Publication

Azidation of beta-Keto Esters and Silyl Enol Ethers with a Benziodoxole Reagent

Jérôme Waser, Maria Victoria Vita
2013
Journal Articles

Abstract

The efficient azidation of beta-keto esters and silyl enol ethers using a benziodoxole-derived azide transfer reagent is reported. The azidation of cyclic beta-keto esters could be achieved in up to quantitative yields in the absence of any catalyst. In the case of less reactive linear beta-keto esters and silyl enol ethers, complete conversion and good yields could be obtained by using a zinc catalyst.

Official source

https://infoscience.epfl.ch/entities/publication/ed52af6b-abd8-484e-abdb-4a00a4e7e64a

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Azidation of beta-Keto Esters and Silyl Enol Ethers with a Benziodoxole Reagent

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