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Two unsymmetrical Zn(II) phthalocyanines 1 and 2 bearing an anchoring carboxylic function linked to the phthalocyanine ring through different rigid arylenevinylene bridges have been designed for dye-sensitized solar cell (DSSC) applications. The phthalocyanines 1 and 2, when anchored onto nanocrystalline TiO2 films, yielded 30% incident monochromatic photon-to-current conversion efficiency (IPCE) and 2% power conversion efficiencies under AM1.5 sun.
Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer
Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra