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Ivan Buslov

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Related publications (5)

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Nickel-catalyzed Hydrosilylation of Alkenes and Transition-Metal-Free Intermolecular α-C-H Amination of Ethers

Ivan Buslov

Transition-metal-catalyzed hydrosilylation of olefins is one of the most important methods for the preparation of organosilicon compounds, which have broad applications in both synthetic and material chemistry. For decades, precious metals, principally pla ...

EPFL2016

An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes

Xile Hu, Fang Song, Ivan Buslov

The first efficient and non-precious nanoparticle catalyst for alkene hydrosilylation with commercially relevant tertiary silanes has been developed. The nickel nanoparticle catalyst was prepared in situ from a simple nickel alkoxide precatalyst Ni((OBu)-B ...

Wiley-Blackwell2016

Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes

Xile Hu, Mickael Montandon-Clerc, Ivan Buslov, Simona Mazza

Chemoselective hydrosilylation of functionalized alkenes is difficult to achieve using base-metal catalysts. Reported herein is that well-defined bis(amino) amide nickel pincer complexes are efficient catalysts for anti-Markovnikov hydrosilylation of termi ...

Wiley-Blackwell2015

Engineered Phenylalanine Ammonia-Lyases for the Enantioselective Synthesis of Aspartic Acid Derivatives

Sarah Sandrine Lucille Desmons, Xile Hu, Ivan Buslov, Yoan Désiré Duhoo

Biocatalytic hydroamination of alkenes is an efficient and selective method to synthesize natural and unnatural amino acids. Phenylalanine ammonia-lyases (PALs) have been previously engineered to access a range of substituted phenylalanines and heteroaryla ...

Wiley-VCH Verlag GmbH2024

Transition Metal-Free Intermolecular alpha-C-H Amination of Ethers at Room Temperature

Xile Hu, Ivan Buslov

We describe a new method for the intermolecular amination of the alpha-C-H bonds of ethers. A hypervalent iodine reagent was used as oxidant to enable the amination of cyclic and acyclic alkyl ethers with a wide range of amides, imides, and amines. The ami ...

Wiley-Blackwell2014