Publication

Cloth catalysts in water denitrification. II. Removal of nitrates using Pd-Cu supported on glass fibers

Albert Renken, Lioubov Kiwi
2001
Journal Articles

Abstract

The use of glass fibers in the form of woven cloth (GFC), as a new type of catalytic support, was studied for the reduction of aqueous nitrate solutions using a Pd/Cu–GFC catalyst. The activity (per gram Pd) and selectivity to nitrogen were found to be comparable with those found for Pd–Cu catalysts supported on the other carriers. The maximal initial removal activity was found for a catalyst with a Pd/(Pd+Cu) ratio of 0.81. The corresponding activity was 0.7 mmol min-1 (gPd)-1, and the selectivity was 97 mol% at 25°C and pH 6.5 for initial nitrate concentration of 100 mg l-1. The selectivity to nitrogen declined at high conversions of nitrate and high pH.

Official source

https://infoscience.epfl.ch/entities/publication/a8125d77-e991-4f9c-97fe-68dfdaa41ef9

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Albert Renken, Lioubov Kiwi
2001
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/a8125d77-e991-4f9c-97fe-68dfdaa41ef9

About this result

Related concepts (32)

Nitrate

Nitrate is a polyatomic ion with the chemical formula NO3−. Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate. The ion is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a formal charge of −1.

In chemistry, pH (piːˈeɪtʃ ), also referred to as acidity, historically denotes "potential of hydrogen" (or "power of hydrogen"). It is a scale used to specify the acidity or basicity of an aqueous solution. Acidic solutions (solutions with higher concentrations of hydrogen () ions) are measured to have lower pH values than basic or alkaline solutions. The pH scale is logarithmic and inversely indicates the activity of hydrogen ions in the solution. where [H+] is the equilibrium molar concentration (mol/L) of H+ in the solution.

Nitrogen cycle

The nitrogen cycle is the biogeochemical cycle by which nitrogen is converted into multiple chemical forms as it circulates among atmospheric, terrestrial, and marine ecosystems. The conversion of nitrogen can be carried out through both biological and physical processes. Important processes in the nitrogen cycle include fixation, ammonification, nitrification, and denitrification. The majority of Earth's atmosphere (78%) is atmospheric nitrogen, making it the largest source of nitrogen.

Related publications (2)

Cloth catalysts in water denitrification. II. Removal of nitrates using Pd-Cu supported on glass fibers

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