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Shaik Mohammed Zakeeruddin

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Publications associées (514)

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Low-Cost and Highly Efficient Carbon-Based Perovskite Solar Cells Exhibiting Excellent Long-Term Operational and UV Stability

Michael Graetzel, Shaik Mohammed Zakeeruddin, Thomas Paul Baumeler, Mohammad Ibrahim Dar, Neha Arora, Ryusuke Uchida, Yuhang Liu, Seckin Akin

Today's perovskite solar cells (PSCs) mostly use components, such as organic hole conductors or noble metal back contacts, that are very expensive or cause degradation of their photovoltaic performance. For future large-scale deployment of PSCs, these comp ...

2019

Interfacial and bulk properties of hole transporting materials in perovskite solar cells: spiro-MeTAD versus spiro-OMeTAD

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt

Two spiro-MeTAD compounds (1 and 2) were synthesized, characterized by experimental and quantum mechanical methods, and used as hole transporting materials (HTMs) in perovskite solar cells (PSCs). The new compounds differ from spiro-OMeTAD only by the pres ...

Royal Society of Chemistry2020

Influence of Sodium Cations of N3 Dye on the Photovoltaic Performance and Stability of Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin

We report on the effect of substituting the two tetrabutyl ammonium counter ions of the standard N719 dye by sodium ions on the performance and stability of dye-sensitized solar cells (DSCs). The disodium analogue of N719 in conjunction with a non-volatile ...

2009

Formation of High-Performance Multi-Cation Halide Perovskites Photovoltaics by delta-CsPbI3/delta-RbPbI3 Seed-Assisted Heterogeneous Nucleation

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mounir Driss Mensi, Ulf Anders Hagfeldt, Thomas Paul Baumeler, Linfeng Pan, Essa Awadh R Alharbi, Zaiwei Wang, Masaud Hassan S Almalki, Bowen Yang, Felix Thomas Eickemeyer, Anurag Krishna, Olivier Ouellette

The performance of perovskite solar cells is highly dependent on the fabrication method; thus, controlling the growth mechanism of perovskite crystals is a promising way towards increasing their efficiency and stability. Herein, a multi-cation halide compo ...

2021

Efficient stable graphene-based perovskite solar cells with high flexibility in device assembling via modular architecture design

Michael Graetzel, Shaik Mohammed Zakeeruddin, Hong Zhang, Chunyang Zhang

Carbon-based perovskite solar cells (C-PSCs) are emerging as low-cost stable photovoltaics. However, their power conversion efficiency (PCE) still lags behind that of devices based on Au or Ag as the current collector. Here, we introduced an innovative mod ...

2019

Indolizine-Based Donors as Organic Sensitizer Components for Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Fabrizio Giordano, Aron Joel Huckaba

Strong electron-donating functionality is desirable for many organic donor-pi-bridge-acceptor (D-pi-A) dyes. Strategies for increasing the electrondonating strength of common nitrogen-based donors include planarization of nitrogen substituents and the use ...

Wiley-V C H Verlag Gmbh2015

New Efficiency Records for Stable Dye-Sensitized Solar Cells with Low-Volatility and Ionic Liquid Electrolytes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Nuttapol Pootrakulchote, Peng Wang

We report a high molar extinction coefficient heteroleptic polypyridyl ruthenium sensitizer, featuring an electron-rich 3,4-ethylenedioxythiophene unit in its ancillary ligand. A nanocrystalline titania film stained with this sensitizer shows an improved o ...

2008

Interfacial Kinetics of Efficient Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Michael Saliba, Daniel Prochowicz

Perovskite solar cells (PSCs) have immense potential for high power conversion efficiency with an ease of fabrication procedure. The fundamental understanding of interfacial kinetics in PSCs is crucial for further improving of their photovoltaic performanc ...

2017

Stable dye-sensitized solar cells based on organic chromophores and ionic liquid electrolyte

Pascal Comte, Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin

A series of polyene-diphenylaniline based organic dyes (coded as D5, D7, D9 and D11) have been reported for the application in ionic liquid electrolyte based dye-sensitized solar cells. The effects of substitution of organic dyes on the photovoltaic perfor ...

2011

Thermodynamic stability screening of IR-photonic processed multication halide perovskite thin films

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Sandy Sanchez Alonso, Natalie Flores Diaz, Pascal Alexander Schouwink, Brian Irving Carlsen

We report a material screening study for phase transitions of multication hybrid halide perovskite films. Two hundred sixty-six films processed with flash infrared annealing were optically and structurally characterized. This data was compiled into a datab ...

