Shaik Mohammed Zakeeruddin

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We present a facile molecular-level interface engineering strategy to augment the long-term operational and thermal stability of perovskite solar cells (PSCs) by tailoring the interface between the perovskite and hole transporting layer (HTL) with a multif ...

A tailored optimization of perovskite solar cells requires a detailed understanding of the processes limiting the device efficiency. Here, we study the role of the hole transport layer (HTL) spiro-MeOTAD and its thickness in a mesoscopic TiO2-based solar c ...

The performance enhancement of dye-sensitized solar cells (DSCs) in lithium-free and lithium-containing electrolytes under visible light-soaking was examined by impedance spectroscopy and photovoltage transient decay measurements. The improvement was found ...

Most photovoltaic (PV) technologies are opaque to maximize visible light absorption. However, see-through solar cells open additional perspectives for PV integration. Looking beyond maximizing visible light harvesting, this work considers the human eye pho ...

Perovskite solar cells (PSCs) have gained tremendous attention owing to their promising photovoltaic performance, surpassing all the alternative technologies based on solution-processed materials. PSCs displaying record efficiencies contain hole transporti ...

Tremendous efforts have been dedicated toward minimizing the open-circuit voltage deficits on perovskite solar cells (PSCs), and the fill factors are still relatively low. This hinders their further application in large scalable modules. Herein, we employ ...

LiMnPO4 (olivine) was surface-modified by two different complexes: Ru-bis(4,4'-diethoxycarbonyl-2,2'-bipyridine)(4,4'-dicarboxylate-2,2'-bipyridine) and Ru-bis(4-carboxylic acid-4'-carboxylate-2,2'-bipyridine)(4,4'-dinonyl-2,2'bipyridine). These complexes ...

Long-term durability is critically important for the commercialization of perovskite solar cells (PSCs). The ionic character of the perovskite and the hydrophilicity of commonly used additives for the hole-transporting layer (HTL), such as lithium bis(trif ...

The slow process in which the light absorbing dye molecules are adsorbed from solution on the nano-crystalline TiO2 photoelectrode film has been a handicap to the fast and cost-effective fabrication of dye-sensitized solar cells (DSSCs) using printing tech ...

Porphyrins have drawn much attention as sensitizers owing to the large absorption coefficients of their Soret and Q bands in the visible region. In a donor and acceptor zinc porphyrin we applied a new strategy of introducing 2,1,3-benzothiadiazole (BTD) as ...

Layered hybrid perovskites have emerged as a promising alternative to stabilizing hybrid organic-inorganic perovskite materials, which are predominantly based on Ruddlesden-Popper structures. Formamidinium (FA)-based Dion-Jacobson perovskite analogs are de ...

Photoelectrochemical carbon dioxide reduction (PEC-CO2R) represents a promising approach for producing renewable fuels and chemicals using solar energy. However, attaining even modest solar-to-fuel (STF) conversion efficiency often necessitates the use of ...

We successfully inkjet printed an ionic liquid electrolyte in the dye-sensitized solar cell (DSSC) as a part of a new cell fabrication sequence that eliminates drilling holes in the DSSC substrates. The inkjet printing of ionic liquid electrolyte does not ...

Two donor-π-acceptor (D-π-A) dyes, coded as L-3T-DPA 1 and B-5T-DPA 2, were synthesized for application in dye-sensitized solar cells. These D-π-A sensitizers use diphenylamine as donor, an oligothiophene as π-bridge, and cyanoacrylic acid as an acceptor g ...

Electrochemical reduction of carbon dioxide, using the electricity generated from renewable energy sources, has the potential of rendering a carbon-neutral energy economy. Developing selective, efficient and robust electrocatalysts is the key step towards ...

We have measured the binding coefficients of iodine to three dyes used in Dye Sensitised Solar Cells (DSSCs). Binding coefficients are quantified via the effect of iodine binding on the UV-vis spectrum of the dye. From iodine titration curves of dye sensit ...

Redox mediators play a major role determining the photocurrent and the photovoltage in dye-sensitized solar cells (DSCs). To maintain the photocurrent, the reduction of oxidized dye by the redox mediator should be significantly faster than the electron bac ...

The synthesis, characterization, and photovoltaic performance of a series of indacenodithiophene (IDT)-based D--A organic dyes with varying electron-accepting units is presented. By control of the electron affinity, perfectly matching energy levels were ac ...

Today's perovskite solar cells (PSCs) mostly use components, such as organic hole conductors or noble metal back contacts, that are very expensive or cause degradation of their photovoltaic performance. For future large-scale deployment of PSCs, these comp ...

Two spiro-MeTAD compounds (1 and 2) were synthesized, characterized by experimental and quantum mechanical methods, and used as hole transporting materials (HTMs) in perovskite solar cells (PSCs). The new compounds differ from spiro-OMeTAD only by the pres ...

Shaik Mohammed Zakeeruddin

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Nanoscale interfacial engineering enables highly stable and efficient perovskite photovoltaics

Light Harvesting and Charge Recombination in CH3NH3PbI3 Perovskite Solar Cells Studied by Hole Transport Layer Thickness Variation

Enhancement of the performance of dye-sensitized solar cell by formation of shallow transport levels under visible light illumination

Transparent and Colorless Dye-Sensitized Solar Cells Exceeding 75% Average Visible Transmittance

A Fully Printable Hole-Transporter-Free Semi-Transparent Perovskite Solar Cell

Interfacial Passivation Engineering of Perovskite Solar Cells with Fill Factor over 82% and Outstanding Operational Stability on n-i-p Architecture

Molecular wiring of LiMnPO4 (olivine) by ruthenium(II)-bipyridine complexes

Synergistic Effect of Fluorinated Passivator and Hole Transport Dopant Enables Stable Perovskite Solar Cells with an Efficiency Near 24%

Dye-sensitized solar cells with inkjet-printed dyes

Molecular Engineering of Push-Pull Porphyrin Dyes for Highly Efficient Dye-Sensitized Solar Cells: The Role of Benzene Spacers

Formamidinium-Based Dion-Jacobson Layered Hybrid Perovskites: Structural Complexity and Optoelectronic Properties

Efficient Cu2O Photocathodes for Aqueous Photoelectrochemical CO2 Reduction to Formate and Syngas

High performance dye-sensitized solar cells with inkjet printed ionic-liquid electrolyte

D-π-A Sensitizers for Dye-Sensitized Solar Cells: Linear vs Branched Oligothiophenes

Bimetallic Electrocatalysts for Carbon Dioxide Reduction

Measured binding coefficients for iodine and ruthenium dyes; implications for recombination in dye sensitised solar cells

Copper Bipyridyl Redox Mediators for Dye-Sensitized Solar Cells with High Photovoltage

Electron-Affinity-Triggered Variations on the Optical and Electrical Properties of Dye Molecules Enabling Highly Efficient Dye-Sensitized Solar Cells

Low-Cost and Highly Efficient Carbon-Based Perovskite Solar Cells Exhibiting Excellent Long-Term Operational and UV Stability

Interfacial and bulk properties of hole transporting materials in perovskite solar cells: spiro-MeTAD versus spiro-OMeTAD