Publications by Ilia Kochetygov

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Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on the lab scale hardly translates into pilot- or industrial-scale applications due to the microcrystalline nature of ...

In this work, a detailed study is conducted to understand how ligand substitution influences the CO, and N-2 adsorption properties of two highly crystalline sodalite metal-organic frameworks (MOFs) known as Cu-BTT (BTT-3 = 1,3,5-benzenetristetrazolate) and ...

The complexes [Co (NH3)(6)][Ir (C2O4)(3)] and [Ir(NH3)(6)][Co (C2O4)(3)center dot H2O have previously been synthesized and their thermal properties studied. The [Ir(NH3)(6)][Ir(C2O4)(3)] and [Co(NH3)(6)][Co(C2O4)(3)]center dot 3H(2)O complexes considered h ...

Herein we present a detailed study of the hydrogen adsorption properties of Cu‐BTTri, a robust crystalline metal–organic framework containing open metal‐coordination sites. Diffraction techniques, carried out on the activated framework, reveal a structure ...

Using azolium-based ligands for the construction of metal-organic frameworks (MOFs) is a viable strategy to immobilize catalytically active N-heterocyclic carbenes (NHC) or NHC-derived species inside MOF pores. Thus, in the present work, a novel copper MOF ...

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Metal-organic frameworks (MOFs) have firmly established in the field of porous materials since their early discovery in the 1990s. With a plethora of applications, these materials offer endless possibilities owing to their tunable, modular nature. The vast ...

Herein, a post-synthetic modification strategy is used to covalently graft polyamines, including ethylenediamine (ED), diethylenetriamine (DETA), tris(2-aminoethyl)amine (TAEA), and polyethyleneimine (PEI) to the amino-ligand inside of a Cr-MOF, NH2-Cr-BDC ...

Introducing oligomeric or polymeric units into metal- organic frameworks (MOFs) can result in composites that have significantly improved properties when compared with the individual MOF or polymer building blocks. With such synergy in mind, this work pres ...

In this contribution, recent advances in the construction of MOF-polymer composites and their corresponding applications are briefly reviewed. The appearance of such architectures is becoming prominent in recent literature, due to the fact that the union o ...

Functionalizing metal–organic frameworks (MOFs) with amines is a commonly used strategy to enhance their performance in CO2 capture applications. As such, in this work, a two-step strategy to covalently functionalize NH2-containing MOFs with short chain po ...

Cu-TDPAT (H6TDPAT = 2,4,6-tris(3,5-dicarboxylphenylamino)-1,3,5-triazine), a stable nanoporous metal-organic framework with rht topology, has sparked broad interest as an adsorbent for several chemical separation processes. In this work, in situ synchrotro ...

While metal-organic frameworks (MOF) alone offer a wide range of structural tunability, the formation of composites, through the introduction of other non-native species, like polymers, can further broaden their structure/property spectrum. Here we demonst ...

The present invention relates to a catalyst free method for the synthesis of a ligand for polymeric tri-dimensional porous network comprising reacting a. at least one amine of formula (VII), (VIII), (IX), (X) or (XIII), with b. at least one aromatic compou ...

Ilia Kochetygov

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Preparation of Highly Porous Metal-Organic Framework Beads for Metal Extraction from Liquid Streams

Understanding How Ligand Functionalization Influences CO2 and N-2 Adsorption in a Sodalite Metal-Organic Framework

Synthesis and investigation of the thermal proper- ties of [Co(N H-3)(6)] [Co(C2O4)(3)]center dot 3H(2)O and [Ir(NH3)(6)][Ir(C2O4)(3)]

An In-Situ Neutron Diffraction and DFT Study of Hydrogen Adsorption in a Sodalite-Type Metal-Organic Framework, Cu-BTTri

3D vs. turbostratic: controlling metal-organic framework dimensionality via N-heterocyclic carbene chemistry

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Development of metal-organic frameworks based on N-heterocyclic ligands

Post-Synthetic Covalent Grafting of Amines to NH2-MOF for Post-Combustion Carbon Capture

Understanding Your Support System: The Design of a Stable Metal-Organic Framework/Polyazoamine Support for Biomass Conversion

Enhancing MOF performance through the introduction of polymer guests

A Two Step Postsynthetic Modification Strategy: Appending Short Chain Polyamines to Zn-NH2-BDC MOF for Enhanced CO2 Adsorption

Large anisotropic negative thermal expansion in Cu-TDPAT metal-organic framework: A combined in situ X-ray diffraction and DRIFTS study

A metal-organic framework/polymer derived catalyst containing single-atom nickel species for electrocatalysis

Large anisotropic negative thermal expansion in Cu-TDPAT metalorganic framework: A combined in situ X-ray diffraction and DRIFTS study (vol 51, pg 631, 2020)

Ligands for metal organic frameworks and a catalyst-free method of making such