Publication

Solid-state carbon-13 NMR and computational characterization of the N719 ruthenium sensitizer adsorbed on TiO2 nanoparticles

Michael Graetzel, Geoffrey Bodenhausen, Diego Carnevale, Julien Edouard Frey, Nicola Salvi
2014
Journal Articles

Abstract

The ruthenium-containing sensitizing dye N719 grafted on TiO2 nanoparticles was investigated by solidstate NMR. The carbon resonances are assigned by means of 13C cross-polarized dipolar dephasing experiments. DFT calculations of the carbon magnetic shielding tensors accurately describe the changes in chemical shifts observed upon grafting onto a titania surface via one or two carboxylic functions in the plane defined by the two isothiocyanate groups

Official source

https://infoscience.epfl.ch/entities/publication/ce161aa2-c489-4f2e-9682-ebb76e6f7b41

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Solid-state carbon-13 NMR and computational characterization of the N719 ruthenium sensitizer adsorbed on TiO2 nanoparticles

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