Vanadium complexes with N-heterocyclic vinylidene ligands

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

This thesis is dedicated to the study of various aspects of the electronic structure of two-dimensional transition metal dichalcogenides (TMDs) of chemical composition MX

_2

(where M is a transition metal atom and X= S, Se, Te), using a combination of \te ...

Chiral cyclopentadienyl (Cp-x) group 9 metal complexes have become versatile catalysts for a variety of efficient enantioselective C-H functionalizations. Atropchiral binaphthyl-derived Cp-x ligands having tuning options at the 3,3'-positions present a rob ...

BackgroundLarge-scale datasets of protein structures and sequences are becoming ubiquitous in many domains of biological research. Experimental approaches and computational modelling methods are generating biological data at an unprecedented rate. The deta ...

Remarkable hardware robustness of deep learning (DL) is revealed by error injection analyses performed using a custom hardware model implementing parallelized restricted Boltzmann machines (RBMs). RBMs in deep belief networks demonstrate robustness against ...

The photophysics and photochemistry of transition metal complexes (TMCs) has long been a hot field of interdisciplinary research. Rich metal-based redox processes, together with a high variety in electronic configurations and excited-state dynamics, have r ...

The 1/4-filled organic compound, delta-(EDT-TTF-CONMe2)(2)AsF6 is a frustrated two-dimensional triangular magnetic system as shown by high-frequency (111.2 and 222.4 GHz) electron spin resonance (ESR) and structural data in the literature. The material gra ...

A key aspect of constructing highly scalable Deep-learning microelectronic systems is to implement fault tolerance in the learning sequence. Error-injection analyses for memory is performed using a custom hardware model implementing parallelized restricted ...

It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer (1MLCT) states of Fe(II) complexes leads to population of the lowest-lying high-spin quintet state (T-5) with unity quantum yield. Here we investigate this so-calle ...

synthesized and characterized by H-1, C-13, P-31 NMR and IR spectroscopies. The reaction of MnCl2 center dot 4H(2)O with L led to the formation of a new 3D system {MnL2Cl2}(n)center dot 34CH(3)OH (C-1). X-ray crystallographic data revealed that the ligand ...

We report on the magnetic properties of individual Fe atoms deposited on MgO(100) thin films probed by x-ray magnetic circular dichroism and scanning tunneling spectroscopy. We show that the Fe atoms have strong perpendicular magnetic anisotropy with a zer ...

Two-metal-ion-dependent nucleases cleave the phosphodiester bonds of nucleic acids via the two-metal-ion (2M) mechanism. Several high-resolution X-ray structures portraying the two-metal-aided catalytic site, together with mutagenesis and kinetics studies, ...

Vanadium complexes with N-heterocyclic vinylidene ligands

Chat with Graph Search

Crystalline and correlated phases in two-dimensional transition metal dichalcogenides

Rh-I, Ir-III ,and Co-III Complexes with Atropchiral Biaryl Cyclopentadienyl Ligands: Syntheses, Structures, and Catalytic Activities

rstoolbox - a Python library for large-scale analysis of computational protein design data and structural bioinformatics

Error Tolerance Analysis of Deep Learning Hardware Using a Restricted Boltzmann Machine Toward Low-Power Memory Implementation

Fe N-Heterocyclic Carbene Complexes as Promising Photosensitizers

Frustration-induced one-dimensionality in the isosceles triangular antiferromagnetic lattice of delta-(EDT-TTF-CONMe2)(2)AsF6

Memory-error tolerance of Scalable and Highly Parallel Architecture for Restricted Boltzmann Machines in Deep Belief Network

Sub-50-fs photoinduced spin crossover in [Fe(bpy)(3)](2+)

Synthesis, structural determination, theoretical studies and catalytic activity of Mn(II) complex of N-isonicotinyl phosphoric triamide ligand

Origin of Perpendicular Magnetic Anisotropy and Large Orbital Moment in Fe Atoms on MgO

Catalytic Metal Ions and Enzymatic Processing of DNA and RNA