Synthetic chemistry with nitrous oxide and triazenes

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A supramolecular receptor for short‐chain perfluoroalkyl carboxylates was developed. The receptor displays a cage‐like geometry, with a defined binding site for the carboxylate head groups and an opening for the perfluoroalkyl side chains. The anionic gues ...

Catalytic hydrogen combustion (CHC) plays a crucial role in enhancing the safety and efficiency of fuel cells and electrolysers, thereby promoting the H2 economy. To increase the catalytic activity of supported metal particles for CHC, the active surface a ...

In contrast to the well-studied 1-vinylcyclobu- tanols, the reactivity of 3-vinylazetidin-3-ols 1 and 3- vinyloxetan-3-ols 2 under transition metal catalysis remains largely unexplored. We report herein their unique reactivity under dual palladium and acid ...

This research aims to compare the greenhouse gas (GHG) emissions of new neighbourhood projects near the Rhône River in France and Switzerland. The study considers the influence of the river on energy demand and resilience to climate change of 12 project-ba ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Redox reactions underlie several biogeochemical processes and are typically spatiotemporally heterogeneous in soils and sediments. However, redox heterogeneity has yet to be incorporated into mainstream conceptualizations and modeling of soil biogeochemist ...

Chiral carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds are pervasive and very essential in natural products, bioactive molecules, and functional materials, and their catalytic construction has emerged as one of the hottest research fields in syntheti ...

The alkyne motif is a versatile functional group often encountered in organic chemistry. It can be involved in various transformations such as the alkyne-azide cycloaddition and has found widespread application in medicinal chemistry, chemical biology and ...

The construction industry plays a major role in the high levels of greenhouse gas emissions, resource consumption, and waste generation observed nowadays. Key to the circular economy, structural component reuse arises as a promising solution to divert cons ...

Isoprene is a key trace component of the atmosphere emitted by vegetation and other organisms. It is highly reactive and can impact atmospheric composition and climate by affecting the greenhouse gases ozone and methane and secondary organic aerosol format ...

Curcuminoids and their complexes continue to attract attention in medicinal chemistry, but little attention has been given to their metabolic derivatives. Here, the first examples of (arene)Ru(II) complexes with curcuminoid metabolites, tetrahydrocurcumin ...

This study addresses the critical need for sustainable architectural designs within the context of climate change and the significant role the built environment plays in greenhouse gas emissions. The focus of this paper is on understanding the influence of ...

The production of aluminium largely depends on the use of fossil fuels, resulting in the emission of significant amounts of greenhouse gases. As the aluminium industry is working towards decreasing its environmental burdens, the elimination of direct emiss ...

Organic solvents are ubiquitous in industrial and domestic applications from the production of pharmaceuticals to household consumer products. The negative impact of most traditional solvents, especially aprotic types, on the environment, health, and safet ...

The development of Ultra-High Performance Fibre-Reinforced Cementitious Composite (UHPFRC) has enabled the design of lightweight constructions. Although the greenhouse gas emissions of UHPFRC per volume are higher than that of conventional concr ...

Frustrated Lewis pairs (FLPs), featuring reactive combinations of Lewis acids and Lewis bases, have been utilized for myriad metal-free homogeneous catalytic processes. Immobilizing the active Lewis sites to a solid support, especially to porous scaffolds, ...

Bicyclic carbocycles containing a high fraction of Csp3 have become highly attractive synthetic targets because of the multiple applications they have found in medicinal chemistry. The formal cycloaddition of bicyclobutanes (BCBs) with two- or three-atom p ...

Macrocycles provide an attractive modality for drug development but the identification of ligands to targets of interest is hindered by the lack of large macrocyclic compound libraries for high-throughput screening. A strategy to efficiently synthesize lar ...

Nanocluster aerosols (NCAs,

The constant urge to construct new molecules in an economical and sustainable fashion led to the development of numerous metal-catalyzed transformations. Organocatalysts consisting of abundant and more sustainable elements offer an elegant solution to over ...

Synthetic chemistry with nitrous oxide and triazenes

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Selective Recognition and Extraction of Short‐Chain Perfluoroalkyl Carboxylates by a Supramolecular Receptor

Engineering Ru Nanoparticle Size and Metal-support Interactions for Enhanced Catalytic Hydrogen Combustion

Arylative Ring Expansion of 3-Vinylazetidin-3-Ols and 3-Vinyloxetan-3-Ols to Dihydrofurans by Dual Palladium and Acid Catalysis

The Effect of Rivers on Energy Balance at the Neighborhood Scale. A comparative analysis of four Rhodanian sites in France and Switzerland

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

X-ray chemical imaging for assessing redox microsites within soils and sediments

Recent advances in Rh(I)-catalyzed enantioselective C-H functionalization

Novel Alkynylation Methods through the Combination of Hypervalent Iodine Reagents and Alkynyl-trifluoroborate Salts

RE:SLAB — a load bearing system for open-ended component reuse in building structures

Atmospheric isoprene measurements reveal larger-than-expected Southern Ocean emissions

Ru(II)-Arene Complexes of Curcumin and Bisdesmethoxycurcumin Metabolites

Embodied Carbon Premium for Cantilevers

CO2 Capture and Management Strategies for Decarbonizing Secondary Aluminium Production

Development of Sustainable Carbohydrate-Based Solvents by Acetal Functionalisation of Biomass

Methods to assess the carbon footprint of structures involving UHPFRC elements

Engineering Frustrated Lewis Pair Active Sites in Porous Organic Scaffolds for Catalytic CO2 Hydrogenation

Lewis acid catalyzed [4+2] annulation of bicyclobutanes with dienol ethers for the synthesis of bicyclo[4.1.1]octanes

Methods for high-throughput synthesis and screening of peptide libraries

Nanocluster Aerosols from Ozone-Human Chemistry Are Dominated by Squalene-Ozone Reactions

New Applications of 1,3,2-Diazaphospholenes in Catalysis