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Mohammad Khaja Nazeeruddin

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Related publications (846)

Quasi-quantum dot-induced stabilization of alpha-CsPbI3 perovskite for high-efficiency solar cells

Mohammad Khaja Nazeeruddin, Xin Liu, Tom Theodorus Antonius Lummen, Yong Ding, Yuanlong Li, Cheng Liu

All-inorganic cesium lead iodide perovskites (CsPbI3) are promising materials for efficient solar cells. However, they suffer from the formation of an undesired yellow delta -phase under ambient conditions. Herein, we provide a novel strategy to in situ pr ...

Royal Society of Chemistry2020

The Role of Goldschmidt's Tolerance Factor in the Formation of A(2)BX(6) Double Halide Perovskites and its Optimal Range

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Nikita Drigo, Alexander Fedorovskiy

Vacancy-ordered double perovskites is a new branch of lead-free halide perovskites with properties promising for photovoltaic application. In this study, data about the crystal structure of 170 known A(2)BX(6) (X = I, Br, Cl, F) are collected and analyzed ...

2020

Universal approach toward high-efficiency two-dimensional perovskite solar cells via a vertical-rotation process

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Cristina Roldán Carmona, Filippo de Angelis, Pascal Alexander Schouwink, Mo Li, Yong Ding, Cheng Liu

The emerging 2D perovskites exhibit superior stability and similar optoelectronic attributes compared to the 3D analogues, but their strong exciton-binding energy and inferior interlayer charge-transport reduce dramatically the device performance. Herein, ...

2020

Nanoscale Mass-Spectrometry Imaging of Grain Boundaries in Perovskite Semiconductors

Mohammad Khaja Nazeeruddin, Paul Gratia, Tom Theodorus Antonius Lummen, Iwan Zimmermann, Hiroyuki Kanda

Incorporation of alkali metals such as Cs+, Rb+, and K+ into hybrid organic-inorganic halide lead perovskites (HOIPs) generally improves the optoelectronic properties of HOIPs. However, it is still uncertain how alkali metals interact and distribute within ...

2020

Vertically Aligned 2D/3D Pb-Sn Perovskites with Enhanced Charge Extraction and Suppressed Phase Segregation for Efficient Printable Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Fei Guo, Xuehui Liu, Chaohui Li, Shi Chen

The concept of mixed 2D/3D heterostructures has emerged as an effective method for improving the stability of lead halide perovskite solar cells, which has been, however, rarely reported in lead-tin (Pb-Sn) mixed perovskite devices. Here, we report a scala ...

2020

Soft Template-Controlled Growth of High-Quality CsPbI3 Films for Efficient and Stable Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yong Ding, Xuehui Liu, Cheng Liu

The unfavorable morphology and inefficient utilization of phase transition reversibility have limited the high-temperature-processed inorganic perovskite films in both efficiency and stability. Here, a simple soft template-controlled growth (STCG) method i ...

2020

In Situ Analysis Reveals the Role of 2D Perovskite in Preventing Thermal-Induced Degradation in 2D/3D Perovskite Interfaces

Mohammad Khaja Nazeeruddin, Valentin Ianis Emmanuel Queloz, Nikita Drigo, Giulia Grancini, Albertus Adrian Sutanto, Rodrigo Szostak

Engineering 2D/3D perovskite interfaces is a common route to realizing efficient and stable perovskite solar cells. Whereas 2D perovskite’s main function in trap passivation has been identified and is confirmed here, little is known about its 2D/3D interfa ...

American Chemical Society (ACS)2020

Azatruxene-Based, Dumbbell-Shaped, Donor-pi-Bridge-Donor Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Cristina Roldán Carmona, Inés Garcia Benito, Cansu Igci, Javier Urieta Mora

Three novel donor-pi-bridge-donor (D-pi-D) hole-transporting materials (HTMs) featuring triazatruxene electron-donating units bridged by different 3,4-ethylenedioxythiophene (EDOT) pi-conjugated linkers have been synthesized, characterized, and implemented ...

2020

Molecular engineering of simple carbazole-arylamine hole-transport materials for perovskite solar cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yong Ding, Xuehui Liu, Cheng Liu

We report synthesis and characterization of novel hole-transport materials (HTMs) with substituents, methylsulfonyl, N,N-dimethylamino or methoxy groups, introduced onto the N of the carbazole unit of carbazole-arylamine and their application in perovskite ...

