Publications by Hirohisa Nagatani

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The transfer mechanism of 1-pyrene sulfonate anion (PSA−) across the polarized water 1,2-dichloroethane (DCE) interface was investigated by a combination of electrochemical techniques and potential modulated fluorescence (PMF) spectroscopy under total inte ...

Fundamental expressions for analyzing potential modulated fluorescence (PMF) responses were derived within the framework of a phenomenological model for adsorption and transfer of ionic species across polarized liquid|liquid interfaces. For small periodic ...

The self-assembly of the oppositely charged watersoluble porphyrins, cobalt tetramethylpyridinium porphyrin (CoTMPyP4+) and cobalt tetrasulphonatophenyl porphyrin (CoTPPS4−), at the interface with an organic solvent to form molecular “rafts”, provides an excellent catalyst to perform the interfacial four-electron reduction of oxygen by lipophilic electron donors such as tetrathiafulvalene (TTF). The catalytic activity and selectivity of the self-assembled catalyst toward the four-electron pathway was found

Meet at the border: Assembly of the water-soluble cobalt tetrakis(N-methylpyridinium-4-yl)porphyrin [CoTMPyP]4+ at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C6F5)4B−. The supramolecular structure t ...

Photocurrent responses associated with the interfacial quenching of the photo-excited water-soluble zinc meso-tetra(4-carboxyphenyl)porphyrin (ZnTPPC) by ferrocene have been studied at a water|1,2-dichloroethane interface in the absence and in the presence ...

Hirohisa Nagatani

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Transfer and adsorption of 1-pyrene sulfonate at the water / 1,2-dichloroethane interface studied by potential modulated fluorescence spectroscopy

A Kinetic Model for Adosorption and Transfer of Ionic Species at Polarized Liquid|Liquid Interfaces as Studied by Potential Modulated Fluorescence Spectroscopy

Self-Assembled Molecular Rafts at Liquid|Liquid Interfaces for Four-Electron Oxygen Reduction

Interfacial Self-Assembly of Water-Soluble Cationic Porphyrins for the Reduction of Oxygen to Water

Photocurrents at polarized liquid|liquid interfaces enhanced by a gold nanoparticle film

Mechanistic Aspects Associated with the Oxidation of L-Ascorbic Acid at the 1,2-Dichloroethane|Water Interface

Adsorption Behaviour of Charged Zinc Porphyrins at the Water|1,2-Dichloroethane Interface Studied by Potential Modulated Fluorescence Spectroscopy

Adsorption and Aggregation of meso-Tetrakis(4-carboxyphenyl)porphyrinato Zinc(II) at the Polarized Water|1,2-Dichloroethane Interface

Surface Second Harmonic Generation of Cationic Water-Soluble Porphyrins at the Polarized Water / 1,2-Dichloroethane Interface

Photoinduced Electron Transfer at Liquid|Liquid Interface. Part IV. Orientation and Reactivity of Zinc Tetra(4-Carboxyphenyl) Porphyrin Self-Assembled at the Water|1,2-Dichloroethane Junction