Shaik Mohammed Zakeeruddin

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The defects present in metal halide perovskite are deleterious to both the performance and stability of photovoltaic devices. Consequently, there is an intense focus on developing defect mitigation strategies. Herein we report a facile strategy that employ ...

Improvements to perovskite solar cells (PSCs) have focused on increasing their power conversion efficiency (PCE) and operational stability and maintaining high performance upon scale-up to module sizes. We report that replacing the commonly used mesoporous ...

State-of-the-art halide perovskite solar cells employ semiconductor oxides as electron transportmaterials. Defects in these oxides, such as oxygen vacancies (Ovac), act as recombination centres and, in air and UV light, reduce the stability of the solar ce ...

A perovskite material including an organic-inorganic perovskite structure of formula (I), AnMX3 (I), n being the number of cation A and an integer >4, A being a monovalent cation selected from inorganic cations Ai and/or from organic cations Ao, M being a ...

A new D-pi-A organic dye, LC-5, containing 4,9-dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b']-dithiophene as a novel pi-conjugated spacer has been synthesized and tested as a sensitizer in dye-sensitized solar cells (DSC). Volatile and ionic liquid el ...

The present invention relates to optoelectronic and/or electrochemical devices comprising an organic charge transporting material which is liquid at a temperature of =180 DEG C. In particular in dye-sensitised solar cells, quantum efficiency higher than wi ...

Metal halide perovskites (MHPs) have shown an incredible increase in efficiency, reaching as high as 25.7%, which now competes with traditional photovoltaic technologies. Herein, we excluded CsX and RbX (X = I–, Br–, Cl–), the most commonly used cations to ...

Herein, green porphyrin sensitizer Y350-based dye-sensitized solar cells (DSCs) with binary ionic liquid-based electrolytes are studied, which are a mixture of 1-methyl-3-propyl-imidazolium iodide and 1-methyl-1-butylpyrrolidinium bis(trifluromethylsulfony ...

Four organic donor–π-bridge–acceptor dyes containing phenothiazine as a spacer and cyanoacrylic acid as an acceptor were synthesized and tested as sensitizers in dye-sensitized solar cells (DSCs). The influence of iodide- and cobalt-based redox electrolyte ...

Semitransparent dye-sensitized solar cells (DSCs) are appealing as aesthetically pleasing and colorful see-through photovoltaics. Green semitransparent DSCs have been presented, but the best ones rely on green zinc porphyrin photosensitizers and high volat ...

Lack of proven stability has become a major obstacle on the path of metal halide perovskite solar cells (PSCs), in particular methylammonium lead triiodide (MAPbI(3)), towards commercial viability. This correlates with the intrinsic affinity of MAPbI(3) to ...

Due to the ease of tuning its redox potential, the cobalt-based redox couple has been extensively applied for highly efficient dye-sensitized solar cells (DSSCs) with extraordinarily high photovoltages. However, a cobalt electrolyte needs particular struct ...

We synthesized the Cu(II) and Zn(II) complexes of the 2,7,12,17-tetrapropionic acid of 3,8,13,18-tetramethyl-21H,23H porphyrin (coproporphyrin-I) and successfully employed them as sensitizers in dye-sensitized solar cells. Copper(II) coproporphyrin-I exhib ...

Perovskite solar cells have garnered significant interest, yet their limited operational stability remains a major challenge. This is especially pronounced at the interface with charge transport layers. In inverted p-i-n perovskite solar cells, fullerene-based electron transport layers pose critical stability issues. This has stimulated the application of low-dimensional perovskite interlayers featuring alkylammonium-based organic spacers that template perovskite slabs to enhance operational stabilities. Ho

All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a "cation cascade" to create perovskite mat ...

The new gold(III) complexes: [Au{2-(2'-pyridyl) imidazolate}Cl-2] and [Au{2,6-bis(2'-benzimidazolate) pyridine}(OCOCH3)] and the mono-and binuclear gold(I) complexes: Au{2-(2'-pyridyl) imidazole} (PPh3), [Au(2-phenylimidazolate)(DAPTA)] (DAPTA = 3,7 ...

Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achi ...

To apply impedance spectroscopy (IS) for studying charge transport in the mesoporous film of solid-state dye-sensitized solar cells (ss-DSCs), it is necessary to determine the relative conductivities of the electron and hole transporting phases, given the ...

Novel donor-p-acceptor (D--A) dyes, coded as SD-1, SD-2 and SD-5, were designed and synthesized for dye-sensitized solar cells. All these dyes comprised the same donor and acceptor units while the oligo thiophene units were introduced as linkers between th ...

Solar-driven carbon dioxide reduction has witnessed a renaissance in the past decades, but the system suffers from low reaction rates. Here the authors develop a copper/tin-oxide electrocatalyst, achieving a new benchmark solar-to-CO energy conversion effi ...

Shaik Mohammed Zakeeruddin

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Methylammonium Triiodide for Defect Engineering of High-Efficiency Perovskite Solar Cells

Conformal quantum dot-SnO2 layers as electron transporters for efficient perovskite solar cells

PbZrTiO3 ferroelectric oxide as an electron extraction material for stable halide perovskite solar cells

Mixed cation perovskite solid state solar cell and fabrication thereof

4,9-Dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b ']dithiophene as a pi-Spacer of Donor-pi-Acceptor Dye and Its Photovoltaic Performance with Liquid and Solid-State Dye-Sensitized Solar Cells

Liquid charge transporting material

Surface Passivation of FAPbI3-Rich Perovskite with Cesium Iodide Outperforms Bulk Incorporation

Photovoltaic Performance of Porphyrin-Based Dye-Sensitized Solar Cells with Binary Ionic Liquid Electrolytes

Long-Range π-Conjugation in Phenothiazine-containing Donor-Acceptor Dyes for Application in Dye-Sensitized Solar Cells

A Blue Photosensitizer Realizing Efficient and Stable Green Solar Cells via Color Tuning by the Electrolyte

Outdoor Performance and Stability under Elevated Temperatures and Long-Term Light Soaking of Triple-Layer Mesoporous Perovskite Photovoltaics

Molecular Engineering of Pyrido[3,4-b]pyrazine-Based Donor-Acceptor-pi- Acceptor Organic Sensitizers: Effect of Auxiliary Acceptor in Cobalt- and Iodine-Based Electrolytes

Application of Cu(II) and Zn(II) coproporphyrins as sensitizers for thin film dye sensitized solar cells

Electroactive naphthalimide and naphthalenediimide interlayers for inverted perovskite solar cells

Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance

Cytotoxic gold compounds: synthesis, biological characterization and investigation of their inhibition properties of the zinc finger protein PARP-1

A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells

Determining the Conductivities of the Two Charge Transport Phases in Solid-State Dye-Sensitized Solar Cells by Impedance Spectroscopy

Molecular design of metal-free D–π-A substituted sensitizers for dye-sensitized solar cells

Solar reduction of carbon dioxide on copper-tin electrocatalysts with energy conversion efficiency near 20%