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Concept

Eutectique

Publications associées (28)

Phase Transformation-Induced Interfacial Debonding of Silica Inclusions in Iron

Andreas Mortensen, Alejandra Inés Slagter, David Hernandez Escobar, Julie Nathalie S Gheysen

We document that in unstressed, undeformed, samples of pure iron containing silica inclusions precipitated by melt deoxidation, the iron matrix and a small fraction of the silica inclusions are locally separated at room temperature by a void. Thermal cycli ...

Springer2023

Crystalline or amorphous? A critical evaluation of phenomenological phase selection rules

Johann Michler, Caroline Hain

In this work, we reviewed the available phase selection rules comprising atomic size and topological aspects, entropies, enthalpies, melting points, valence and itinerant electron concentrations, as well as electronegativity, and validated them using a car ...

ELSEVIER SCI LTD2023

Full Solution Process of a Near-Infrared Light-Emitting Electrochemical Cell Based on Novel Emissive Ruthenium Complexes of 1,10-Phenanthroline-Derived Ligands and a Eutectic Alloy as the Top Electrode

Mohammad Khaja Nazeeruddin

Near-infrared luminescent materials have recently received considerable attention for a large number of applications, including in solid-state lighting, as bioimaging agents, as photovoltaic cells, and in the telecommunication industry. By adding diverse e ...

AMER CHEMICAL SOC2023

Elastocapillary menisci mediate interaction of neighboring structures at the surface of a compliant solid

John Martin Kolinski, Lebohang Molefe

Surface stress drives long-range elastocapillary interactions at the surface of compliant solids, where it has been observed to mediate interparticle interactions and to alter the transport of liquid drops. We show that such an elastocapillary interaction ...

2023

Phase and microstructure selection in peritectic alloys under high G-V ratio

Wilfried Kurz

A new model for the case of a superposition of a phase transformation and a microstructure transition from columnar plane front to equiaxed dendritic growth for peritectic alloys is presented. This model is applied to Fe-Ni alloys where a phase transition ...

WALTER DE GRUYTER GMBH2022

Peritectic equilibrium in Fe-Co alloys

Wilfried Kurz

Recent results of directional solidification experiments with Fe-Co alloys were not consistent with the presently accepted peritectic phase diagram. Therefore, the Fe-rich part of this phase diagram was re-examined. High-temperature gradient plane front so ...

WALTER DE GRUYTER GMBH2022

Screw vs. edge dislocation strengthening in body-centered-cubic high entrophy alloys and implications for guided alloy design

William Curtin, Francesco Maresca, Carolina Baruffi

Body-centered-cubic (BCC) high entropy alloys (HEAs) can show exceptionally high strength up to high temperatures. Mechanistic theories are needed to guide alloy discovery within the immense multicomponent HEA compositional space. Here, two new theories fo ...

SPRINGER HEIDELBERG2022

Effect of post-heat treatment conditions on shape memory property in 4D printed Fe-17Mn-5Si-10Cr-4Ni shape memory alloy

Christian Leinenbach, Irene Ferretto

The influence of post-heat treatment on the microstructure and properties of 4D printed Fe-17Mn-5Si-10Cr-4Ni (wt. %) shape memory alloy (SMA) produced via a laser powder bed fusion process is investigated in this study. It is shown that heat-treatment temp ...

2022

Progress and challenges in the theory and modeling of complex concentrared alloys

William Curtin, Satish I Rao

The high atomic-scale complexity inherent in the aptly named complex concentrated alloys, or high entropy alloys, presents unique challenges in understanding (1) the structure and motion of defects that control mechanical properties and (2) the thermodynam ...

SPRINGER HEIDELBERG2022

Multiscale microshaping of functionally graded polymer-derived SiCN ceramics

Lorenz Hagelüken

Polymer-derived ceramics (PDCs) exhibit excellent properties and are compatible with many shaping techniques due to the liquid character of the preceramic polymers (PCPs). Furthermore, their properties are adjustable by modifying the precursor composition ...

