Publication

Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

2018
Journal Articles

Abstract

Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu, Ho) has been studied. pH values, at which the metal ions leave the metalloporphyrin complex were established using two-phase spectrophotometric titration with potentiometric pH-control. The pH values decrease with the increase of atomic numbers of lanthanide groups, as well as with increase of 4f-electrons. The reaction of an extra ligand exchange for the hydroxide ion was studied. For Dy-, Er- and Ho-tetraphenylporphyrin complexes one particle of extra ligand coordinates with one porphyrin complex. A complex with dimeric particles can be formed for the system of Lu-tetraphenylporphyrin. Constants of the ion exchange reactions were calculated. Synopsis: The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu, Ho) has been studied. The heterophase reaction of ion-selective electrodes were calculated, as well as the reaction of an extra ligand exchange for the hydroxide ion. (C) 2017 Published by Elsevier B.V.

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https://infoscience.epfl.ch/entities/publication/2b266e4a-3940-40fa-84d3-32f49f670850

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2018
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/2b266e4a-3940-40fa-84d3-32f49f670850

About this result

Related concepts (32)

Porphyrin

Porphyrins (ˈpɔːrfərɪn ) are a group of heterocyclic macrocycle organic compounds, composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges (=CH−). In vertebrates, an essential member of the porphyrin group is heme, which is a component of hemoproteins, whose functions include carrying oxygen in the bloodstream. In plants, an essential porphyrin derivative is chlorophyll, which is involved in light-harvesting and electron transfer in photosynthesis.

Heavy metals

Heavy metals are generally defined as metals with relatively high densities, atomic weights, or atomic numbers. The criteria used, and whether metalloids are included, vary depending on the author and context. In metallurgy, for example, a heavy metal may be defined on the basis of density, whereas in physics the distinguishing criterion might be atomic number, while a chemist would likely be more concerned with chemical behaviour. More specific definitions have been published, none of which have been widely accepted.

Lanthanide

The lanthanide (ˈlænθənaɪd) or lanthanoid (ˈlænθənɔɪd) series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare-earth elements or rare-earth metals. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide.

Related publications (32)

Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

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