Publications related to Supramolecular Modulation of Hybrid Perovskite Solar Cells via Bifunctional Halogen Bonding Revealed by Two-Dimensional 19F Solid-State NMR Spectroscopy

Related publications (45)

Localized Tunneling 1D Perovskitoid Passivated Contacts for Efficient and Stable Perovskite Solar Modules

Mohammad Khaja Nazeeruddin, Yong Ding, Kai Zhang

Interface engineering has proven to be an effective approach for passivating interfacial imperfections to mitigate non-radiative recombination, but the subpar interface quality between the perovskite and the charge transport layer has hindered advancements ...

2025

Texture-enhanced Mechanical Stability of Transparent Electrodes for Flexible Optoelectronics with Near-infrared Response

Simon Baptiste Rieckhoff

Transparent electrodes with high conductivity and mechanical robustness are essential for flexible opto-electronic applications. Indium tin oxide (ITO) single layers have long been considered as unsuitable for flexible applications due to their brittleness ...

WILEY2025

Optical assessment of lignin-containing nanocellulose films under extended sunlight exposure

Tiffany Abitbol

This study investigates the stability and UV-blocking properties of cellulose nanofibril (CNF) and TEMPO-oxidized cellulose nanofibril (TOCNF) films, with and without lignin, under 1000 h of artificial sunlight. The literature to date provides no quantitat ...

SPRINGER2025

Solar photons beyond the band gap wavelengths: their effect on solution-processed solar cells

Michael Graetzel

A deep understanding of how solution-processed solar cells (SSCs) perform under varying temperatures and irradiance is crucial for their optimal design, synthesis, and use. However, current partial spectral characterization, primarily below the band gap wa ...

Royal Society of Chemistry2025

High-Efficiency Carbon Perovskite Solar Cells via Cathode Interface Engineering by using CuPc Hole-Transporting Layers

Mohammad Khaja Nazeeruddin

Carbon perovskite solar cells (C-PSCs) represent a promising photovoltaic (PV) technology that addresses the long-term operating stability needed to compete with commercial Si solar cells. However, the poor interface contacts between the carbon electrode a ...

2025

Metal Doping of Strongly Confined Halide Perovskite Nanocrystals under Ambient Conditions

Emad Oveisi, Aurélien Bornet, Pascal Alexander Schouwink, Sascha Feldmann, Tejas Deshpande, Zachary Andrew Vanorman

Halide perovskite nanocrystals are promising materials for optoelectronic applications. Metal doping provides an avenue to boost their performance further, e.g., by enhancing light emission, or to provide additional functionalities, such as nanoscale magne ...

American Chemical Society (ACS)2025

Controls of Ecohydrological Grassland Dynamics in Agrivoltaic Systems

Sara Bonetti

Agrivoltaic systems are characterized by the co-existence of photovoltaic panels on agricultural land, allowing simultaneous solar energy and food production without need for further land. Agrivoltaic installations alter the local microclimatic conditions ...

AMER GEOPHYSICAL UNION2025

Realizing Uniform Defect Passivation via Self‐Polymerization of Benzenesulfonate Molecules in Perovskite Photovoltaics

Michael Graetzel, Likai Zheng, Mingyang Wei, Xiaoqing Jiang

Realizing high‐quality perovskite films through uniform defect passivation and crystallization control is pivotal to unlocking the potential of scalable applications. However, prevalent small‐molecule additives are inherently susceptible to the crystalliza ...

Wiley2025

Optimization of hybrid sensible-latent seasonal heat storage systems

William Orlando Delgado Díaz, Sophia Haussener

This study presents a coupled techno-economic and environmental model of hybrid sensible-latent thermal energy storage (TES) systems, integrating phase change material (PCM) macro-capsules to enhance storage capacity and performance. The multi-scale model ...

2025

Formation Dynamics of Thermally Stable 1D/3D Perovskite Interfaces for High-Performance Photovoltaics

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei

Direct understanding of the formation and crystallization of low-dimensional (LD) perovskites with varying dimensionalities employing the same bulky cations can offer insights into LD perovskites and their heterostructures with 3D perovskites. In this stud ...

