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Concept

Physique des polymères

Publications associées (31)

Ion Adsorption Enhances Apparent Nonelectrostatic Attraction between Monomers in Polyelectrolyte Brushes

Harm-Anton Klok

Polyelectrolyte brushes are responsive to salt in the environment, and this has found broad applications in antifouling, biolubrication, and drug delivery. Salt primarily influences the conformation of the polyelectrolytes through ion adsorption. While ion ...

American Chemical Society2024

Soft Mechanochemistry of Disulfide-Crosslinked Polymer Networks

Zhao Meng

Mechanochemistry harnesses mechanical force to facilitate chemical reactions. Traditionally, the field of polymer mechanochemistry has used methods to activate chemical bonds, which use forces that are larger than those that are required to break a covalen ...

EPFL2024

Influence of structural dynamics on cell uptake investigated with single-chain polymeric nanoparticles

Francesco Stellacci, Lixia Wei, Suiyang Liao, Arthur Eliot Bouchez

Most nanoparticles' parameters affect their interactions with cells. To date, all the parameters studied are basically static (e.g., size, shape, ligands, and charge). This is unfortunate, because proteins have struc-tural dynamics that most nanoparticles ...

CELL PRESS2023

Influence of the molecular weight and physical properties of a thermoplastic polymer on its dynamic wetting behavior

Valentin Rougier

The wetting dynamics of molten thermoplastic polymers, which are known to influence the force balance of the triple line, are not understood properly despite their importance in many industrial processes. In particular, the influence of the molecular weigh ...

Elsevier2023

Effects of Electrode Design on the Melt Electrowriting of Sinusoidal Structures

Biranche Tandon

Melt electrowriting is a microscale manufacturing technique that uses polymer-based melts to create fibrous structures. An electric field is used to stabilize a continuous molten jet, which is then written onto a substrate as a microscale fiber. Herein, it ...

WILEY-V C H VERLAG GMBH2023

CONVERGENCE AND NONCONVERGENCE OF SCALED SELF-INTERACTING RANDOM WALKS TO BROWNIAN MOTION PERTURBED AT EXTREMA

Thomas Mountford

We use generalized Ray-Knight theorems, introduced by B. Toth in 1996, together with techniques developed for excited random walks as main tools for establishing positive and negative results concerning convergence of some classes of diffusively scaled sel ...

Inst Mathematical Statistics-Ims2023

Time Estimation of Polymer Translocation through Nano-Membrane

Maria-Alexandra Paun

In this paper, the charged polymer escapement phenomenon, via a little hole of nano-metric dimensions arranged in a constitutive biological membrane, is studied. We will present the case of the transport process of an ideal polymer in a 3-dimensional exten ...

MDPI2022

Electron Trap Dynamics in Polymer Light-Emitting Diodes

Frank Nüesch, Matthias Diethelm, Wei-Hsu Hu

Semiconducting polymers are being studied intensively for optoelectronic device applications, including solution-processed light-emitting diodes (PLEDs). Charge traps in polymers limit the charge transport and thus the PLED efficiency. It is firmly establi ...

WILEY-V C H VERLAG GMBH2022

De Novo Crystal Structure Determination from Machine Learned Chemical Shifts

David Lyndon Emsley, Manuel Cordova, Albert Hofstetter, Martins Balodis

Determination of the three-dimensional atomic-level structure of powdered solids is one of the key goals in current chemistry. Solid-state NMR chemical shifts can be used to solve this problem, but they are limited by the high computational cost associated ...

2022

Statistical potentials from the Gaussian scaling behaviour of chain fragments buried within protein globules

Stefano Zamuner

Knowledge-based approaches use the statistics collected from protein data-bank structures to estimate effective interaction potentials between amino acid pairs. Empirical relations are typically employed that are based on the crucial choice of a reference ...

