Investigations about the Chemistry of Tetraarylethene- and Iridium-Based Luminophores

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Metal-organic frameworks (MOFs) are a class of porous materials prepared by the self-assembly of metal ions or clusters with organic ligands. The unique characteristics of MOFs, including structural tunability, high surface areas, low densities and tailore ...

Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu ...

The development of transition metal complexes for application in light-emitting devices is currently attracting significant research interest. Among phosphorescent emitters, those involving iridium (III) complexes have proven to be exceedingly useful due t ...

The electronic and steric properties of tailored cyclopentadienyl (Cp) ligands are powerful handles to modulate the catalytic properties of their metal complexes. This requires the individual preparation, purification and storage of each ligand/metal combi ...

Obtaining light emission from silicon has been the holy grail of optoelectronics over the last few decades. One of the most common methods for obtaining light emission from silicon is to reduce it to a nanoscale structure, for example by producing porous s ...

In the search of new ligand environment for the ruthenium(II) complexes with pyridine-type ligands, we developed seven new cyclometalated ruthenium complexes with N-heterocyclic carbenes (NHCs). In a two-step procedure, we synthesized complexes with the ge ...

Here we report another surprising feature of the methylammonium metal halide material family, the phototunability of the diode response of a heterojunction made of CH3NH3PbI3 and its close relative, CH3NH3SnI3. In the dark state the device behaves as a dio ...

The photophysics and photochemistry of transition metal complexes (TMCs) has long been a hot field of interdisciplinary research. Rich metal-based redox processes, together with a high variety in electronic configurations and excited-state dynamics, have r ...

The redox chemistry of f-elements is drawing the attention of inorganic chemists due to their unusual reaction pathways. Notably low-valent f-element complexes have been shown to be able to activate small molecules such as CO2 and N2 in mild conditions. Co ...

synthesized and characterized by H-1, C-13, P-31 NMR and IR spectroscopies. The reaction of MnCl2 center dot 4H(2)O with L led to the formation of a new 3D system {MnL2Cl2}(n)center dot 34CH(3)OH (C-1). X-ray crystallographic data revealed that the ligand ...

A series of cationic iridium(III) complexes with two carbene-based cyclometalating ligands and five different NN bipyridine and 1,10-phenanthroline ancillary ligands is presented. For the first time in the frame of a rarely studied class of bis(heterole ...

Investigations about the Chemistry of Tetraarylethene- and Iridium-Based Luminophores

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Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications

Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

Phosphorescent Neutral Iridium (III) Complexes for Organic Light-Emitting Diodes

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Nanoporous silicon tubes: the role of geometry in nanostructure formation and application to light emitting diodes

Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands

Photodiode Response in a CH3NH3PbI3/CH3NH3SnI3 Heterojunction

Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers

Synthesis of molecular complexes for small molecule activation

Synthesis, structural determination, theoretical studies and catalytic activity of Mn(II) complex of N-isonicotinyl phosphoric triamide ligand

Cationic Iridium(III) Complexes with Two Carbene-Based Cyclometalating Ligands: Cis Versus Trans Isomers