Wiley2025

Valence and Site Engineering Enable Efficient Broadband Near‐Infrared Emission at 960 nm in Cr3+‐Activated Forsterite

Jean-Claude Bünzli

Near‐infrared (NIR) light sources hold great potential for applications in night vision illumination, bio‐imaging, and non‐destructive testing. However, radiationless de‐activation and low absorption restrict the development of high‐efficiency blue light e ...

Wiley2025

Photo-doping of spiro-OMeTAD for highly stable and efficient perovskite solar cells

Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra, Kai Zhu

A widely used component of high-efficiency perovskite solar cells (PSCs) is the molecular hole-transport material (HTM) spiro-OMeTAD. This organic solid needs to be p-doped to acquire sufficient hole conductivity. However, the conventional doping method us ...

2024

Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal-halide perovskites

Anaël Morgane Jaffrès, Christophe Ballif, Quentin Thomas Jeangros, Aïcha Hessler-Wyser, Christian Michael Wolff, Mostafa Rabie Shlaly Bahr Othman, Daniel Anthony Jacobs, Austin George Kuba

The technique of alloying FA+ with Cs+ is often used to promote structural stabilization of the desirable alpha-FAPbI3 phase in halide perovskite devices. However, the precise mechanisms by which these alloying approaches improve the optoelectronic quality ...

Royal Soc Chemistry2024

Assessing the Influence of Illumination on Ion Conductivity in Perovskite Solar Cells

Christophe Ballif, Aïcha Hessler-Wyser, Christian Michael Wolff, Mostafa Rabie Shlaly Bahr Othman

Whether illumination influences the ion conductivity in lead-halide perovskite solar cells containing iodide halides has been an ongoing debate. Experiments to elucidate the presence of a photoconductive effect require special devices or measurement techni ...

2024

Identification and Mitigation of Degradation Mechanisms Induced by Heat and Light in NiOx-based Perovskite Solar Cells

Marion Solange Madeleine Dussouillez

Perovskite solar cells (PSCs) offer an attractive solution to increase the efficiency of PV panels via perovskite/silicon tandems thanks to their potential cost-effectiveness and high efficiency. In inverted PSC architecture (p-i-n), commonly used hole con ...

EPFL2024

Synergistic Redox Modulation for High-Performance Nickel Oxide-Based Inverted Perovskite Solar Modules

Mohammad Khaja Nazeeruddin, Bin Ding, Xianfu Zhang

Nickel oxide (NiOx)-based inverted perovskite solar cells stand as promising candidates for advancing perovskite photovoltaics towards commercialization, leveraging their remarkable stability, scalability, and cost-effectiveness. However, the interfacial r ...

Wiley2024

Influence of F-Containing Materials on Perovskite Solar Cells

Likai Zheng

Perovskite solar cells (PSCs) are usually modified and passivated to improve their performance and stability. The interface modification and bulk doping are the two basic strategies. Fluorine (F)-containing materials are highly favored because of their uni ...

2024

Cu(II) and Ni(II) Phthalocyanine-Based Hole-Transporting Materials for Stable Perovskite Solar Cells with Efficiencies Reaching 20.0%

Mohammad Khaja Nazeeruddin, Jianxing Xia

Herein, Cu(II)Pcs and Ni(II)Pcs peripherally tetra-functionalized with 5-hexylthiophene (HT), 5-hexyl-2,2 '-bithiophene (HBT), and tertbutyl groups (TB) are readily synthesized and employed as hole-transporting materials (HTMs) in mixed-ion perovskite ([FA ...

WILEY-V C H VERLAG GMBH2024

Supramolecular Modulation for Hybrid Perovskite Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Hong Zhang, Jovana Milic, Ghewa Alsabeh, Masaud Hassan S Almalki

Hybrid perovskites are emerging as top contenders in the next generation of photovoltaics, yet their stability under operational conditions remains a significant challenge. Specifically, degradation occurs at the interface with charge transport layers in p ...

2024

Stress tolerance of lightweight glass-free PV modules for vehicle integration

Kléber Nicolet-dit-Félix, Christophe Ballif, Matthieu Despeisse, Aïcha Hessler-Wyser, Jacques Levrat, Antonin Faes, Gianluca Cattaneo, Umang Bhupatrai Desai, Fahradin Mujovi

Electric vehicles (EVs) currently dominate the sales in the automotive market. A big leap in this market can be made by developing a photovoltaic product that can be integrated to an EV, as it can boost the driving range of the EV while reducing the chargi ...

Edp Sciences S A2024