Wacker Oxidation of Trisubstituted Alkenes: Pd(II)‐Catalyzed Oxidative Ring Expansion of Exocyclic <i>α,β</i>‐Unsaturated Carbonyl to 2‐Fluoro‐1,3‐Dicarbonyl Compounds
In situ investigation of the surface composition of catalyst particles improves the understanding of the active species in heterogeneous catalysis. This study analyzed the surface chemistry of ruthenium nanoparticles supported on alumina during CO2 methana ...
In this work, for the first time, naphthalene (NA)-based polymers were synthesized by one-stage Friedel-Crafts crosslinking. The influence of NA functionalization by -OH, -SO3H, and -NO2 groups on the polymers' porosity and distribution of the catalyticall ...
The effect of water on the kinetics of oxymethylene dimethyl ether (OME) synthesis from dimethoxymethane (OME1) and trioxane (TRI) has been investigated in a combined kinetic and in situ infrared spectroscopy study. The kinetic study revealed that a water ...
The influence of phosphane "arm-on, arm-off" assocn./dissocn. in rhodium catalyzed alkene hydrogenation using [Rh(COD)(k3-triphos)]PF6 {1, COD = cyclooctadiene, triphos = 1,1,1-tris(diphenylphosphanylmethyl)ethane} has been investigated by comparison of th ...
