Synthesis, Characterization, and Dielectric Properties of Phthalocyanines with Ester and Carboxylic Acid Functionalities

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Nonlinear electro-mechanical coupling and thermally stimulated currents in relaxor ferroelectrics

Lukas Riemer

In this work, the emergence of polarization and electro-mechanical coupling in Pb(Mg1/3Nb2/3)O3 and Pb(Mg1/3Nb2/3)O3 â PbTiO3 was investigated by means of thermally stimulated current, and nonlinear dielectric and electro-mechanical measurements. The pre ...

EPFL2022

Ultimate Limit for Optical Losses in Gold, Revealed by Quantitative Near-Field Microscopy

Sergejs Boroviks

We report thorough measurements of surface plasmon polaritons (SPPs) running along nearly perfect air-gold interfaces formed by atomically flat surfaces of chemically synthesized gold monocrystals. By means of amplitude-and phase-resolved near-field micros ...

AMER CHEMICAL SOC2022

Solvent-Free Synthesis and Processing of Conductive Elastomer Composites for Green Dielectric Elastomer Transducers

Frank Nüesch

Stretchable electrodes are more suitable for dielectric elastomer transducers (DET) the closer the mechanical characteristics of the electrodes and elastomer are. Here, a solvent-free synthesis and processing of conductive composites with excellent electri ...

WILEY-V C H VERLAG GMBH2022

Negative Capacitance in HfO2 Gate Stack Structures With and Without Metal Interlayer

Mihai Adrian Ionescu, Igor Stolichnov, Ali Saeidi, Francesco Bellando, Matteo Cavalieri, Carlotta Gastaldi, Eamon Patrick O'Connor

In this work, we experimentally explore and compare FET gate stacks with and without an inner metal plane between a linear dielectric (SiO2) and a ferroelectric layer (Si-doped HfO2) operating in the negative capacitance (NC) regime. The use of nanosecond- ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022

Accurate and efficient band-gap predictions for metal halide perovskites at finite temperature

Alfredo Pasquarello, Patrick Gono, Thomas Bischoff, Haiyuan Wang

We develop a computationally efficient scheme to accurately determine finite-temperature band gaps for metal halide perovskites belonging to the class ABX(3) (A = Rb, Cs; B = Ge, Sn, Pb; and X = F, Cl, Br, I). First, an initial estimate of the band gap is ...

NATURE PORTFOLIO2022

Simultaneous Generation of Methyl Esters and CO in Lignin Transformation

Paul Joseph Dyson, Mingyang Liu

Lignin is an abundant renewable carbon source. Due to its complex structure, utilization of lignin is very challenging. Herein, we describe an efficient strategy for the simultaneous utilization of lignin, in which the methoxy groups in lignin react with c ...

Wiley-VCH Verlag GmbH2022

Inflight Microwave Drying Process of Micro-droplets for High Resolution 3D printing

Kwanghoon Choi

A new Additive-Manufacturing (AM) or 3D printing concept is proposed to improve the printing resolution for metal additive manufacturing in the frame of the SFA-AM project, Powder Focusing for Beam-Induced Laser 3D Printing. The project aims to transport s ...

EPFL2022

Standard-Free Quantification of Dicarboxylic Acids: Case Studies with Salt-Rich Effluents and Serum

Christian Ludwig, Daniil Salionov

The present study evaluates the ionization efficiency (IE) of linear and branched C2–C14 dicarboxylic acids (DCAs) by electrospray ionization (ESI) under different conditions. The influence of the concentration of organic modifier (MeOH); mobile phase addi ...

2022

Polysiloxanes Modified with Different Types and Contents of Polar Groups: Synthesis, Structure, and Thermal and Dielectric Properties

Holger Frauenrath, Yauhen Sheima

Polymers with high dielectric permittivity are promising for the construction of next-generation transducers and energy storage devices with improved energy density. Here, we report the synthesis, glass-transition temperature (T-g), and dielectric properti ...

American Chemical Society2021

Ag-doped As-S-Se chalcogenide glasses: a correlative study of structural and dielectrical properties

Mirjana Dimitrievska

This work is focused on investigating the effect of Ag doping on the dielectric and structural properties of the As-S-Se glass system and their suitability for potential applications in optoelectronics, such as electronic and switching components. A series ...

SPRINGER2021

Reply to the Comment on "Phase transitions, screening and dielectric response of CsPbBr3" by S. Svirskas, S. Balciunas, M. Simenas, G. Usevicius, M. Kinka, M. Velicka, D. Kubicki, M. E. Castillo, A. Karabanov, V. V. Shvartsman, M. R. Soares, V. Sablinskas, A. N. Salak, D. C. Lupascu and J. Banys, J. Mater. Chem. A, 2020, 8, 14015

Dominik Józef Kubicki

In this reply, we address the concerns that were raised about our paper on CsPbBr3 single crystals. M. Szafranski criticized the dielectric and DSC data in our original paper claiming that they were affected by the experimental artefacts or poor quality of ...

Royal Society of Chemistry2021