Publications related to Determination of Thermal Expansion Coefficients and Locating the Temperature-Induced Phase Transition in Methylammonium Lead Perovskites Using X-ray Diffraction

Related publications (40)

Visualising ionic screening in perovskite solar cells: a bumpy ride along the J–V curve

The J–V bump and hysteresis in perovskite solar cells are studied combining measurement and simulation, linking them to spatial collection efficiency changes from ionic charge accumulation, as visualised in external quantum efficiency (EQE) spectra. ...

Royal Society of Chemistry (RSC)2025

Unraveling the Role of Electron-Withdrawing Molecules for Highly Efficient and Stable Perovskite Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Likai Zheng, Mingyang Wei

Electron-withdrawing molecules (EWMs) have exhibited remarkable efficacy in boosting the performance of perovskite solar cells (PSCs). However, the underneath mechanisms governing their positive attributes remain inadequately understood. Herein, we conduct ...

Wiley-VCH Verlag GmbH2025

Enhancing lifetime, forecasting, and economic benefits of photovoltaic technologies undergoing UV-induced degradation with optical filtering

Christophe Ballif, Antonin Faes, Christian Michael Wolff, Marion Solange Madeleine Dussouillez

Ultraviolet-induced degradation (UV-ID) of various PV cell types was analyzed under optical UV filters with different cutoff wavelengths. Cell types studied included interdigitated back contact (IBC), passivated emitter and rear totally diffused (PERT), an ...

2025

Facile and Low-Cost Design Alternative of Spiro-OMeTAD as p-Type Semiconductor for Efficient Perovskite Solar Cells

Mohammad Khaja Nazeeruddin

A simple diphenylamine-based hole transporting material V1553 was synthesized and incorporated into a perovskite solar cell, which showed remarkable power conversion efficiency close to 23%. The investigated HTM was synthesized via one-step catalyst-free c ...

WILEY-V C H VERLAG GMBH2025

All-perovskite tandem solar cells achieving >29% efficiency with improved (100) orientation in wide-bandgap perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Virginia Carnevali, Nikolaos Lempesis, Mingyang Wei, Vladislav Slama, Lorenzo Agosta

Monolithic all-perovskite tandem solar cells present a promising approach for exceeding the efficiency limit of single-junction solar cells. However, the substantial open-circuit voltage loss in the wide-bandgap perovskite subcell hinders further improveme ...

NATURE PORTFOLIO2025

Buried SnI2 Induces Gradient Heterojunctions in Sn–Pb Perovskite Solar Cells

Chenxu Zhao

Tin–lead (Sn–Pb) mixed perovskite solar cells (PSCs) offer the potential for higher power conversion efficiency (PCE) than their pure lead counterparts. However, the lack of a well-defined Sn/Pb compositional profile results in disordered internal electric ...

American Chemical Society (ACS)2025

Machine-learning-empowered FDTD/FEM simulations for predictive solar energy absorption in plasmonic metamaterial nanocavity arrays

Amir Jafargholi

FDTD/FEM simulations, strengthened by machine learning, achieve 95.44% optical absorption efficiency in TiO 2 /TiN plasmonic nanocavities for solar energy harvesting. ...

Royal Society of Chemistry (RSC)2025

A phase transition between positional and semantic learning in a solvable model of dot-product attention

Lenka Zdeborová, Florent Gérard Krzakala, Hugo Chao Cui, Freya Behrens

Many empirical studies have provided evidence for the emergence of algorithmic mechanisms (abilities) in the learning of language models, that lead to qualitative improvements in the model capabilities. Yet, a theoretical characterization of how such mecha ...

2025

Probing the latent hierarchical structure of data via diffusion models

Noam Itzhak Levi, Alessandro Favero, Antonio Sclocchi

High-dimensional data must be highly structured to be learnable. Although the compositional and hierarchical nature of data is often put forward to explain learnability, quantitative measurements establishing these properties are scarce. Likewise, accessin ...

2025

Structural and magnetic properties of β-Li2IrO3 after grazing-angle focused ion beam thinning

Christian Rüegg

Manipulating the size and orientation of quantum materials is often used to tune emergent phenomena, but precise control of these parameters is also necessary from an experimental point of view. Various synthesis techniques already exist, such as epitaxial ...

