Surface tensionSurface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play.
HeatIn thermodynamics, heat is the thermal energy transferred between systems due to a temperature difference. In colloquial use, heat sometimes refers to thermal energy itself. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat.
Friedmann equationsThe Friedmann equations are a set of equations in physical cosmology that govern the expansion of space in homogeneous and isotropic models of the universe within the context of general relativity. They were first derived by Alexander Friedmann in 1922 from Einstein's field equations of gravitation for the Friedmann–Lemaître–Robertson–Walker metric and a perfect fluid with a given mass density ρ and pressure p. The equations for negative spatial curvature were given by Friedmann in 1924.
Heat transferHeat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species (mass transfer in the form of advection), either cold or hot, to achieve heat transfer.
Non-equilibrium thermodynamicsNon-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.
Equation of stateIn physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most modern equations of state are formulated in the Helmholtz free energy. Equations of state are useful in describing the properties of pure substances and mixtures in liquids, gases, and solid states as well as the state of matter in the interior of stars.
Finite element methodThe finite element method (FEM) is a popular method for numerically solving differential equations arising in engineering and mathematical modeling. Typical problem areas of interest include the traditional fields of structural analysis, heat transfer, fluid flow, mass transport, and electromagnetic potential. The FEM is a general numerical method for solving partial differential equations in two or three space variables (i.e., some boundary value problems).
PolyamorphismPolyamorphism is the ability of a substance to exist in several different amorphous modifications. It is analogous to the polymorphism of crystalline materials. Many amorphous substances can exist with different amorphous characteristics (e.g. polymers). However, polyamorphism requires two distinct amorphous states with a clear, discontinuous (first-order) phase transition between them. When such a transition occurs between two stable liquid states, a polyamorphic transition may also be referred to as a liquid–liquid phase transition.
Plane stressIn continuum mechanics, a material is said to be under plane stress if the stress vector is zero across a particular plane. When that situation occurs over an entire element of a structure, as is often the case for thin plates, the stress analysis is considerably simplified, as the stress state can be represented by a tensor of dimension 2 (representable as a 2×2 matrix rather than 3×3). A related notion, plane strain, is often applicable to very thick members.
Gravitational collapseGravitational collapse is the contraction of an astronomical object due to the influence of its own gravity, which tends to draw matter inward toward the center of gravity. Gravitational collapse is a fundamental mechanism for structure formation in the universe. Over time an initial, relatively smooth distribution of matter will collapse to form pockets of higher density, typically creating a hierarchy of condensed structures such as clusters of galaxies, stellar groups, stars and planets.
Equation of state (cosmology)In cosmology, the equation of state of a perfect fluid is characterized by a dimensionless number , equal to the ratio of its pressure to its energy density : It is closely related to the thermodynamic equation of state and ideal gas law. The perfect gas equation of state may be written as where is the mass density, is the particular gas constant, is the temperature and is a characteristic thermal speed of the molecules. Thus where is the speed of light, and for a "cold" gas.
EnthalpyEnthalpy ˈɛnθəlpi, a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings.
