Publication

Kinetic isotope effects for fast deuterium and proton exchange rates

Geoffrey Bodenhausen, Philippe Pelupessy, Daniele Mammoli, Estel Canet Martinez, Pavel Kaderavek
2016
Journal Articles

Abstract

By monitoring the effect of deuterium decoupling on the decay of transverse N-15 magnetization in D-N-15 spin pairs during multiple-refocusing echo sequences, we have determined fast D-D exchange rates k(D) and compared them with fast H-H exchange rates k(H) in tryptophan to determine the kinetic isotope effect as a function of pH and temperature.

Official source

https://infoscience.epfl.ch/entities/publication/cb0cccd9-d064-4ddc-8531-f6d9f2474e83

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Kinetic isotope effects for fast deuterium and proton exchange rates

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