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Zhaofu Fei

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Publications associées (133)

Page 2 sur 7

Functionalized Ionic (Poly)Styrenes and their Application as Catalysts in the Cycloaddition of CO2 to Epoxides

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei, Felix Daniel Bobbink, Shoubhik Das

Valorization of CO2, an abundant C(1) synthon, into platform chemicals is of growing interest. In this context, a key reaction is the cycloaddition of CO2 to epoxides to form carbonates (CCE). A series of organocatalysts for this reaction, based on imidazo ...

Wiley-Blackwell2016

Aqueous-phase hydrogenation of alkenes and arenes: The growing role of nano scale catalysts

Paul Joseph Dyson, Zhaofu Fei, Ning Yan, Safak Bulut, Sviatlana Siankevich

In this article we highlight some of the recent developments in the aqueous-phase hydrogenation of alkenes and arenes. The traditional types of water-soluble catalysts applied in aqueous media are outlined together with recent trends towards the developmen ...

Elsevier Science Bv2015

Unconventional Tough Double-Network Hydrogels with Rapid Mechanical Recovery, Self-Healing, and Self-Gluing Properties

Paul Joseph Dyson, Zhaofu Fei, Zhangjun Huang, Haiyan Jia, Xunhui Wang

Hydrogels are polymeric materials that have a relatively high capacity for holding water. Recently, a double network (DN) technique was developed to fabricate hydrogels with a toughness comparable to rubber. The mechanical properties of DN hydrogels may be ...

Amer Chemical Soc2016

Efficient Solid-State Electrolytes Based on Aryl-Modified Imidazolium Ionic Crystals for Quantum Dot-Sensitized Solar Cells

Paul Joseph Dyson, Zhaofu Fei

Cost-effective solid-state electrolytes with improved conductivity and device performances have received much research interest in (photo)-electrochemical cells, including solar cells, secondary batteries, and so on. In this work, a series of organic ionic ...

AMER CHEMICAL SOC2021

Controlling Tin Halide Perovskite Oxidation Dynamics in Solution for Perovskite Optoelectronic Devices

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Aurélien Bornet, Roland Christopher Turnell-Ritson, Guixiang Li, Shun Tian

As a leading contender to replace lead halide perovskites, tin-based perovskites have demonstrated ever increasing performance in solar cells and light-emitting diodes (LEDs). They tend to be processed with dimethyl sulfoxide (DMSO) solvent, which has been ...

Wiley-VCH Verlag GmbH2024

Synthesis of Cross-linked Ionic Poly(styrenes) and their Application as Catalysts for the Synthesis of Carbonates from CO2 and Epoxides

Paul Joseph Dyson, Zhaofu Fei, Felix Daniel Bobbink, Antoine Philippe Van Muyden, Aswin Gopakumar

A series of dicationic styrene-functionalized imidazolium-based salts, in which the two imidazolium rings are bridged by a functionalized spacer, are prepared. The salts are polymerized to afford cross-linked imidazolium-based ionic polystyrene materials, ...

Wiley-VCH Verlag2017

Benzimidazolium salt-based solid-state electrolytes afford efficient quantum-dot sensitized solar cells

Paul Joseph Dyson, Zhaofu Fei, Zhangjun Huang

A novel solid-state electrolyte based on 1,3-dihexylbenzimidazolium ([DHexBIm]) cations combined with Br-, BF4- or SCN- anions is used in CdS/CdSe sensitized quantum dot sensitized solar cells (QDSSCs). A power conversion efficiency of 4.26% was achieved w ...

Royal Society of Chemistry2017

A Crystallographic Story of Snakes and Ladders: Encapsulated Water Polymers and Rigid Metal Complexes Based on Mono-N-substituted Carboxylate 4,4'-Bipyridine

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei, Wee Han Ang, Andrew Douglas Phillips

A new zwitterionic bidentate ligand was synthesized incorporating a 4,4'-bipyridine core with a carboxylate group as a single building block, specifically designed for the rational construction of supramol. structures (metal-org. frameworks) that are capab ...

2009

Enhancing the Efficiency and Stability of Perovskite Solar Cells Using Chemical Bath Deposition of SnO2 Electron Transport Layers and 3D/2D Heterojunctions

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Hiroyuki Kanda, Pascal Alexander Schouwink, Liping Zhong, Xiaoxin Gao, Shun Tian, David Fernando Reyes Vasquez, Yanyan Fang

Chemical bath deposition (CBD) is an effective technique used to produce high-quality SnO2 electron transport layers (ETLs) employed in perovskite solar cells (PSCs). By optimizing the CBD process, high-quality SnO2 films are obtained with minimal oxygen v ...

2024

Allyl-functionalised ionic liquids: Synthesis, characterisation, and reactivity

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Zhaofu Fei, Dongbin Zhao

The two known Me- and allyl-substituted 1H-imidazol-3-ium bromides 1 and 2, respectively, were converted to the corresponding BF4- and BPh4- salts 3-6 (Scheme 1). Compounds 3 and 4 were liquids at ambient temperature. Reaction of 1 or 2 with [PdCl2] afford ...

