Publications related to Stability Assessment in Aqueous and Organic Solvents of Metal-Organic Framework PCN 333 Nanoparticles through a Combination of Physicochemical Characterization and Computational Simulations

Related publications (12)

Enhanced Solid Electrolyte Interphase Layer in Li-Ion Batteries with Fluoroethylene Carbonate Additives Evidenced by Liquid-Phase Transmission Electron Microscopy

The solid electrolyte interphase (SEI) layer is essential for battery performance and safety due to its electron insulation and Li-ion conduction. However, issues such as ongoing electrolyte decomposition and Li dendrite growth often arise. The most common ...

American Chemical Society (ACS)2025

Nano onions based on an amphiphilic Au3(pyrazolate)3 complex

Kay Severin, Farzaneh Fadaei Tirani, Atena-Bianca Solea

Multilayer vesicles with an onion-like architecture can form by self-assembly of organic amphiphiles such as dendrimers, small-molecule surfactants, and block copolymers. Thus far, there are limited reports about multilayer vesicles based on coordination c ...

ROYAL SOC CHEMISTRY2024

Electronic transport in graphene with out-of-plane disorder

Oleg Yazyev, Yifei Guan

Real-world samples of graphene often exhibit various types of out-of-plane disorder-ripples, wrinkles and folds-introduced at the stage of growth and transfer processes. These complex out-of-plane defects resulting from the interplay between self-adhesion ...

Nature Portfolio2024

3D vs. turbostratic: controlling metal-organic framework dimensionality via N-heterocyclic carbene chemistry

Emad Oveisi, Wendy Lee Queen, Mounir Driss Mensi, Mehrdad Asgari, Shuliang Yang, Ilia Kochetygov, Vikram Vinayak Karve, Till Marian Schertenleib, Anita Justin

Using azolium-based ligands for the construction of metal-organic frameworks (MOFs) is a viable strategy to immobilize catalytically active N-heterocyclic carbenes (NHC) or NHC-derived species inside MOF pores. Thus, in the present work, a novel copper MOF ...

ROYAL SOC CHEMISTRY2022

Computational Studies of the Proton-Coupled Metal Ion Transport in the SLC11/NRAMP Family of Transporters

Maria Letizia Merlini

In the last years, it has been demonstrated a link between the overload of metal ions inside nervous system cells and the onset of severe neurodegenerative diseases. This prompted the investigation of the structural and functional properties of transporter ...

EPFL2022

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Andrzej Sienkiewicz, Aurélien René Willauer

Trinuclear molecular complexes of europium (II)and ytterbium(II) [Ln3{(Ph2SiO)2O}3(THF)6],1-Ln3L3(Ln = Euand Yb), supported by the dianionic tetraphenyl disiloxanediolateligand, were synthesized via protonolysis of the [Ln{N-(SiMe3)2}2(THF)2] complexes. In ...

2022

cell2mol: encoding chemistry to interpret crystallographic data

Anne-Clémence Corminboeuf, Rubén Laplaza Solanas, Sergio Vela Llausi, Yuri Cho

The creation and maintenance of crystallographic data repositories is one of the greatest data-related achievements in chemistry. Platforms such as the Cambridge Structural Database host what is likely the most diverse collection of synthesizable molecules ...

NATURE PORTFOLIO2022

Aggregate dissolution in different pore solutions

Mahsa Bagheri

The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...

EPFL2021

Variant selection in martensitic steels

Annick Pauline Baur

The martensitic phase transformation in steel is one of the most famous solid state transformation because of its contribution in the development of the modern industry. This transformation from a face-centered cubic (FCC) high temperature phase, called th ...

EPFL2019

Micellization behavior of bile salt with pluronic (F-127) and synthesis of silver nanoparticles in a mixed system

Mohammad Khaja Nazeeruddin

The sequestrant is a substance used to cure bile salt diarrhea. They bind to bile salts by hydrophobic and electrostatic forces to stop them from contact with colon mucosa. The block copolymer could be used as bile salt binding agents. Herein, the physicoc ...

WILEY2019

Production of phosphorene nanoribbons

Vasiliki Tileli

Phosphorene is a mono-elemental, two-dimensional (2D) substance with outstanding, highly directional properties and a bandgap that depends on the number of layers of the material(1-8). Nanoribbons, meanwhile, combine the flexibility and unidirectional prop ...

NATURE PUBLISHING GROUP2019

Extrinsic Defects in Amorphous Oxides: Hydrogen, Carbon, and Nitrogen Impurities in Alumina

Alfredo Pasquarello, Francesco Ambrosio, Zhendong Guo

We present a procedure for addressing extrinsic defects in amorphous oxides, in which the most stable defect configurations are identified through ab initio molecular dynamics in various charge states and studied through hybrid functional calculations. The ...

American Physical Society (APS)2019