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A strategy based on the use of ligand steric hindrance and metal doping is reported for the design and synthesis of near-infrared (NIR) emitting lanthanide-based metal-organic frameworks (MOFs). The lanthanide ions are free of coordinated solvents, and the resulting NIR-MOFs are highly emissive and exhibit long luminescence lifetimes.
David Lyndon Emsley, Marinella Mazzanti, Anne-Sophie Chauvin, Gabriele Stevanato, Yu Rao, Amrit Venkatesh, Chad Thomas Palumbo, Megan Renee Keener