Publications associées à Laminar flow reactor

Revisiting the Impact of Morphology and Oxidation State of Cu on CO2 Reduction Using Electrochemical Flow Cell

Michael Graetzel, Shaik Mohammed Zakeeruddin, Dan Ren, Jing Gao

Electroreduction of carbon dioxide (CO2) in a flow electrolyzer represents a promising carbon-neutral technology with efficient production of valuable chemicals. In this work, the catalytic performance of polycrystalline copper (Cu), Cu2O-derived copper (O ...

AMER CHEMICAL SOC2022

Tandem effect of Ag@C@Cu catalysts enhances ethanol selectivity for electrochemical CO2 reduction in flow reactors

Andreas Züttel, Wen Luo, Liping Zhong, Thi Ha My Pham, Mo Li, Jie Zhang, Youngdon Ko, Cedric David Koolen

CO-selective metals (e.g., Ag) on Cu catalysts improve the selec-tivity of multi-carbon (C2+) products in electrochemical CO2 reduc-tion. However, the origin of the improvement remains unclear due to the convolution of tandem and interface effects. Here, A ...

ELSEVIER2022

Crossover of liquid products from electrochemical CO2 reduction through gas diffusion electrode and anion exchange membrane

Andreas Züttel, Wen Luo, Jie Zhang

We reveal that a significant amount (>30%) of the liquid products from electrochemical CO2 reduction (CO2RR) in a flow reactor can cross the gas diffusion electrode (GDE) and anion exchange membrane (AEM). Crossover of volatile products through the GDE occ ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2020

Electrochemical reconstruction of ZnO for selective reduction of CO2 to CO

Andreas Züttel, Wen Luo, Jie Zhang, Kun Zhao, Emanuele Moioli

Electrocatalytic conversion of CO2 to valuable chemicals is a highly promising route to close the carbon cycle. Herein, Zn catalysts derived from electrochemical reconstruction of ZnO materials are presented as efficient CO2-to-CO catalysts. We found that ...

2020

On isothermality in some commonly used plug flow reactors for X-ray based investigations of catalysts

Dragos-Constantin Stoian, Mark Adrian Newton

We compare two reactor setups commonly used to make operando measurements of catalyst behavior using X-rays in terms of the degree to which they may be considered to yield radial and axial isothermality. We use axial and radial Cu K-edge XANES mapping of c ...

2019

Nondiffusive transport regimes for suprathermal ions in turbulent plasmas

Ambrogio Fasoli, Ivo Furno, Paolo Ricci, Kyle Gustafson, Alexandre Dominique Bovet

The understanding of the transport of suprathermal ions in the presence of turbulence is important for fusion plasmas in the burning regime that will characterize reactors, and for space plasmas to understand the physics of particle acceleration. Here, thr ...

Amer Physical Soc2015

Kinematics of age mixing in advection-dispersion models

Andrea Rinaldo, Paolo Benettin

This paper investigates age mixing processes arising in advection-dispersion models, where large-scale travel and residence time distributions can be explicitly calculated based on the underlying velocity field. In particular, we analyze spatially integrat ...

American Geophysical Union2013

Inferences from catchment-scale tracer circulation experiments

Andrea Rinaldo, Enrico Bertuzzo

In this paper the mechanisms determining the mobilization and transport of solutes driven by rainfall through runoff pathways at catchment scales are investigated through the analysis of tracer experiments. The hydro-chemical response of a small catchment ...

Elsevier2009

Cinétique de réaction hétérogène d'importance troposphérique sur des substrats modèles et sur des aérosols

Pascal Pratte

The first part of this study consists in the investigation of the evaporation and the condensation rate of H2O in the presence of different types of ice in a low pressure flow reactor. The second part of the present work reports the study of chlorine activ ...

EPFL2006