Publications related to Biphenylene-bridged mesostructured organosilica as a novel hybrid host material for Ln(III) (Ln = Eu, Gd, Tb, Er, Yb) ions in the presence of 2-thenoyltrifluoroacetone

Related publications (36)

Narrow‐Linewidth Emission and Weak Exciton‐Phonon Coupling in 2D Layered Germanium Halide Perovskites

The photophysical properties of low‐dimensional metal‐halide semiconductors and their tunability make them promising candidates for light‐absorbing and emitting applications. Yet, the germanium‐based halide perovskites to date lack desirable light‐emitting ...

Wiley2025

Flexible and stretchable thin-film encapsulation for chronic implantable bioelectronics

Kangling Wu

Chronic neural interfaces are vital for sustained neural communication but face challenges such as foreign body responses and encapsulation failures. Polymer-based soft interfaces offer promise for long-term use due to their softness and compliance, yet wa ...

EPFL2024

Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3

David Lyndon Emsley, Dominik Józef Kubicki, Daniel Prochowicz, Amita Ummadisingu, Albert Hofstetter

Lanthanides are versatile modulators of optoelectronic properties owing to their narrow optical emission spectra across the visible and near-infrared range. Their use in metal halide perovskites (MHPs) has recently gained prominence, although their fate in ...

Amer Chemical Soc2024

Improving the photoelectrocatalytic efficiency of CuWO4 through molybdenum for tungsten substitution and coupling with BiVO4

Kevin Sivula

A systematic investigation on the photoelectrocatalytic (PEC) performance of a series of CuW1-xMoxO4 materials with different Mo for W substitution (x = 0-0.8), successfully synthesized as single, transparent photoactive layers, allowed us to identify copp ...

Royal Soc Chemistry2024

Assessing the Charge Carrier Dynamics at Hybrid Interfaces of Organic Photoanodes for Solar Fuels

Kevin Sivula, Yongpeng Liu, Han-Hee Cho

Organic semiconductors (OSCs) have emerged as promising active layers for photoanodes to drive photoelectrochemical (PEC) oxidation reactions. Interfacing an OSC with an inorganic electron transport layer (ETL) is key to enabling both high performance and ...

Amer Chemical Soc2024

Co-deposition of hole-selective contact and absorber for improving the processability of perovskite solar cells

Mohammad Khaja Nazeeruddin, Yi Zhang

Simplifying the manufacturing processes of renewable energy technologies is crucial to lowering the barriers to commercialization. In this context, to improve the manufacturability of perovskite solar cells (PSCs), we have developed a one-step solution-coa ...

NATURE PORTFOLIO2023

Influence of triphenylamine derivatives in efficient dye-sensitized/organic solar cells

Mohammad Khaja Nazeeruddin

Dye-sensitized/organic solar cells (DS/O-SCs) have gradually improved their power conversion efficiencies (PCEs) and are now being considered for commercialization. This comprehensive review focuses on a prominent class of small organic molecules called tr ...

Royal Society of Chemistry2023

Photoelectrochemical Cell Engineering for Solar Energy Conversion

Dan Zhang

Solar energy is the most abundant energy source, harnessing solar energy holds the solution to the challenge of increasing global energy demand and reducing our dependence on fossil fuels. Photovoltaics which directly convert solar energy into electricity ...

EPFL2023

Controlled crystallization and surface engineering of mixed-halide y-CsPbI2Br inorganic perovskites via guanidinium iodide additive in air-processed perovskite solar cells

Mohammad Khaja Nazeeruddin

In this report, we demonstrate enlarged grain size (up to-3 lm) in ambient-stable black c-phase CsPbI2Br thin films through the regulated addition of guanidinium iodide (GAI) as an effective volatile additive. Nuclear magnetic resonance (NMR) and X-ray pho ...

Elsevier Sci Ltd2023

Molecular engineering of low-cost, efficient, and stable photosensitizers for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Lukas Pfeifer, Jing Gao, Marina Freitag, Zhongjin Shen

The cost, stability, and photovoltaic performance of photosensi-tizers play a key role in the commercialization of dye-sensitized solar cells (DSCs). Herein, three novel sensitizers termed ZS10, ZS11, and ZS12 are described based on the simple chemical str ...

