Gibbs measureIn mathematics, the Gibbs measure, named after Josiah Willard Gibbs, is a probability measure frequently seen in many problems of probability theory and statistical mechanics. It is a generalization of the canonical ensemble to infinite systems. The canonical ensemble gives the probability of the system X being in state x (equivalently, of the random variable X having value x) as Here, E is a function from the space of states to the real numbers; in physics applications, E(x) is interpreted as the energy of the configuration x.
Gibbs free energyIn thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure-volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as where p is pressure, T is the temperature, U is the internal energy, V is volume, H is the enthalpy, and S is the entropy.
Helmholtz free energyIn thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process in which temperature is held constant. At constant temperature, the Helmholtz free energy is minimized at equilibrium.
Thermodynamic free energyIn thermodynamics, the thermodynamic free energy is one of the state functions of a thermodynamic system (the others being internal energy, enthalpy, entropy, etc.). The change in the free energy is the maximum amount of work that the system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point.
Large deviations theoryIn probability theory, the theory of large deviations concerns the asymptotic behaviour of remote tails of sequences of probability distributions. While some basic ideas of the theory can be traced to Laplace, the formalization started with insurance mathematics, namely ruin theory with Cramér and Lundberg. A unified formalization of large deviation theory was developed in 1966, in a paper by Varadhan. Large deviations theory formalizes the heuristic ideas of concentration of measures and widely generalizes the notion of convergence of probability measures.
Partition function (statistical mechanics)In physics, a partition function describes the statistical properties of a system in thermodynamic equilibrium. Partition functions are functions of the thermodynamic state variables, such as the temperature and volume. Most of the aggregate thermodynamic variables of the system, such as the total energy, free energy, entropy, and pressure, can be expressed in terms of the partition function or its derivatives. The partition function is dimensionless.
Partition function (mathematics)The partition function or configuration integral, as used in probability theory, information theory and dynamical systems, is a generalization of the definition of a partition function in statistical mechanics. It is a special case of a normalizing constant in probability theory, for the Boltzmann distribution. The partition function occurs in many problems of probability theory because, in situations where there is a natural symmetry, its associated probability measure, the Gibbs measure, has the Markov property.
Quantum trivialityIn a quantum field theory, charge screening can restrict the value of the observable "renormalized" charge of a classical theory. If the only resulting value of the renormalized charge is zero, the theory is said to be "trivial" or noninteracting. Thus, surprisingly, a classical theory that appears to describe interacting particles can, when realized as a quantum field theory, become a "trivial" theory of noninteracting free particles. This phenomenon is referred to as quantum triviality.
Gibbs phenomenonIn mathematics, the Gibbs phenomenon is the oscillatory behavior of the Fourier series of a piecewise continuously differentiable periodic function around a jump discontinuity. The th partial Fourier series of the function (formed by summing the lowest constituent sinusoids of the Fourier series of the function) produces large peaks around the jump which overshoot and undershoot the function values.
InfinityInfinity is something which is boundless, endless, or larger than any natural number. It is often denoted by the infinity symbol . Since the time of the ancient Greeks, the philosophical nature of infinity was the subject of many discussions among philosophers. In the 17th century, with the introduction of the infinity symbol and the infinitesimal calculus, mathematicians began to work with infinite series and what some mathematicians (including l'Hôpital and Bernoulli) regarded as infinitely small quantities, but infinity continued to be associated with endless processes.
Asymptotic freedomIn quantum field theory, asymptotic freedom is a property of some gauge theories that causes interactions between particles to become asymptotically weaker as the energy scale increases and the corresponding length scale decreases. (Alternatively, and perhaps contrarily, in applying an S-matrix, asymptotically free refers to free particles states in the distant past or the distant future.) Asymptotic freedom is a feature of quantum chromodynamics (QCD), the quantum field theory of the strong interaction between quarks and gluons, the fundamental constituents of nuclear matter.
