Publications related to A Complete Picture of Cation Dynamics in Hybrid Perovskite Materials from Solid-State NMR Spectroscopy

Related publications (14)

Durable Perovskite Solar Cells with 24.5% Average Efficiency: The Role of Rigid Conjugated Core in Molecular Semiconductors

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Felix Thomas Eickemeyer

Efficient and robust n-i-p perovskite solar cells necessitate superior organic hole-transport materials with both mechanical and electronic prowess. Deciphering the structure-property relationship of these materials is crucial for practical perovskite sola ...

Wiley-V C H Verlag Gmbh2024

Linking Nanoscopic Insights to Millimetric-Devices in Formamidinium-Rich Perovskite Photovoltaics

Christophe Ballif, Aïcha Hessler-Wyser, Quentin Thomas Jeangros, Mostafa Rabie Shlaly Bahr Othman

Halide-perovskite semiconductors have a high potential for use in single-junction and tandem solar cells. Despite their unprecedented rise in power conversion efficiencies (PCEs) for photovoltaic (PV) applications, it remains unclear whether perovskite sol ...

Wiley-V C H Verlag Gmbh2024

Band Gap Renormalization at Different Symmetry Points in Perovskites

Majed Chergui, Lijie Wang

Using ultrafast broad-band transient absorption (TA) spectroscopy of photoexcited MAPbBr3 thin films with probe continua in the visible and the mid- to deep-ultraviolet (UV) ranges, we capture the ultrafast renormalization at the fundamental gap at the R s ...

Amer Chemical Soc2024

Quantification of Native Lignin Structural Features with Gel-Phase 2D-HSQC0 Reveals Lignin Structural Changes During Extraction

Jeremy Luterbacher, Stefania Bertella, Claire Laura Marion Charline Bourmaud

Our ability to study and valorize the lignin fraction of biomass is hampered by the fundamental and still unmet challenge of precisely quantifying native lignin's structural features. Here, we developed a rapid elevated-temperature H-1-C-13 Heteronuclear S ...

Wiley-VCH Verlag GmbH2024

Stabilization of FAPbI(3) with Multifunctional Alkali-Functionalized Polymer

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Hong Zhang, Jing Gao, Anurag Krishna, Masaud Hassan S Almalki

The defects located at the interfaces and grain boundaries (GBs) of perovskite films are detrimental to the photovoltaic performance and stability of perovskite solar cells. Manipulating the perovskite crystallization process and tailoring the interfaces w ...

Wiley-V C H Verlag Gmbh2023

Synthetic approaches for perovskite thin films and single-crystals

Mohammad Khaja Nazeeruddin

Halide perovskites are compelling candidates for the next generation of clean-energy-harvesting photovoltaic technologies owing to an unprecedented increase in power conversion efficiency and their low cost, facile fabrication and outstanding semiconductor ...

Royal Soc Chemistry2023

Photogenerated charge transfer in Dion-Jacobson type layered perovskite based on naphthalene diimide

Jacques-Edouard Moser, Kevin Sivula, Jun Ho Yum, Etienne Christophe Socie, Simon Nussbaum, George Cameron Fish, Nicolas Johannes Diercks

Incorporating organic semiconducting spacer cations into layered lead halide perovskite structures provides a powerful approach to mitigate the typical strong dielectric and quantum confinement effects by inducing charge-transfer between the organic and in ...

2023

Tuning 2D Perovskite Passivation: Impact of Electronic and Steric Effects on the Performance of 3D/2D Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Hiroyuki Kanda, Xiaoxin Gao, Roland Christopher Turnell-Ritson, Ümmügülsüm Günes

Surface passivation with 2D perovskites is a powerful strategy to achieve improved stability and performance in perovskite solar cells (PSCs). Various large organic cations have been successfully implemented, led by phenylethylammonium (PEA+) and its deriv ...

WILEY-V C H VERLAG GMBH2023

Article Organic-inorganic hybrid nature enables efficient and stable CsPbI3-based perovskite solar cells

Mohammad Khaja Nazeeruddin

CsPbI3-based perovskite solar cells (PSCs) have attracted intense research interest since the inorganic absorber layer has better thermal stability compared with hybrid perovskites. However, CsPbI3 suffers from structural instability due to an easily induc ...

Cell Press2023

Distributed flexibility as a cost-effective alternative to grid reinforcement

Christophe Ballif, Nicolas Würsch, Jordan Holweger, Alejandro Pena Bello, Noémie Alice Yvonne Ségolène Jeannin

The deployment of distributed photovoltaics (PV) in low-voltage networks may cause technical issues such as voltage rises, line ampacity violations, and transformer overloading for distribution system operators (DSOs). These problems may induce grid reinfo ...

ELSEVIER2023

Deuterated TEKPol Biradicals and the Spin-Diffusion Barrier in MAS DNP

David Lyndon Emsley, Dominik Józef Kubicki, Yu Rao, Amrit Venkatesh, Federico De Biasi

The sensitivity of NMR spectroscopy is considerably enhanced by dynamic nuclear polarization (DNP). In DNP polarization is transferred from unpaired electrons of a polarizing agent to nearby proton spins. In solids, this transfer is followed by the transpo ...

Wiley-VCH Verlag GmbH2023

Review of technology-specific degradation in c-Si, CdTe, CIGS, dye sensitised, organic and perovskite solar cells in photovoltaic modules: Understanding how reliability improvements in mature technologies can enhance emerging technologies

Andrew Wayne Fairbrother

A comprehensive understanding of failure modes of solar photovoltaic (PV) modules is key to extending their operational lifetime in the field. In this review, first, specific failure modes associated with mature PV technologies, such as crystalline silicon ...

WILEY2022

Conformal quantum dot-SnO2 layers as electron transporters for efficient perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Yuhang Liu, Haizhou Lu, Jaeki Jeong

Improvements to perovskite solar cells (PSCs) have focused on increasing their power conversion efficiency (PCE) and operational stability and maintaining high performance upon scale-up to module sizes. We report that replacing the commonly used mesoporous ...

American Association for the Advancement of Science2022

Status and perspectives of crystalline silicon photovoltaics in research and industry

Christophe Ballif, Franz-Josef Haug, Mathieu Gérard Boccard

Crystalline silicon (c-Si) photovoltaics has long been considered energy intensive and costly. Over the past decades, spectacular improvements along the manufacturing chain have made c-Si a low-cost source of electricity that can no longer be ignored. Over ...

2022