2025

2D Metalorganic Ferromagnets

Diego Radillo Ochoa, Céline Hensky, Christian Wäckerlin, Quy Hien Le

Low-dimensional materials exhibiting stable magnetic ordering are interesting from a fundamental point of view as well as for future application in information technologies. Metalorganic magnets, created by linking metal atoms with specific organic molecul ...

WILEY2025

Encapsulated Co–Ni alloy boosts high-temperature CO2 electroreduction

Jiaming Tian, Xile Hu, Jeremy Luterbacher, Wenhao Ren, Wenchao Ma, Seongmin Jin

Electrochemical CO 2 reduction into chemicals and fuels holds great promise for renewable energy storage and carbon recycling 1–3 . Although high-temperature CO 2 electroreduction in solid oxide electrolysis cells is industrially relevant, current catalyst ...

Springer Science and Business Media LLC2025

Hybrid Ag-mesh/Ta-doped TiO2 thin film configuration as a visible and near-infrared transparent electrode

Andreas Schueler, Jérémy Jacques Antonin Fleury, Krishna Manwani

This study focuses on the fabrication of a hybrid Ag-mesh/Ta-doped TiO2 (TTO) electrode that has a low sheet resistance and high transparency in the visible and near-infrared region, thereby holding significant commercialization potential. Here, ∼82 nm thi ...

2025

Atmospheric reactive nitrogen and its dry deposition regimes under anthropogenic influence: Insights from intensive and long-term monitoring in Switzerland

Athanasios Nenes, Andrea Baccarini, Kalliopi Violaki, Ghislain Gilles Jean-Michel Motos, Ali Waseem

Excessive nitrogen deposition from anthropogenic activities poses significant challenges to ecosystems and air quality.1 The atmospheric deposition of ammonium and nitrate plays a critical role in regulating ecosystem productivity and driving particulate m ...

2025

A comprehensive physical model for the sensitivity of silicon heterojunction photovoltaic modules to water ingress

Christophe Ballif, Alessandro Francesco Aldo Virtuani, Luca Gnocchi, Olatz Arriaga Arruti

Silicon heterojunction (SHJ)-solar modules-when encapsulated with ethylene vinyl acetate (EVA)-are known to be extremely sensitive to water ingress. The reason for this is, however, not clear. Here, we explain the root causes of this degradation mechanism ...

Cell Press2024

Microstructural and electrical characterization of high temperature passivating contacts for silicon solar cells

Sofia Libraro

Recombination at metal/semiconductor interfaces represents the main limitation in mainstream c-Si solar cells, primarily based on the passivated emitter and rear cell (PERC) concept. Full-area passivating contacts based on SiOx/poly-Si stacks are a candida ...

EPFL2024

Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal-halide perovskites

Anaël Morgane Jaffrès, Christophe Ballif, Quentin Thomas Jeangros, Aïcha Hessler-Wyser, Christian Michael Wolff, Mostafa Rabie Shlaly Bahr Othman, Daniel Anthony Jacobs, Austin George Kuba

The technique of alloying FA+ with Cs+ is often used to promote structural stabilization of the desirable alpha-FAPbI3 phase in halide perovskite devices. However, the precise mechanisms by which these alloying approaches improve the optoelectronic quality ...

Royal Soc Chemistry2024

Photo-doping of spiro-OMeTAD for highly stable and efficient perovskite solar cells

Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra, Kai Zhu

A widely used component of high-efficiency perovskite solar cells (PSCs) is the molecular hole-transport material (HTM) spiro-OMeTAD. This organic solid needs to be p-doped to acquire sufficient hole conductivity. However, the conventional doping method us ...

2024

Identification and Mitigation of Degradation Mechanisms Induced by Heat and Light in NiOx-based Perovskite Solar Cells

Marion Solange Madeleine Dussouillez

Perovskite solar cells (PSCs) offer an attractive solution to increase the efficiency of PV panels via perovskite/silicon tandems thanks to their potential cost-effectiveness and high efficiency. In inverted PSC architecture (p-i-n), commonly used hole con ...

EPFL2024

Supramolecular interactions using β-cyclodextrin in controlling perovskite solar cell performance

Parnian Ferdowsi, Kevin Sivula, Jun Ho Yum, Jiyoun Seo

In the context of perovskite solar cells (PSCs), enhancing device performance often involves adding a small excess of lead iodide (PbI2) to the precursor solution. However, the presence of unreacted PbI2 can lead to accelerated degradation compromising lon ...

Royal Society of Chemistry2024