VCH Verlag GmbH2023

Single-chip electron spin resonance detectors operating at 50 GHz, 92 GHz, and 146 GHz

Jürgen Brugger, Henrik Moodysson Rønnow, Giovanni Boero, Ivica Zivkovic, Jens Anders, Alessandro Valentino Matheoud, Gabriele Gualco

We report on the design and characterization of single-chip electron spin resonance (ESR) detectors operating at 50 GHz, 92 GHz, and 146 GHz. The core of the single-chip ESR detectors is an integrated LC-oscillator, formed by a single turn aluminum planar ...

Academic Press Inc - Elsevier Science2017

Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Lucile Sylvie Danielle Chatelain, Luciano Barluzzi

Uranium nitride complexes are of high interest because of their ability to effect dinitrogen reduction and functionalization and to promote magnetic communication, but studies of their properties and reactivity remain rare. Here we have prepared in 73% yie ...

2019

Dissipation processes in the insulating skyrmion compound Cu2OSeO3

Helmuth Berger, Ivica Zivkovic

We present a detailed study of the phase diagram surrounding the skyrmion lattice (SkL) phase of Cu2OSe2O3 using high-precision magnetic ac susceptibility measurements. An extensive investigation of transition dynamics around the SkL phase using the imagin ...

Amer Physical Soc2014

Quantification of the local magnetized nanotube domains accelerating the photocatalytic removal of the emerging pollutant tetracycline

Henrik Moodysson Rønnow, Juan Kiwi, Sami Rtimi, Ivica Zivkovic

( )Evidence is presented for the enhanced photodegradation of tetracycline (TC) by AgxO/FeOx/ZnO nanotubes (NTs) compared to AgxO/ZnO nanotubes under low-intensity solar light irradiation. A higher amount of the local magnetic domains with random orientati ...

ELSEVIER SCIENCE BV2019

A trinuclear metallasilsesquioxane of uranium(III)

Rosario Scopelliti, Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Nadir Jori, Maxime Christian Gérard Tricoire

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS) ...

Royal Society of Chemistry2024

Assembly of High-Spin [Fe-3] Clusters by Ligand-Based Multielectron Reduction

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Davide Toniolo

The hexanuclear [Na12Fe6(tris-cyclo-salophen)(2)(THF)(14)], 1-THF, and the trinuclear [Na6Fe3(tris-cyclo-salophen)(py)(9)], 1-py, Fe(II) clusters can be easily assembled in one step from the ligand-based reduction of the [FeII(salophen)(THF)] complex. Thes ...

2020

Possibility of an unconventional spin state of Ir4+ in Ba21Ir9O43 single crystal

László Forró, Henrik Moodysson Rønnow, Oleg Yazyev, Arnaud Magrez, Bálint Náfrádi, Ivica Zivkovic, Alla Arakcheeva, Lin Yang, Andrea Pisoni, Sergiy Katrych, Jacim Jacimovic, Noore Elahi Shaik

We report the synthesis of single crystals of a novel layered iridate Ba21Ir9O43 and present the crystallographic, transport, and magnetic properties of this material. The compound has a hexagonal structure with two iridium oxide layers stacked along the c ...

Amer Physical Soc2016

Glassy dynamics in the low-temperature inhomogeneous ferromagnetic phase of the quantum spin ice Yb2Sn2O7

Ivica Zivkovic, Julian Piatek

Here we present a detailed muon spin relaxation (mu SR), neutron diffraction, and ac-susceptibility study of Yb2Sn2O7 that shows that despite the onset of ferromagnetic long-range order at T-c approximate to 0.140 K, the low-temperature phase of this mater ...

