Concept

Structure presque complexe

Publications associées (29)

Rh-I, Ir-III ,and Co-III Complexes with Atropchiral Biaryl Cyclopentadienyl Ligands: Syntheses, Structures, and Catalytic Activities

Nicolai Cramer, Coralie Danielle Annick Duchemin, Gints Smits

Chiral cyclopentadienyl (Cp-x) group 9 metal complexes have become versatile catalysts for a variety of efficient enantioselective C-H functionalizations. Atropchiral binaphthyl-derived Cp-x ligands having tuning options at the 3,3'-positions present a rob ...

2019

Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting (CpRhIII)-Rh-X-Catalyzed C-H Functionalization

Nicolai Cramer, Marcus Brauns

Chiral sulfoximines with stereogenic sulfur atoms are promising motifs in drug discovery. We report an efficient method to access chiral sulfoximines through a C-H functionalization based kinetic resolution. A rhodium(III) complex equipped with a chiral Cp ...

Wiley-VCH Verlag GmbH2019

Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C-H Functionalizations

Nicolai Cramer, Yun-Suk Jang, Kristers Ozols

The synthesis of a set of cobalt(III)-complexes equipped with trisubstituted chiral cyclopentadienyl ligands is reported, and their steric and electronic parameters are mapped. The application potential of these complexes for asymmetric C-H functionalizati ...

2019

An Optimal Planning Framework to Deploy Self-Reconfigurable Modular Robots

Auke Ijspeert, Mehmet Hasan Mutlu, Simon Lukas Hauser, Alexandre Bernardino, Hala Khodr

Self-reconfiguration is a hard problem due to the high dimensionality of self-reconfigurable modular systems. Searchbased approaches offer complete and optimal solutions. However, naive search algorithms cannot directly solve self-reconfiguration tasks in ...

2019

Some regularity results for p-harmonic mappings between Riemannian manifolds

Changyu Guo

Let M be a C-2-smooth Riemannian manifold with boundary and N a complete C-2-smooth Riemannian manifold. We show that each stationary p-harmonic mapping u: M -> N, whose image lies in a compact subset of N, is locally C-1,C-alpha for some alpha is an eleme ...

2019

Phase resolved characterization of nanoscale features in optical microstructures

Michail Symeonidis

In this study, we apply interferometric microscopy to study the phase, alongside the intensity, of the light field transmitted through a wide variety of samples. Additionally, we conduct those interferometric measurements at different wavelengths within th ...

EPFL2019

Experimental Insights Into Fault Reactivation in Gouge-Filled Fault Zones

Carolina Giorgetti, Francesco Tesei

Faults in the brittle crust constitute preexisting weakness zones that can be reactivated depending on their friction, orientation within the local stress field, and stress field magnitude. Analytical approaches to evaluate the potential for fault reactiva ...

AMER GEOPHYSICAL UNION2019

Negentropic linguistic evolution: A comparison of seven languages

Frédéric Kaplan, Vincent Christian Buntinx

The relationship between the entropy of language and its complexity has been the subject of much speculation – some seeing the increase of linguistic entropy as a sign of linguistic complexification or interpreting entropy drop as a marker of greater regul ...

Red de Humanidades Digitales A. C.2018

Structure-Preserving Reduced Basis Methods for Hamiltonian Systems with a State-dependent Poisson Structure

Jan Sickmann Hesthaven, Cecilia Pagliantini

We develop structure-preserving reduced basis methods for a large class of nondissipative problems by resorting to their formulation as Hamiltonian dynamical systems. With this perspective, the phase space is naturally endowed with a Poisson manifold struc ...

2018