Publications by Federico De Biasi

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Signal amplification by reversible exchange (SABRE) uses metal-mediated reversible binding of parahydrogen to transfer polarization via spin-spin couplings in transient complexes, particularly iridium complexes with N-heterocyclic carbenes (NHC). The magne ...

Pt(II)-based molecular catalysts stand as a prototypical system in hydrogen evolution reactions (HER) owing to their consistently elevated activity levels. Their integration into heterogeneous systems thus provides an ideal platform to develop catalytic ma ...

In the study of small molecule ligands and candidate macromolecular targets, water spins in long-lived association with macromolecules (proteins or nanoparticles) constitute a remarkable source of magneti-zation that can be exploited to reveal ligand-targe ...

Low sensitivity is the primary limitation to extendingnuclearmagnetic resonance (NMR) techniques to more advanced chemical andstructural studies. Photochemically induced dynamic nuclear polarization(photo-CIDNP) is an NMR hyperpolarization technique where ...

The sensitivity of NMR spectroscopy is considerably enhanced by dynamic nuclear polarization (DNP). In DNP polarization is transferred from unpaired electrons of a polarizing agent to nearby proton spins. In solids, this transfer is followed by the transpo ...

1H photochemically induced dynamic nuclear polarization (photo-CIDNP) has recently emerged as a tool to enhance bulk 1H nuclear magnetic resonance (NMR) signals in solids at magnetic fields ranging from 0.3 to 21.1 T, using synthetic donor-chromophore-acce ...

Solid-state photochemically induced dynamic nuclear polarization (photo-CIDNP) is a nuclear magnetic resonance spectroscopy technique in which nuclear spin hyperpolarization is generated upon optical irradiation of an appropriate donor-acceptor system. Unt ...

The inherently low sensitivity of nuclear magnetic resonance (NMR) spectroscopy is the major limiting factor for its application to elucidate structure and dynamics in solids. In the solid state, nuclear spin hyperpolarization methods based on microwave-in ...

To address the urgent need for sustainable energy processes, there is a growing demand for multifunctional materials that mimic natural photosynthetic enzyme functions, specifically light-harvesting, efficient photoinduced charge separation, and integratio ...

Published by American Chemical Society.Triphenylphosphine (PPh3) is a ubiquitous ligand in organometallic chemistry that has been shown to give enhanced 31P NMR signals at high magnetic field via a scalar-dominated Overhauser effect dynamic nuclear polariz ...

Federico De Biasi

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Predicting the Nmr Chemical Shifts of Hydrides in Sabre-active Ir Complexes by Relativistic Dft

Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

Uniform water-mediated saturation transfer: A sensitivity-improved alternative to WaterLOGSY

Optically Enhanced Solid-State H-1 NMR Spectroscopy

Deuterated TEKPol Biradicals and the Spin-Diffusion Barrier in MAS DNP

Mechanism of Solid-State 1H Photochemically Induced Dynamic Nuclear Polarization in a Synthetic Donor-Chromophore-Acceptor at 0.3 T

Magic Angle Spinning Solid-State 13C Photochemically Induced Dynamic Nuclear Polarization by a Synthetic Donor-Chromophore-Acceptor System at 9.4 T

Light-Induced 1H NMR Hyperpolarization in Solids at 9.4 and 21.1 T

Synergistic Integration of a Ru(bda)-Based Catalyst in a Covalent Organic Framework for Enhanced Photocatalytic Water Oxidation

Probing Homogeneous Catalysts and Precatalysts in Solution by Exchange-Mediated Overhauser Dynamic Nuclear Polarization NMR