Amer Physical Soc2014

Structure, heat capacity and Raman spectra of Ba2MgWO6 single crystals grown in BaCl2-MgCl2 flux

Henrik Moodysson Rønnow, Ivica Zivkovic, Richard Gaal, Wen Hua Bi, Jana Pásztorová

We present a new method of Ba2MgWO6 single crystal synthesis that allows to grow larger crystals using a BaCl2 and MgCl2 flux. Difficulties to grow single crystals of a size suitable for macroscopic material property measurements caused the majority of cha ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2023

Synthesis of murunskite single crystals: A bridge between cuprates and pnictides

László Forró, Henrik Moodysson Rønnow, Ivica Zivkovic, Ana Akrap, Edoardo Martino, Davor Tolj, Trpimir Ivsic, Konstantin Semeniuk

Numerous contemporary investigations in condensed matter physics are devoted to high temperature (high-T-c) cuprate superconductors. Despite its unique effulgence among research subjects, the enigma of the high-T-c mechanism still persists. One way to adva ...

ELSEVIER2021

Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Luciano Barluzzi, Fang-Che Hsueh

Single-atom (group 15 and group 16 anions) bridged dimetallic complexes of low oxidation state uranium provide a convenient route to implement multielectron transfer and promote magnetic communication in uranium chemistry, but remain extremely rare. Here w ...

ROYAL SOC CHEMISTRY2024

Cavity-magnon-polariton spectroscopy of strongly hybridized electro-nuclear spin excitations in LiHoF4

Henrik Moodysson Rønnow, Ivica Zivkovic, Richard Gaal, Peter Babkevich

We first present a formalism that incorporates the input-output formalism and the linear response theory to employ cavity-magnon-polariton coupling as a spectroscopic tool for investigating strongly hybridized electro-nuclear spin excitations. A microscopi ...

Nature Research2024

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Andrzej Sienkiewicz, Dieuwertje Katelijn Modder, Mikhail Batov

Radical-bridged diuranium complexes are desirable for their potential high exchange coupling and single molecule magnet (SMM) behavior, but remain rare. Here we report for the first time radical-bridged diuranium(IV) and diuranium(III) complexes. Reaction ...

ROYAL SOC CHEMISTRY2022

Phase diagram with an enhanced spin-glass region of the mixed Ising–XY magnet LiHoxEr1-xF4

Henrik Moodysson Rønnow, Ivica Zivkovic, Julian Piatek, Bastien Dalla Piazza, Neda Nikseresht Ghanepour, Nikolay Tsyrulin

We present the experimental phase diagram of LiHoxEr1-xF4, a dilution series of dipolar-coupled model magnets. The phase diagram was determined using a combination of ac susceptibility and neutron scattering. Three unique phases in addition to the Ising fe ...

Amer Physical Soc2013

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Luciano Barluzzi, Nadir Jori

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to nitrides (N3-), but the mechanism remains ambiguous due to the lack of isolated intermediates. Herein, we report the reduction of the complex [K-2{[U-V(OSi((OBu)-Bu ...

2021

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Andrzej Sienkiewicz, Aurélien René Willauer

Trinuclear molecular complexes of europium (II)and ytterbium(II) [Ln3{(Ph2SiO)2O}3(THF)6],1-Ln3L3(Ln = Euand Yb), supported by the dianionic tetraphenyl disiloxanediolateligand, were synthesized via protonolysis of the [Ln{N-(SiMe3)2}2(THF)2] complexes. In ...

2022

FeOx magnetization enhancing E-coli inactivation by orders of magnitude on Ag-TiO2 nanotubes under sunlight

César Pulgarin, Juan Kiwi, Arnaud Magrez, Sami Rtimi, Ivica Zivkovic, Stefanos Giannakis

Drastic bacterial enhancement was observed when the Ag(3%)-TiO2 nanotubes were modified with FeOx (3%) magnetic oxide. On bare TiO2- nanotubes a reduction of 0.21og(10)CFU was observed within one hour under simulated low intensity solar light. Under simila ...

Elsevier2017

Singlet state formation and its impact on the magnetic structure in the tetramer system SeCuO3

Helmuth Berger, Henrik Moodysson Rønnow, Arnaud Magrez, Ivica Zivkovic, Krunoslav Prsa, Peter Babkevich

We present an experimental investigation of the magnetic structure in a tetramer system SeCuO3 using neutron powder-diffraction and nuclear resonance techniques. We establish a commensurate antiferromagnetic ordering with a propagation vector k = (0, 0, 1) ...

2018