2020

Effective Preparation of Nanoscale CH3NH3PbI3 Perovskite Photosensitizers for Mesoporous TiO2-Based Solar Cells by Successive Precursor Layer Adsorption and Reaction Process

Mohammad Khaja Nazeeruddin, Yonghui Lee, Tom Theodorus Antonius Lummen, Kyung Taek Cho, Sanghyun Paek, Iwan Zimmermann, Aron Joel Huckaba, Hobeom Kim, So-Min Yoo

Nanoscale CH3NH3PbI3 perovskite sensitizers are grown by delivering each precursor successively onto the surface of mesoporous (meso) TiO2 electrodes. Using Pb(NO3)(2) ions as a lead(II) source and CH3NH3I (MAI) for methylammonium and iodide sources, repet ...

2020

Stable and High-Efficiency Methylammonium-Free Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yi Zhang, Wen Luo, Ruiyuan Hu, Bing Zhang

Organic-inorganic metal halide perovskite solar cells (PSCs) have achieved certified power conversion efficiency (PCE) of 25.2% with complex compositional and bandgap engineering. However, the thermal instability of methylammonium (MA) cation can cause the ...

Wiley2020

Nanoscale Perovskite-Sensitized Solar Cell Revisited: Dye-Cell or Perovskite-Cell?

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, So-Min Yoo

A general and straightforward way of preparing few-nanometer-sized well-separated MAPbI(x)Br(3-x) (MA=methylammonium) perovskite photosensitizers on the surface of an approximately 1 mu m thick mesoporous TiO2 photoanode was suggested through a two-step se ...

2020

Tetrasubstituted Thieno[3,2-b]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Iwan Zimmermann, Inés Garcia Benito, Javier Urieta Mora

Three hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to ...

2020

Green-Emitting Lead-Free Cs4SnBr6 Zero-Dimensional Perovskite Nanocrystals with Improved Air Stability

Mohammad Khaja Nazeeruddin, Valentin Ianis Emmanuel Queloz, Tom Theodorus Antonius Lummen, Giulia Grancini

We report the synthesis and characterization of nanocrystals of a novel fully inorganic lead-free zero-dimensional perovskite, Cs4SnBr6. Samples are made of crystals with an average size of similar to 20 nm with green emission centered around 530 nm. Inter ...

2020

Proton-transfer-induced 3D/2D hybrid perovskites suppress ion migration and reduce luminance overshoot

Mohammad Khaja Nazeeruddin, Emad Oveisi, Hobeom Kim

Perovskite light-emitting diodes (PeLEDs) based on three-dimensional (3D) polycrystalline perovskites suffer from ion migration, which causes overshoot of luminance over time during operation and reduces its operational lifetime. Here, we demonstrate 3D/2D ...

Nature Research2020

Surface, Interface, and Bulk Electronic and Chemical Properties of Complete Perovskite Solar Cells: Tapered Cross-Section Photoelectron Spectroscopy, a Novel Solution

Mohammad Khaja Nazeeruddin, Iwan Zimmermann, Thomas Mayer

The surface, interface, and bulk properties are a few of the most critical factors that influence the performance of perovskite solar cells. The photoelectron spectroscopy (PES) is used as a technique to analyze these properties. However, the information d ...

AMER CHEMICAL SOC2020

Increasing efficiency of perovskite solar cells using low concentrating photovoltaic systems (vol 4, pg 528, 2020)

Mohammad Khaja Nazeeruddin, Hasan Baig, Hiroyuki Kanda

Correction for 'Increasing efficiency of perovskite solar cells using low concentrating photovoltaic systems' by Hasan Baiget al.,Sustainable Energy Fuels, 2020,4, 528-537, DOI: ;10.1039/c9se00550a. ...

2020

D-pi-A-Type Triazatruxene-Based Dopant-Free Hole Transporting Materials for Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Kasparas Rakstys, Sanghyun Paek, Cristina Roldán Carmona, Hiroyuki Kanda, Cansu Igci, Hobeom Kim

Three donor-pi-bridge-acceptor (D-pi-A)-type organic small molecules coded CI-B1, CI-B2, and CI-B3 are designed, synthesized, and used as dopant-free hole transporting materials (HTMs) for perovskite solar cells (PSCs). The strong electron-donating triazat ...

WILEY-V C H VERLAG GMBH2020

Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Henry Snaith, Konrad Domanski, Wolfgang Richard Tress, Antonio Abate, Michael Saliba, Monica Marcela Lira Cantu, Haibing Xie, Kai Zhu

Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters repor ...

NATURE PUBLISHING GROUP2020

A hysteresis-free perovskite transistor with exceptional stability through molecular cross-linking and amine-based surface passivation

Mohammad Khaja Nazeeruddin, Peng Gao, Hobeom Kim

Organo-metal halide perovskite field-effect transistors present serious challenges in terms of device stability and hysteresis in the current-voltage characteristics. Migration of ions located at grain boundaries and surface defects in the perovskite film ...

ROYAL SOC CHEMISTRY2020

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