Recherche

Afficher tous les résultats pour

Accueil

Personne

Michael Graetzel

À propos
Confidentialité
Mentions légales

Graph Chatbot

Publications associées (1 223)

Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts

Michael Graetzel, Mohammad Khaja Nazeeruddin, Marcel Roland Schreier, Stanley David Tilley, Matthew Thomas Mayer, Jingshan Luo, Jeong-Hyeok Im

Although sunlight-driven water splitting is a promising route to sustainable hydrogen fuel production, widespread implementation is hampered by the expense of the necessary photovoltaic and photoelectrochemical apparatus. Here, we describe a highly efficie ...

American Association for the Advancement of Science2014

Perovskite Solar Cells Based on Nanocolumnar PlasmaDeposited ZnO Thin Films

Michael Graetzel, Mohammad Khaja Nazeeruddin, Francisco Javier Ramos Mellado

ZnO thin films having a nanocolumnar microstructure are grown by plasma-enhanced chemical vapor deposition at 423 K on pre-treated fluorine-doped tin oxide (FTO) substrates. The films consist of c-axis-oriented wurtzite ZnO nanocolumns with well-defined mi ...

Wiley-Blackwell2014

A Bismuth Vanadate-Cuprous Oxide Tandem Cell for Overall Solar Water Splitting

Michael Graetzel, Kevin Sivula, Pauline Bornoz, Stanley David Tilley

Through examination of the optoelectronic and photoelectrochemical properties of BiVO4 and Cu2O photoelectrodes, we evaluate the feasibility of a BiVO4/Cu2O photoanode/photocathode tandem cell for overall unassisted solar water splitting. Using state-of-th ...

American Chemical Society2014

New pyrido[3,4-b]pyrazine-based sensitizers for efficient and stable dye-sensitized solar cells

Pascal Comte, Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Thomas Moehl, Mateusz Barnaba Wielopolski, Jiabao Yang

A series of new pyrido[3,4-b]pyrazine-based organic sensitizers (PP-I and APP-I–IV) containing different donors and p-spacers have been synthesized and employed in dye-sensitized solar cells (DSSCs). The absorption spectra properties of dyes are analysed b ...

Royal Soc Chemistry2014

Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation

Michael Graetzel, Nripan Mathews

Lead free perovskite solar cells based on a CsSnI3 light absorber with a spectral response from 950 nm is demonstrated. The high photocurrents noted in the system are a consequence of SnF2 addition which reduces defect concentrations and hence the backgrou ...

Wiley-V C H Verlag Gmbh2014

Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers

Michael Graetzel, Mohammad Khaja Nazeeruddin, Robin Humphry-Baker, Ursula Röthlisberger, Ivano Tavernelli, Basile Curchod, Negar Ashari Astani, Aswani Yella, Peng Gao, Simon Mathew

Dye-sensitized solar cells have gained widespread attention in recent years because of their low production costs, ease of fabrication and tunable optical properties, such as colour and transparency. Here, we report a molecularly engineered porphyrin dye, ...

2014

Extended pi-Bridge in Organic Dye-Sensitized Solar Cells: the Longer, the Better?

Michael Graetzel, Mohammad Khaja Nazeeruddin, Chenyi Yi, Hoi Nok Tsao, Peng Gao

The elongation of pi-conjugated bridges between the donor (D) and the acceptor (A) represents a feasible strategy towards enhancement of light-harvesting in both breadth and depth of organic D-pi-A dyes suitable for nanocrystalline TiO2-based dye-sensitize ...

Wiley-VCH Verlag Berlin2014

Strong Photocurrent Amplification in Perovskite Solar Cells with a Porous TiO2 Blocking Layer under Reverse Bias

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Thomas Moehl, Leo-Philipp Heiniger, Mohammad Ibrahim Dar, Konrad Domanski, Fabrizio Giordano, Yonghui Lee, Jeong-Hyeok Im

We investigate two different types of TiO2 blocking layer (BL) deposition techniques commonly used in solid-state methylammonium lead triiodide perovskite (MaPbI(3))-based solar cells. Although these BLs lead to similar photovoltaic device performance, the ...

Amer Chemical Soc2014

Effect of Extended π-Conjugation of the Donor Structure of Organic D–A−π–A Dyes on the Photovoltaic Performance of Dye-Sensitized Solar Cells

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Takeru Bessho, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski

Two new D−A−π-spacer−A organic dyes, KM-10 and KM-11, containing a benzothiadiazole unit in a π-spacer and a cyanoacrylic acid as an acceptor have been synthesized and tested as sensitizers in dye-sensitized solar cells. Structural variations of the donor ...

Amer Chemical Soc2014

Highly Efficient Metal-Free Sulfur-Doped and Nitrogen and Sulfur Dual-Doped Reduced Graphene Oxide Counter Electrodes for Dye-Sensitized Solar Cells

Michael Graetzel, Lichen Zhao, Hujiang Shen, Shilong Wang

Developing metal-free electrocatalysts with both high performance and low cost for the reduction reaction at the cathode of dye-sensitized solar cells (DSCs) is critical for further cost reduction and large-scale implementation of DSCs. Here, sulfurdoped r ...

