Publications related to Function Follows Form: Correlation between the Growth and Local Emission of Perovskite Structures and the Performance of Solar Cells

Related publications (44)

All-perovskite tandem solar cells achieving >29% efficiency with improved (100) orientation in wide-bandgap perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Nikolaos Lempesis, Mingyang Wei, Virginia Carnevali, Lorenzo Agosta, Vladislav Slama

Monolithic all-perovskite tandem solar cells present a promising approach for exceeding the efficiency limit of single-junction solar cells. However, the substantial open-circuit voltage loss in the wide-bandgap perovskite subcell hinders further improveme ...

NATURE PORTFOLIO2025

Unraveling the Role of Electron-Withdrawing Molecules for Highly Efficient and Stable Perovskite Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingyang Wei, Likai Zheng

Electron-withdrawing molecules (EWMs) have exhibited remarkable efficacy in boosting the performance of perovskite solar cells (PSCs). However, the underneath mechanisms governing their positive attributes remain inadequately understood. Herein, we conduct ...

Wiley-VCH Verlag GmbH2025

Visualising ionic screening in perovskite solar cells: a bumpy ride along the J–V curve

Frank Nüesch

The J–V bump and hysteresis in perovskite solar cells are studied combining measurement and simulation, linking them to spatial collection efficiency changes from ionic charge accumulation, as visualised in external quantum efficiency (EQE) spectra. ...

Royal Society of Chemistry (RSC)2025

Enhancing lifetime, forecasting, and economic benefits of photovoltaic technologies undergoing UV-induced degradation with optical filtering

Christophe Ballif, Antonin Faes, Marion Solange Madeleine Dussouillez, Christian Michael Wolff

Ultraviolet-induced degradation (UV-ID) of various PV cell types was analyzed under optical UV filters with different cutoff wavelengths. Cell types studied included interdigitated back contact (IBC), passivated emitter and rear totally diffused (PERT), an ...

2025

Facile and Low-Cost Design Alternative of Spiro-OMeTAD as p-Type Semiconductor for Efficient Perovskite Solar Cells

Mohammad Khaja Nazeeruddin

A simple diphenylamine-based hole transporting material V1553 was synthesized and incorporated into a perovskite solar cell, which showed remarkable power conversion efficiency close to 23%. The investigated HTM was synthesized via one-step catalyst-free c ...

WILEY-V C H VERLAG GMBH2025

Buried SnI2 Induces Gradient Heterojunctions in Sn–Pb Perovskite Solar Cells

Chenxu Zhao

Tin–lead (Sn–Pb) mixed perovskite solar cells (PSCs) offer the potential for higher power conversion efficiency (PCE) than their pure lead counterparts. However, the lack of a well-defined Sn/Pb compositional profile results in disordered internal electric ...

American Chemical Society (ACS)2025

Machine-learning-empowered FDTD/FEM simulations for predictive solar energy absorption in plasmonic metamaterial nanocavity arrays

Amir Jafargholi

FDTD/FEM simulations, strengthened by machine learning, achieve 95.44% optical absorption efficiency in TiO 2 /TiN plasmonic nanocavities for solar energy harvesting. ...

Royal Society of Chemistry (RSC)2025

Aryl-Acetylene Layered Hybrid Perovskites in Photovoltaics

Christophe Ballif, Aïcha Hessler-Wyser, Michael Graetzel, Ursula Röthlisberger, Mostafa Rabie Shlaly Bahr Othman, Masaud Hassan S Almalki, Fatemeh Ansari, Felix Thomas Eickemeyer, Ghewa Alsabeh, Lukas Pfeifer, Christian Michael Wolff, Nikolaos Lempesis, Virginia Carnevali, Vladislav Slama, Andrea Vezzosi

Metal halide perovskites have shown exceptional potential in converting solar energy to electric power in photovoltaics, yet their application is hampered by limited operational stability. This stimulated the development of hybrid layered (two-dimensional, ...

WILEY-V C H VERLAG GMBH2025

Spiro-Phenothiazine Hole-Transporting Materials: Unlocking Stability and Scalability in Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jaeki Jeong, Likai Zheng

Improving both the efficiency and long-term stability of perovskite solar cells (PSCs) is critical for their commercial deployment. Despite the widespread use of spiro-OMeTAD as a hole-transporting material (HTM), its inhomogeneous doping behavior and susc ...

2025

Hybrid Ag-mesh/Ta-doped TiO2 thin film configuration as a visible and near-infrared transparent electrode

Andreas Schueler, Jérémy Jacques Antonin Fleury, Krishna Manwani

This study focuses on the fabrication of a hybrid Ag-mesh/Ta-doped TiO2 (TTO) electrode that has a low sheet resistance and high transparency in the visible and near-infrared region, thereby holding significant commercialization potential. Here, ∼82 nm thi ...

