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Concept

Photochimie

Publications associées (32)

Ozone concentration measured during the Arctic Ocean 2018 expedition

Julia Schmale, Andrea Baccarini

Ozone was measured with a 2B Technology ozone monitor (model 205). The concentration is reported as a mixing ratio in parts per billion [ppb], at 60 seconds average. Ozone is a trace gas that can be formed directly in the troposphere (the most important fo ...

2020

Mixed scalar-current bootstrap in three dimensions

Alessandro Vichi, Marten Jan Reehorst

We study the mixed system of correlation functions involving a scalar field charged under a global U(1) symmetry and the associated conserved spin-1 current J(mu). Using numerical bootstrap techniques we obtain bounds on new observables not accessible in t ...

Springer Nature2020

A general framework for non-exponential delayed fluorescence and phosphorescence decay analysis, illustrated on Protoporphyrin IX

Georges Wagnières, Jaroslava Joniová, Emmanuel Louis Arthur Gerelli, Aurelien Stephen Arnaud Gregor

Delayed fluorescence (DF) is a long-lived luminescence process used in a variety of applications ranging from oxygen sensing in biological tissues to organic Light Emitting Diodes. In common cases, DF results from the deexcitation of the first excited trip ...

2020

Z-Selective Synthesis of Vinyl Boronates through Fe-Catalyzed Alkyl Radical Addition

Xile Hu, Guido Barzanò, Alexis Baptiste Cheseaux

Z-Selective synthesis of vinyl boronates is challenging. This work describes Fe-catalyzed addition of alkyl radicals, formed by the corresponding alkyl halides, to ethynyl ethynylboronic acid pinacol ester that gives rise to Z-vinyl boronates in high stere ...

2019

Standard ion transfer potential at the water|butyronitrile interface

Hubert Girault, Astrid Johana Olaya Avendano, Victor Costa Bassetto, Julieta Soledad Riva

Butyronitrile is an organic solvent stable enough to be used in photochemical reactions at liquid/liquid interfaces. However, it provides a rather short polarisation window making the analysis of ion transfer across the water|butyronitrile interface challe ...

2019

Effects of Ozone on the Photochemical and Photophysical Properties of Dissolved Organic Matter

Urs von Gunten, Frank Jonathan Leresche

This study focused on the effects of ozonation on the photochemical and photophysical properties of dissolved organic matter (DOM). Upon ozonation, a decrease in DOM absorbance was observed in parallel with an increase in singlet oxygen (O-1(2)) and fluore ...

AMER CHEMICAL SOC2019

Directly Photoexcited Oxides for Photoelectrochemical Water Splitting

Ulf Anders Hagfeldt, Nikolaos Vlachopoulos, Linfeng Pan

Artificial photosynthesis promises to become a sustainable way to harvest solar energy and store it in chemical fuels by means of photoelectrochemical (PEC) cells. Although it is intriguing to shift the fossil-fuel-based economy to a renewable carbon-neutr ...

WILEY-V C H VERLAG GMBH2019

Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu ...

2018

Efficient intersystem crossing in 2-aminopurine riboside probed by femtosecond time-resolved transient vibrational absorption spectroscopy

Rebecca Ann Ingle, Hugo Jean Baptiste Marroux

The photophysical dynamics of 2-aminopurine riboside (2APr) in CHCl3 have been studied following excitation at (pump) = 310 nm by means of femtosecond transient vibrational absorption spectroscopy (TVAS) aided by quantum chemical density functional theory ...

ROYAL SOC CHEMISTRY2018

Heptacoordinate Co-II Complex: A New Architecture for Photochemical Hydrogen Production

Euro Solari, Albert Ruggi

The first heptacoordinate cobalt catalyst for light-driven hydrogen production in water has been synthesized and characterized. Photochemical experiments using Ru(bpy)(3) as photosensitizer gave a turnover number (TON) of 16300molH(2)(molcat.)(-1) ac ...

Wiley-V C H Verlag Gmbh2017

Synthesis and Characterization of High-Photoactivity Electrodeposited Cu2O solar absorber by photoelectrochemistry and ultrafast spectroscopy

Michael Graetzel, Jacques-Edouard Moser, Jan Cornelius Brauer, Adriana Paracchino

We present a systematic study on the effects of electrodeposition parameters on the photoelectrochemical properties of Cu2O. The influence of deposition variables (temperature, pH, and deposition current density) on conductivity has been widely explored in ...

2012

Phototransformation of Acesulfame K in surface waters: Comparison of two techniques for the measurement of the second-order rate constants of indirect photodegradation, and modelling of photoreaction kinetics

Stefanos Giannakis

By use of photochemical modelling we show that acesulfame K (ACE) can undergo photodegradation in surface waters, mainly by reaction with (OH)-O-center dot and possibly (CDOM)-C-3* (the triplet states of chromophoric dissolved organic matter). With the pos ...

Elsevier2017