Publication

Interfacial Self-Assembly of Water-Soluble Cationic Porphyrins for the Reduction of Oxygen to Water

Hubert Girault, Astrid Johana Olaya Avendano, Hirohisa Nagatani, Delphine Henriette Schaming
2012
Journal Articles

Abstract

Meet at the border: Assembly of the water-soluble cobalt tetrakis(N-methylpyridinium-4-yl)porphyrin [CoTMPyP]4+ at soft interfaces is enhanced and stabilized by its interfacial interaction with the lipophilic anion (C6F5)4B−. The supramolecular structure thus formed (see picture) provides excellent catalytic activity in the four-electron reduction of oxygen.

Official source

https://infoscience.epfl.ch/entities/publication/ab738ff8-bf93-403d-b9cf-b31456f3e7df

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Interfacial Self-Assembly of Water-Soluble Cationic Porphyrins for the Reduction of Oxygen to Water

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