Cell Press2023

CsPbBr3 Quantum Dots-Sensitized Mesoporous TiO2 Electron Transport Layers for High-Efficiency Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jingshan Luo, Felix Thomas Eickemeyer, Hong Zhang, Jing Gao

The carrier transport layer plays a critical role in high efficiency and stable perovskite solar cells (PSCs). Herein, CsPbBr3 quantum dots-sensitized mesoporous TiO2 (CPB-TiO2) electron transport layer for fabricating high-quality perovskite films with en ...

WILEY-V C H VERLAG GMBH2023

Synthesis and Characterization of Functionalized Spacer Cations for the Incorporation in Layered Perovskites

Simon Nussbaum

Layered hybrid organic-inorganic perovskite (LHOIP) materials are an emerging class of semiconductors endorsed as a more stable alternative compared to the more widely investigated 3D hybrid organic-inorganic halide perovskites (HOIP). Consisting of altern ...

EPFL2023

Zn3P2 as an earth-abundant photovoltaic material: from growth to device

Rajrupa Paul

The development of cost-effective and earth-abundant semiconducting materials is imperative for the sustainable deployment of photovoltaic technology. Zinc phosphide (Zn3P2) is a promising candidate for terawatt-scale electricity generation. It has a near- ...

EPFL2023

A Triethyleneglycol C-60 Mono-adduct Derivative for Efficient Electron Transport in Inverted Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Konstantina Kalliopi Armadorou

Inverted perovskite solar cells (PSCs) have attracted increasing attention in recent years owing to their low-temperature fabrication proces s. However, they suffer from a limited number of electron transport materials available with [6,6]-phenyl C-61 buty ...

WILEY-V C H VERLAG GMBH2023

Transparent Porous Conductive Substrates for Gas-Phase Photoelectrochemical Hydrogen Production

Kevin Sivula, Jun Ho Yum, Simon Nussbaum, Rebekah Anne Wells, Marina Caroline Michèle Caretti, Hannah Elizabeth Johnson, Emeline Cécile Rideau, Benjamin Goldman, Elizaveta Potapova Mensi

Gas diffusion electrodes are essential components of common fuel and electrolysis cells but are typically made from graphitic carbon or metallic materials, which do not allow light transmittance and thus limit the development of gas-phase based photoelectr ...

Wiley-V C H Verlag Gmbh2023

Transparent Liquid Crystal Hole-Transporting Material for Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Kasparas Rakstys, Jianxing Xia

Hexakis(hexyloxy)triphenylene (HAT6) discotic liquid crystal is employed as a transparent hole-transporting material (HTM) for perovskite solar cells (PSCs) and a power conversion efficiency (PCE) of 15.7% is obtained, which is the highest using HAT6 type ...

WILEY-V C H VERLAG GMBH2023

Playing Brains: The Ethical Challenges Posed by Silicon Sentience and Hybrid Intelligence in DishBrain

Georg Michael Joachim Starke

The convergence of human and artificial intelligence is currently receiving considerable scholarly attention. Much debate about the resulting Hybrid Minds focuses on the integration of artificial intelligence into the human brain through intelligent brain- ...

2023

A critical perspective for emerging ultra-thin solar cells with ultra-high power-per-weight outputs

Michael Graetzel, Essa Awadh R Alharbi, Georgios Kakavelakis

Ultrathin, solution-processed emerging solar cells with high power-per-weight (PPW) outputs demonstrate unique potential for applications where low weight, high power output, and flexibility are indispensable. The following perspective explores the literat ...

Aip Publishing2023

Isomeric imidazole functionalized bithiophene-based hole transporting materials for stable perovskite solar cells

Mohammad Khaja Nazeeruddin, Albertus Adrian Sutanto, Jianxing Xia

2,2,7,7-tetrakis(N,N-dip-methoxyphenylamine)-9,9-spirobifluorene (spiro-OMeTAD) is a popular hole-transporting material (HTM) in perovskite solar cells (PSCs), However, it suffers from high-cost and stability issues, which need to be overcome for PSC comme ...

ELSEVIER2023

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022