Publications by Raphaël Ihringer

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Electrical output behaviour obtained on solid oxide fuel cell stacks, based on planar anode supported cells (50 or 100 cm2 active area) and metallic interconnects, is reported. Stacks (1–12 cells) have been operated with cathode air and anode hydrogen flow ...

A short overview of recent work on electroceramic materials relevant to methane-fueled SOFC systems is given. Various fuel feed options are considered, such as pure methane, biogas, and the addition of reforming agents. The principle and implementation into SOFC systems of mixed conducting ceramics for oxygen separation is described, as well as their characterisation by electrochemical methods. Ceramic anodes capable of operating with methane-rich fuel injection are presented. The document concludes with el

Progress on anode supported cell stacks (SOFCONNEX design, 50 m2 per cell) is presented. A 6-cell stack and a 8 cell-stack were mounted and tested with hydrogen fuel at 800 degre C, yielding 100 W el and 140 W el, corresponding to a power density of 1kW el/L (0.34 W/cm2). Fuel utilisation was 50% and electrical efficiency 25%. A one-cell stack delivered 0.4 W/cm 2 at 70% fuel utilisation and 33 % electrical efficiency, and showed a performance increase over its 450 h test period. Another one-cell stack was

Ni-YSZ anode supports show a fundamentally different microstructure from screenprinted Ni-YSZ anodes on YSZ electrolyte supports. Of high density and composed of fine zirconia and nickel oxide to allow for cofiring with a thin zirconia electrolyte film (5 µm), the anode support shows advantages of adequate strength and increased electrochemical activity probably not only limited to the TPB, unlike screen printed porous anodes. Areas up to 100 cm2 have been fabricated. Electrochemical cell testing produced r

Recent progress in our development of anode supported electrolyte (ASE) SOFcells is reported. The cells are fabricated by cocasting of aqueous slurries of NiO/YSZ and 8YSZ, followed by cofiring. A gradient cathode is deposited by screenprinting successive layers of LSM/YSZ composite and lanthanum cobaltite, followed by a 2nd firing step. Full cells show a final thickness of ? 0.25 mm, high flexibility and reasonable warpage. Proper anode current collection is crucial and obtained by cofiring an additional o

A tape casting co-sintering route is described in which thin dense layers of LaSrFeCoO3 (LSFC) have been formed on planar, porous MgO substrates 100- 200 micron thick. SEM analysis of the sintered structure showed that it was possible to eliminate most of the residual porosity in the LSFC layer, but maintain a porosity between 25 and 45% in the MgO support layer. The LSFC layer dit not reveal many cracks. The overall shrinkage of the co-sintered structure was about 25%. The LSFC layer topography was smooth

A SOFC concept based on microtubular cells is presented. Mechanical tests and modelling show viability for fast thermal cycling in air for both zirconia and ceria electrolyte tubes. To combine advantages of both these materials, the concept includes a thin ...

Solid Oxide Fuel Cell (SOFC) application development is very well represented in Switzerland by two companies. Sulzer Hexis AG is one of the world leaders in the commercialization of SOFC systems for single family houses. A smaller company, HTceramix, is a ...

Our SOFC stack development technology is based on the unique SOFConnexTM concept, using flexible gas distribution layers between metal sheet interconnect and thin ASE cells. Flexibility is given both in material and design. This ensures proper electrical c ...

Raphaël Ihringer

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Dynamic behaviour of SOFC short stacks

Materials for Methane-fueled SOFC Systems

Compact 100 W stacks using thin components of anode supported cells and metal interconnects

Anode Supported Thin Zirconia Based Cells for Intermediate Temperature SOFC

Stability and performance of tape cast anode supported electrolyte (ASE) cells

Co-casting and co-sintering of porous MgO support plates with thin dense perovskite layers of LaSrFeCoO3

Concept and technology of SOFC for electric vehicles

Swiss SOFC Integration Activities : Stacks, Systems, and Applications

PROGRESS IN STACK POWER DENSITY USING THE SOFCONNEX™ CONCEPT

Electrolytes minces sur supports anode dans les piles à combustible SOFC