PUBLIC LIBRARY SCIENCE2022

Static and dynamic mechanical properties of nanosilica and multiwalled carbon nanotube reinforced acrylonitrile butadiene styrene composites: theoretical mechanism of nanofiller reinforcement

Thomas Keller

Experimental and theoretical approaches were employed to analyze the static and dynamic mechanical properties of acrylonitrile butadiene styrene (ABS) nanocomposites reinforced with multiwalled carbon nanotube (MWCNT) and nanosilica. Enhanced stiffness and ...

SPRINGER2021

All-polymeric transient neural probe for prolonged in-vivo electrophysiological recordings

Diego Ghezzi, Laura Ferlauto, Paola Vagni, Adele Fanelli, Elodie Geneviève Zollinger

Transient bioelectronics has grown fast, opening possibilities never thought before. In medicine, transient implantable devices are interesting because they could eliminate the risks related to surgical retrieval and reduce the chronic foreign body reactio ...

2021

Mechanical Activation of Chemical Bonds at Polymer Interfaces

Julian Nicolas Bleich

Polymer brushes are a specific class of polymer thin films in which each chain is tethered to the underlying substrate via one chain end. In sufficiently densely grafted assemblies, the individual polymer chains are forced into an extended chain conformati ...

EPFL2021

Viscoelastic behavior of suspensions of reduced graphene oxide nanoparticles in epoxy

László Forró, Yves Leterrier, Arnaud Magrez, Maryam Majidian

The viscoelastic behavior of dilute suspensions of reduced graphene oxide (RGO) nanoparticles in a liquid SU8 epoxy dissolved in gamma butyrolactone was investigated at RGO concentrations in the range from 0.16 to 1.07 vol. %. Our results revealed that the ...

AMER INST PHYSICS2021

Phase behaviour and structure of a model biomolecular condensate

Julian Charles Shillcock

Phase separation of immiscible fluids is a common phenomenon in polymer chemistry, and is recognized as an important mechanism by which cells compartmentalize their biochemical reactions. Biomolecular condensates are condensed fluid droplets in cells that ...

2020

Toward Bright Red-Emissive Carbon Dots through Controlling Interaction among Surface Emission Centers

Nikita Tepliakov

Relatively weak red photoluminescence of carbon dots (CDots) is a major challenge on the way to their successful implementation in biological and optoelectronic devices. We present a theoretical analysis of the interaction among the surface emission center ...

2020

Modular soft robotic microdevices for dexterous biomanipulation

Francesco Stellacci, Mahmut Selman Sakar, Ahmet Bekdemir, Murat Kaynak, Ece Özelçi, Berna Ayse Özkale Edelmann, Lucio Feo Pancaldi-Giubbini, Raquel Filipa Penacho Parreira

We present a methodology for building biologically inspired, soft microelectromechanical systems (MEMS) devices. Our strategy combines several advanced techniques including programmable colloidal self-assembly, light-harvesting with plasmonic nanotransduce ...

2019

Composition containing a polymer and an additive

John Christopher Plummer, Holger Frauenrath, Daniel Görl

The invention describes a composition containing a) a functionalized polymer (10) that comprises at least one polymer segment (13) and at least two polymer aggregating segments (11,12) capable of forming non-covalent bonds based on a supramolecular interac ...

2019

Ultraviolet Functionalization of Electrospun Scaffolds to Activate Fibrous Runways for Targeting Cell Adhesion

Silvestro Micera

A critical challenge in scaffold design for tissue engineering is recapitulating the complex biochemical patterns that regulate cell behavior in vivo. In this work, we report the adaptation of a standard sterilization methodology-UV irradiation-for pattern ...

2019

Tuning Interaction Parameters of Thermoplastic Polyurethanes in a Binary Solvent To Achieve Precise Control over Microphase Separation

Oguzhan Oguz

Thermoplastic polyurethanes (TPUs) are designed using a large variety of basic building blocks but are only synthesized in a limited number of solvent systems. Understanding the behavior of the copolymers in a selected solvent system is of particular inter ...

AMER CHEMICAL SOC2019