Publication

Synthesis of Four-Membered BN3 Heterocycles by the Borylation of Triazenes

Rosario Scopelliti, Kay Severin, Abdusalom Suleymanov
2022
Journal Articles

Abstract

Borylated triazenes were synthesized by the dehydrocoupling of triazenes with 9-borabicyclo(3.3.1)nonane, by the condensation of triazenes with BEt3, or by the reaction of sodium triazenides with dialkyl- or diarylboron halides. The structures of the products were found to depend on the size of the substituents. Sterically demanding mesityl groups at boron or nitrogen gave rise to open-chain structures, whereas smaller substituents led to the formation of novel BN3 heterocycles.

Official source

https://infoscience.epfl.ch/entities/publication/db97aa6c-4aa6-4a2c-9096-5b06b36ef34b

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Synthesis of Four-Membered BN3 Heterocycles by the Borylation of Triazenes

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