Under the Pd(II)/Pd(IV) catalytic cycle, the cyclization of pent-4-en-1-amine derivatives typically yields either pyrrolidines or piperidines depending on the N-protecting group. We report herein an unprecedented Pd(II)-catalyzed oxidative domino process t ...
Solar hydrogen production with semiconductor photocatalyst particles typically requires co-catalysts to accelerate the hydrogen evolution reaction, but since co-catalysts are often deposited in situ, the rate of their nucleation/growth and role in parasiti ...
Motivated by the need to perform large-scale kinetic Monte Carlo (KMC) simulations, in the context of unravelling complex phenomena such as catalyst reconstruction and pattern formation, we extend the work of Ravipati et al. [S. Ravipati, G. D. Savva, I.-A ...
Supported palladium catalysts are the most active ones toward the complete oxidation of methane. However, the presence of relevant amounts of water hinders the catalytic activity and long-term stability, due to competition between methane and water for the ...
Catalytic reduction of oximes represents a direct efficient approach to synthesize valuable hydroxylamine derivatives. However this transformation presents significant challenges: oximes are hard to reduce and, if reactive, reductive cleavage of the weak N ...