2005

Structure of nitrile-functionalized alkyltrifluoroborate salts

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei, Dongbin Zhao

Two nitrile-functionalized alkyltriflouroborate anion based complexes [(Ph3P)(2)N][CH3CH(BF3)CH2CN] and [K(18-crown-6)][CH3CH(BF3)CH2CN] were synthesized and characterized by spectroscopic methods and single X-ray diffraction analysis. In the former comple ...

2005

Phosphorylation of Diaminopyridines: Synthesis of a Compound Containing Both a Diphosphinoamine ( P-N-P) and an Iminobiphosphine ( N=P-P) Fragment

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei, Wee Han Ang, Emilia Paunescu

The phosphorylation of a series of diaminopyridines (2,3-, 3,4-, 2,5- and 2,6-diaminopyridine), with various molecular equivalents of chlorodiphenylphosphine in the presence of TEA has been studied. Notably, phosphorylation of 2,3- and 3,4-diaminopyridine ...

Wiley-V C H Verlag Gmbh2014

Carbonized wood impregnated with bimetallic nanoparticles as a monolithic continuous-flow microreactor for the reduction of 4-nitrophenol

Qingtong Zhang, Paul Joseph Dyson, Zhaofu Fei, Rosemarie Janet Somerville

Porous monolithic microreactors show great promise in catalytic applications, but are usually based on non-renewable materials. Herein, we demonstrate a Ni/Au nanoparticle-decorated carbonized wood (Ni/Au-CW) monolithic membrane microreactor for the effici ...

ELSEVIER2023

An efficient Pt nanoparticle–ionic liquid system for the hydrodeoxygenation of bio-derived phenols under mild conditions

Paul Joseph Dyson, Gabor Laurenczy, Zhaofu Fei, Lu Chen, Cornel Fink

Platinum nanoparticles (NPs) were synthesized in situ in the ionic liquid (IL) [Emim]NTf2 (1-ethyl-3- methylimidazolium bis(trifluoromethylsulfonyl)imide) as well as in mixtures of [Emim]NTf2 with a second IL, Lewis acid or Brønsted acid, but in the absenc ...

Royal Society of Chemistry2017

Electrostatic and Non-covalent Interactions in Dicationic Imidazolium-Sulfonium Salts with Mixed Anions

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Zhaofu Fei, Ning Yan

A series of thioether-functionalised imidazolium salts have been prepared and characterized. Subsequent reaction of the thioether-functionalised imidazolium salts with iodomethane affords imidazolium-sulfonium salts composed of doubly charged cations and t ...

Wiley-V C H Verlag Gmbh2014

Dopant-Free Pyrene-Based Hole Transporting Material Enables Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Farzaneh Fadaei Tirani, Zhaofu Fei, Bin Ding, Yong Ding, Keith Gregory Brooks

Dopant-free hole transporting materials (HTMs) is significant to the stability of perovskite solar cells (PSCs). Here, we developed a novel star-shape arylamine HTM, termed Py-DB, with a pyrene core and carbon-carbon double bonds as the bridge units. Compa ...

Wiley-VCH Verlag GmbH2024

Application of Ionic Liquids in the Downstream Processing of Lignocellulosic Biomass

Paul Joseph Dyson, Zhaofu Fei, Ning Yan, Sviatlana Siankevich

Chemical transformations of lignocellulosic substrates to valuable platform chemicals are challenging as lignin and cellulose have high thermal and chemical stabilities. However, certain ionic liquids are able to dissolve and deconstruct biomass and, in th ...

Schweizerische Chemische Gesellschaft2015

Synthesis and characterization of ether-derivatized aminophosphines and their application in C-C coupling reactions

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei

Four new bis(phosphino)amine ligands (Ph2P)2N-C6H3-R, where R = 3,5-OMe (1), 2,5-OMe (2), 2,4-OMe (3) or 3,4-OMe (4), were prepd. via aminolysis of the corresponding dimethoxyanilines with 2 equiv. of diphenylphosphine chloride in the presence of tri-Et am ...

Elsevier2010

Transformation of Glucose to 5-Hydroxymethylfurfural Over Regenerated Cellulose Supported Nb2O5 center dot nH(2)O in Aqueous Solution

Fangmin Huang, Paul Joseph Dyson, Zhaofu Fei, Lu Chen

Niobic acid (Nb2O5 center dot nH(2)O) was immobilized on regenerated cellulose (Re-Cellulose) to afford a heterogeneous catalyst, termed Nb2O5 center dot nH(2)O@Re-Cellulose, that was characterized by powder X-ray diffraction, microscopy (SEM and TEM) and ...

SPRINGER2020

A strategy for the synthesis of transition-metal nanoparticles and their transfer between liquid phases

Paul Joseph Dyson, Zhaofu Fei, Wee Han Ang, Dongbin Zhao

Nanoparticles can be stabilized by an ionic liq. polymer (ILP) composed of imidazolium units incorporating a hydrophobic benzyl group. The resulting gold, platinum, and palladium nanoparticles can be efficiently transferred from water to ionic liqs. by exc ...

2006