Publication

Sub-50-fs photoinduced spin crossover in [Fe(bpy)(3)](2+)

Majed Chergui, Gerald Auböck
2015
Journal Articles

Abstract

It is known that excitation by visible light of the singlet metal-to-ligand charge-transfer (1MLCT) states of Fe(II) complexes leads to population of the lowest-lying high-spin quintet state (T-5) with unity quantum yield. Here we investigate this so-called spin crossover (SCO) transition in aqueous iron(II) tris(bipyridine). We use pump-probe transient absorption spectroscopy with a high time resolution of

Official source

https://infoscience.epfl.ch/entities/publication/226d5d9b-388f-4f3f-9038-543dc67a0407

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Sub-50-fs photoinduced spin crossover in [Fe(bpy)(3)](2+)

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