EPFL2022

Numerical Model of Rapidly Solidified Droplets of Al-33 Wt Pct Cu Eutectic Growth

Michel Rappaz, Jonas Valloton

Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization (a type of drop tube). Two distinct morphologies were observed: an irregular undulated eutectic assumed to form during recalescence, followed by a regu ...

SPRINGER2022

Stiff, Strong, Tough, and Highly Stretchable Hydrogels Based on Dual Stimuli-Responsive Semicrystalline Poly(urethane–urea) Copolymers

Pascal Alexander Schouwink, Nicolas Candau, Oguzhan Oguz, Adrien Julien Demongeot

There has been a considerable interest in developing stiff, strong, tough, and highly stretchable hydrogels in various fields of science and technology including biomedical and sensing applications. However, simultaneous optimization of stiffness, strength ...

2021

Strengthening of Steel Connections in a 92-Year-Old Railway Bridge Using Prestressed CFRP Rods: Multiaxial Fatigue Design Criterion

Alain Nussbaumer, Elyas Ghafoori, Masoud Motavalli, Hossein Heydarinouri

This paper presented a new retrofit system for strengthening the stringer-to-floor-beam double-angle connections in a 92-year-old riveted railway bridge in Switzerland, using prestressed carbon fiber-reinforced polymer (CFRP) rods. The strengthening system ...

ASCE-AMER SOC CIVIL ENGINEERS2021

First principles study of the effect of hydrogen in austenitic stainless steels and high entropy alloys

William Curtin, Xiao Zhou

Hydrogen (H) embrittlement in multicomponent austenitic alloys is a serious limitation to their application in many environments. Recent experiments show that the High-Entropy Alloy (HEA) CoCrFeMnNi absorbs more H than 304 Stainless Steel but is less prone ...

2020

Measurement and prediction of the transformation strain that controls ductility and toughness in advanced steels

William Curtin, Helena Van Swygenhoven, Francesco Maresca

New-generation multi-phase martensitic steels derive their high strength from the body-centered cubic (BCC) phase and high toughness from transformation of the metastable face-centered cubic (FCC) austenite that transforms into martensite upon loading. In ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Re-entry survival analysis and ground risk assessment of space debris considering by-products generation

Pénélope Leyland, Stefano Mischler, Seong-Hyeon Park

Space debris that re-enter the Earth's atmosphere can be partially or fully ablated along the trajectory path after hitting the atmosphere layers, once these become denser (approximately below 82 km). This paper combines re-entry survival analysis to by-pr ...

2020

Solute-dislocation interactions and creep-enhanced Cu precipitation in a novel ferritic-martensitic steel

Roland Logé, Cyril Cayron

G115 steel has gained a growing interesting recently for its use in next-generation ultra-supercritical power plant applications. Due to the high densities of dislocations and lath martensite boundaries in G115 steel, interactions between solutes and dislo ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Exploring the Chemical Reactivity of Gallium Liquid Metal Nanoparticles in Galvanic Replacement

Raffaella Buonsanti, Laia Castilla Amorós, Dragos-Constantin Stoian, James Richard Pankhurst, Seyedehbehnaz Varandili

Micron/nanosized particles of liquid metals possess intriguing properties and are gaining popularity for applications in various research fields. Nevertheless, the knowledge of their chemistry is still very limited compared to that of other classes of mate ...

2020

Microfluidics of binary liquid mixtures with temperature-dependent miscibility

Esther Amstad, Stefan Guldin

Liquid-liquid microfluidic systems rely on the intricate control over the fluid properties of either miscible or immiscible mixtures. Herein, we report on the use of partially miscible binary liquid mixtures that lend their microfluidic properties from a h ...

ROYAL SOC CHEMISTRY2020

Concurrent multiscale modeling and theory of solute-strengthening for dilute and complex concentrated alloys

Shankha Nag

Under common processing conditions, both dilute and complex concentrated alloys are often realized as random alloys, with no correlation in the occupancy of lattice sites by the constituent atom types. The current thesis primary addresses two problems in r ...

EPFL2020