American Chemical Society2014

High efficiency electrospun TiO2 nanofiber based hybrid organic-inorganic perovskite solar cell

Michael Graetzel, Thi Thu Trang Pham, Nripan Mathews

The good electrical and morphological characteristics of TiO2 nanofibers and the high extinction coefficient of CH3NH3PbI3 perovskite are combined to obtain a solar cell with a power conversion efficiency of 9.8%. The increase of the film thickness dramati ...

Royal Society of Chemistry2014

Photoanode Based on (001)-Oriented Anatase Nanoplatelets for Organic-Inorganic Lead Iodide Perovskite Solar Cell

Michael Graetzel, Mohammad Khaja Nazeeruddin, Mohammad Ibrahim Dar, Francisco Javier Ramos Mellado

The methodology adopted for the preparation of perovskites plays a critical role in achieving high efficiency. Toward this direction, various strategies have been adopted to achieve a rational control over the growth of the perovskite layer for the fabrica ...

American Chemical Society2014

Hematite photoelectrodes for water splitting: evaluation of the role of film thickness by impedance spectroscopy

Michael Graetzel, Kevin Sivula, Florian Le Formal

The electrochemical behavior of alpha-Fe2O3 photoelectrodes prepared by spray pyrolysis with different thicknesses was examined under dark and illumination conditions. The main charge transport phenomena occurring in the PEC cell photoelectrodes were chara ...

Royal Soc Chemistry2014

Quantum-Confined ZnO Nanoshell Photoanodes for Mesoscopic Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Aravind Kumar Chandiran, Aswani Yella, Chenyi Yi, Mojtaba Abdi Jalebi, Mohammad Ibrahim Dar

We present a photoanode for dye-sensitized solar cell (DSC) based on ZnO nanoshell deposited by atomic layer deposition at 150°C, on a mesoporous insulating template. An ultrathin layer of ZnO between 3 and 6 nm, which exhibits quantum confinement effect, ...

American Chemical Society2014

Back Electron-Hole Recombination in Hematite Photoanodes for Water Splitting

Michael Graetzel, Maurin Cornuz, Florian Le Formal, Stanley David Tilley

The kinetic competition between electron-hole recombination and water oxidation is a key consideration for the development of efficient photoanodes for solar driven water splitting. In this study, we employed three complementary techniques, transient absor ...

American Chemical Society2014

Thiocyanate-Free Ruthenium(II) Sensitizers for Dye-Sensitized Solar Cells Based on the Cobalt Redox Couple

Michael Graetzel, Mohammad Khaja Nazeeruddin, Aswani Yella, Kuan-Lin Wu, Filippo de Angelis, Shilong Wang

Two thiocyanate-free ruthenium(II) sensitizers, TFRS-41 and TFRS-42, with distinctive dialkoxyphenyl thienyl substituents were successfully prepared and tested for potential applications in making dye-sensitized solar cells (DSCs). Subsequent device fabric ...

Wiley-VCH Verlag Berlin2014

Electronic tuning effects via pi-linkers in tetrathiafulvalene-based dyes

Michael Graetzel, Chenyi Yi

Four new tetrathiafuIvalene (TTF)-based dyes featured with a donor-bridge-acceptor (D-pi-A) structure were synthesized and characterized. ALL of them undergo two reversible oxidations to form stable radical cation and dication species. The eIectronic inter ...

Royal Society of Chemistry2014

Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency

Michael Graetzel, Mohammad Khaja Nazeeruddin, Nicolas Tétreault, Peng Qin

Organo-lead halide perovskites have attracted much attention for solar cell applications due to their unique optical and electrical properties. With either low-temperature solution processing or vacuum evaporation, the overall conversion efficiencies of pe ...

Nature Publishing Group2014

High-Surface-Area Porous Platinum Electrodes for Enhanced Charge Transfer

Michael Graetzel, Marcel Roland Schreier, Francesco Stellacci, Aswani Yella, Yelin Hu, Morgan Mertens Stefik, Stefan Guldin

Cobalt-based electrolytes are highly tunable and have pushed the limits of dye-sensitized solar cells, enabling higher open-circuit voltages and new record efficiencies. However, the performance of these electrolytes and a range of other electrolytes suffe ...

Wiley-V C H Verlag Gmbh2014

Electrochemical Characterization of TiO2 Blocking Layers for Dye-Sensitized Solar Cells

Michael Graetzel, Ladislav Kavan, Nicolas Tétreault, Thomas Moehl

Thin compact layers of TiO2 are grown by thermal oxidation of Ti, by spray pyrolysis, by electrochemical deposition, and by atomic layer deposition. These layers are used in dye-sensitized solar cells to prevent recombination of electrons from the substrat ...

American Chemical Society2014

Page 29 sur 62