Rate functionIn mathematics — specifically, in large deviations theory — a rate function is a function used to quantify the probabilities of rare events. Such functions are used to formulate large deviation principle. A large deviation principle quantifies the asymptotic probability of rare events for a sequence of probabilities. A rate function is also called a Cramér function, after the Swedish probabilist Harald Cramér. Rate function An extended real-valued function I : X → [0, +∞] defined on a Hausdorff topological space X is said to be a rate function if it is not identically +∞ and is lower semi-continuous, i.
Asymptotic analysisIn mathematical analysis, asymptotic analysis, also known as asymptotics, is a method of describing limiting behavior. As an illustration, suppose that we are interested in the properties of a function f (n) as n becomes very large. If f(n) = n2 + 3n, then as n becomes very large, the term 3n becomes insignificant compared to n2. The function f(n) is said to be "asymptotically equivalent to n2, as n → ∞". This is often written symbolically as f (n) ~ n2, which is read as "f(n) is asymptotic to n2".
Dirac delta functionIn mathematical physics, the Dirac delta distribution (δ distribution), also known as the unit impulse, is a generalized function or distribution over the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire real line is equal to one. The current understanding of the unit impulse is as a linear functional that maps every continuous function (e.g., ) to its value at zero of its domain (), or as the weak limit of a sequence of bump functions (e.g.
Dynamical systemIn mathematics, a dynamical system is a system in which a function describes the time dependence of a point in an ambient space, such as in a parametric curve. Examples include the mathematical models that describe the swinging of a clock pendulum, the flow of water in a pipe, the random motion of particles in the air, and the number of fish each springtime in a lake. The most general definition unifies several concepts in mathematics such as ordinary differential equations and ergodic theory by allowing different choices of the space and how time is measured.
Standard deviationIn statistics, the standard deviation is a measure of the amount of variation or dispersion of a set of values. A low standard deviation indicates that the values tend to be close to the mean (also called the expected value) of the set, while a high standard deviation indicates that the values are spread out over a wider range. Standard deviation may be abbreviated SD, and is most commonly represented in mathematical texts and equations by the lower case Greek letter σ (sigma), for the population standard deviation, or the Latin letter s, for the sample standard deviation.
Lattice gauge theoryIn physics, lattice gauge theory is the study of gauge theories on a spacetime that has been discretized into a lattice. Gauge theories are important in particle physics, and include the prevailing theories of elementary particles: quantum electrodynamics, quantum chromodynamics (QCD) and particle physics' Standard Model. Non-perturbative gauge theory calculations in continuous spacetime formally involve evaluating an infinite-dimensional path integral, which is computationally intractable.
Partition function (quantum field theory)In quantum field theory, partition functions are generating functionals for correlation functions, making them key objects of study in the path integral formalism. They are the imaginary time versions of statistical mechanics partition functions, giving rise to a close connection between these two areas of physics. Partition functions can rarely be solved for exactly, although free theories do admit such solutions. Instead, a perturbative approach is usually implemented, this being equivalent to summing over Feynman diagrams.
Partition function (number theory)In number theory, the partition function p(n) represents the number of possible partitions of a non-negative integer n. For instance, p(4) = 5 because the integer 4 has the five partitions 1 + 1 + 1 + 1, 1 + 1 + 2, 1 + 3, 2 + 2, and 4. No closed-form expression for the partition function is known, but it has both asymptotic expansions that accurately approximate it and recurrence relations by which it can be calculated exactly. It grows as an exponential function of the square root of its argument.
Quantum statistical mechanicsQuantum statistical mechanics is statistical mechanics applied to quantum mechanical systems. In quantum mechanics a statistical ensemble (probability distribution over possible quantum states) is described by a density operator S, which is a non-negative, self-adjoint, trace-class operator of trace 1 on the Hilbert space H describing the quantum system. This can be shown under various mathematical formalisms for quantum mechanics. One such formalism is provided by quantum logic.