2025

Machine Learning for Screening Small Molecules as Passivation Materials for Enhanced Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Bin Ding, Xianfu Zhang

Utilization of small molecules as passivation materials for perovskite solar cells (PSCs) has gained significant attention recently, with hundreds of small molecules demonstrating passivation effects. In this study, a high-accuracy machine learning model i ...

Wiley-VCH Verlag Gmbh2024

Photo-doping of spiro-OMeTAD for highly stable and efficient perovskite solar cells

Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, Aaron Tomas Terpstra, George Cameron Fish, Kai Zhu

A widely used component of high-efficiency perovskite solar cells (PSCs) is the molecular hole-transport material (HTM) spiro-OMeTAD. This organic solid needs to be p-doped to acquire sufficient hole conductivity. However, the conventional doping method us ...

2024

Device Performance of Emerging Photovoltaic Materials (Version 5)

Mohammad Khaja Nazeeruddin

This 5th annual "Emerging PV Report" highlights the latest advancements in the performance of emerging photovoltaic (e-PV) devices across various e-PV research areas, as documented in peer-reviewed articles published since August 2023. Updated graphs, tabl ...

WILEY-V C H VERLAG GMBH2024

Encapsulation strategies for mechanical impact and damp heat reliability improvement of lightweight photovoltaic modules towards vehicle-integrated applications

Fabiana Lisco

Lightweight modules are essential for next-generation vehicle-integrated photovoltaic (VIPV) applications, such as solar-powered cars, allowing integration of solar cells beyond the roof, and on the hood, boot and body panels, and thereby extending the dri ...

Elsevier2024

Supramolecular interactions using β-cyclodextrin in controlling perovskite solar cell performance

Jun Ho Yum, Kevin Sivula, Jiyoun Seo, Parnian Ferdowsi

In the context of perovskite solar cells (PSCs), enhancing device performance often involves adding a small excess of lead iodide (PbI2) to the precursor solution. However, the presence of unreacted PbI2 can lead to accelerated degradation compromising lon ...

Royal Society of Chemistry2024

Elimination of buried interfacial voids for efficient perovskite solar cells

Bin Ding, Xianfu Zhang

Establishing optimal interfacial contact is crucial for enhancing the efficiency of perovskite solar cells (PSCs). However, formation of voids at buried interface of perovskite films often hinders this critical objective. Our investigation reveals that the ...

Elsevier2024

Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal-halide perovskites

Christophe Ballif, Aïcha Hessler-Wyser, Quentin Thomas Jeangros, Mostafa Rabie Shlaly Bahr Othman, Daniel Anthony Jacobs, Christian Michael Wolff, Anaël Morgane Jaffrès, Austin George Kuba

The technique of alloying FA+ with Cs+ is often used to promote structural stabilization of the desirable alpha-FAPbI3 phase in halide perovskite devices. However, the precise mechanisms by which these alloying approaches improve the optoelectronic quality ...

Royal Soc Chemistry2024

Carbazole Treated Waterproof Perovskite Films with Improved Solar Cell Performance

Michael Graetzel, Paul Joseph Dyson, Ursula Röthlisberger, Haizhou Lu, Felix Thomas Eickemeyer, Yeonju Kim, Jaeki Jeong, Lukas Pfeifer, Nikolaos Lempesis, Virginia Carnevali, Vladislav Slama

Surface passivation has been widely employed to suppress non-radiative charge recombination and prevent interfacial charge accumulation in perovskite photovoltaics. In this report, carbazole modified with ammonium iodide connected via alkyl chains of diffe ...

Wiley-V C H Verlag Gmbh2024

Identification and Mitigation of Degradation Mechanisms Induced by Heat and Light in NiOx-based Perovskite Solar Cells

Marion Solange Madeleine Dussouillez

Perovskite solar cells (PSCs) offer an attractive solution to increase the efficiency of PV panels via perovskite/silicon tandems thanks to their potential cost-effectiveness and high efficiency. In inverted PSC architecture (p-i-n), commonly used hole con ...

EPFL2024

Micro-homogeneity of lateral energy landscapes governs the performance in perovskite solar cells

Mohammad Khaja Nazeeruddin, Yong Ding

Suppression of energy disorders in the vertical direction of a photovoltaic device, along which charge carriers are forced to travel, has been extensively studied to reduce unproductive charge recombination and thus achieve high-efficiency perovskite solar ...

Nature Portfolio2024