Publication

Titanium-mediated and neighboring-group-assisted d-methylation of homoallyl alcohols: a new regio- and stereoselective carbon-carbon linking reaction

Manfred Schlosser
1982
Journal Articles

Abstract

Upon treatment with Me2TiCl2 or Me3Al in the presence of TiCl4, an H atom at the olefinic 4-position is replaced by a Me group. Terminal homoallyl alcs. afford E isomers. If the double bond is internal, the C chain (at the other side of the OH group) gives up its original position to the entering Me group and switches to the other one at the same C atom. [on SciFinder (R)]

Official source

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Titanium-mediated and neighboring-group-assisted d-methylation of homoallyl alcohols: a new regio- and stereoselective carbon-carbon linking reaction

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Theoretical Studies of the Reductive C-S Bond Cleavage in Complexes of the Form [M(9S3)2]2+ (M = Re, Tc, and Ru; 9S3 = 1,4,7-Trithiacyclononane)