Royal Society of Chemistry2021

Transport and Interfacial Transfer of Electrons in Dye-Sensitized Solar Cells Utilizing a Co(dbbip)(2) Redox Shuttle

Michael Graetzel, Shaik Mohammed Zakeeruddin

The transport and interfacial transfer of electrons in dye-sensitized solar cells utilizing the Co(dbbip)(2) (dbbip = 2,6-bis(l'-butylbenzimidazol-2'-yl)pyridine) redox couple as an alternative to the conventional I-3(-)/l(-) couple have been investigated ...

American Chemical Society2010

Design, synthesis and characterization of 1,8-naphthalimide based fullerene derivative as electron transport material for inverted perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Hui-Seon Kim

A new fullerene derivative, PC61BNI, was designed and synthesized in which [6,6]-phenyl C-61-butyric acid methyl ester (PC61BM) was modified by replacing the methyl group with 1,8-naphthalimide (NI) to investigate the molecular structure modification effec ...

ELSEVIER SCIENCE SA2019

Solar Water Splitting Using Earth-Abundant Electrocatalysts Driven by High-Efficiency Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Dan Ren, Hong Zhang

Hydrogen is considered as the "holy grail" for the energy community. One of the most promising strategies to produce hydrogen is to split water using renewable energy such as solar radiation. The abundance of water and solar energy enables the potential of ...

WILEY-V C H VERLAG GMBH2022

Low-Cost Dopant Additive-Free Hole-Transporting Material for a Robust Perovskite Solar Cell with Efficiency Exceeding 21%

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Linfeng Pan, Yuhang Liu, Felix Thomas Eickemeyer, Yameng Ren, Hongwei Zhu, Zhongjin Shen

Developing hole-transporting materials (HTMs) with appropriate molecular configuration and charge mobility is important to improve perovskite solar cell (PSC) photovoltaic performance and their feasibility for commercialization. In this work, a novel pyram ...

2021

Extraordinarily efficient conduction in a redox-active ionic liquid

Michael Graetzel, Jacques-Edouard Moser, Guido Rothenberger, Shaik Mohammed Zakeeruddin, Jan Cornelius Brauer

Iodine added to iodide-based ionic liquids leads to extraordi- narily efficient charge transport, vastly exceeding that expect- ed for such viscous systems. Using terahertz time-domain spectroscopy, in conjunction with dc conductivity, diffusivity and visc ...

Wiley-Blackwell2011

Synthesis, characterisation and biological properties of gold(iii) compounds with modified bipyridine and bipyridylamine ligands

Michael Graetzel, Shaik Mohammed Zakeeruddin, Rosario Scopelliti, Paul Joseph Dyson, Angela Casini

Square planar gold(iii) complexes that contain functionalised bipyridine ligands of general formula [Au(NN)Cl2][PF6] [where NN = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine, 4,4'-dimethoxy-2,2'-bipyridine and 4,4'-diamino-2,2'-bipyridine] have been prep ...

Royal Society of Chemistry2010

Helical interfacial modulation for perovskite photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jovana Milic, Marco Alejandro Ruiz Preciado, Felix Thomas Eickemeyer, Hong Zhang, Ghewa Alsabeh

Hybrid metal halide perovskites have demonstrated remarkable performances in modern photovoltaics, although their stabilities remain limited. We assess the capacity to advance their properties by relying on interfacial modulators featuring helical chiralit ...

Royal Soc Chemistry2024

Tridentate cobalt complexes as alternative redox couples for high-efficiency dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Thomas Moehl

Cobalt terpyridine complexes could rival the classical triiodide/iodide redox couple as efficient alternative redox couples for dye-sensitized solar cells. Cobalt bis(2,2',6',2 ''-terpyridine) complexes enable systematic tuning of the redox potential by va ...

Royal Soc Chemistry2013

Radical polymeric p-doping and grain modulation for stable, efficient perovskite solar modules

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yuhang Liu, Brian Irving Carlsen, Felix Thomas Eickemeyer

High-quality perovskite light harvesters and robust organic hole extraction layers are essential for achieving high-performing perovskite solar cells (PSCs). We introduce a phosphonic acid???functionalized fullerene derivative in mixed-cation perovskites a ...

American Association for the Advancement of Science2023

Combined Precursor Engineering and Grain Anchoring Leading to MA-Free, Phase-Pure, and Stable alpha-Formamidinium Lead Iodide Perovskites for Efficient Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Carole Graetzel, Linfeng Pan, Yuhang Liu, Dan Ren, Jing Gao, Hongwei Zhu, Anurag Krishna, Olivier Ouellette

alpha-Formamidinium lead iodide (alpha-FAPbI(3)) is one of the most promising candidate materials for high-efficiency and thermally stable perovskite solar cells (PSCs) owing to its outstanding optoelectrical properties and high thermal stability. However, ...

Wiley-VCH Verlag GmbH2021