Lecture

Chemical Bonds: Types and Structures

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In course

MSE-101(b): Materials:from chemistry to properties

Ce cours permet l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimique en liaison avec les propriétés mécaniques, thermiques, électriques, magnétiques et optiques des matériaux. ...

Description

This lecture covers the different types of chemical bonds, including metallic, covalent, and ionic bonds, explaining their characteristics and the factors influencing their formation. It also delves into the structuring of solids, discussing the levels of structuring, the periodic table of elements, and the crystallographic structures induced by the arrangement of ions. The lecture further explores the mechanical properties of metals, the concept of weak bonds, and the states of matter, emphasizing the distinction between crystalline and amorphous structures. Additionally, it introduces crystal systems and Bravais networks, providing insights into the symmetry and patterns of crystals.

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Instructors (4)

Michel Rappaz

After a PhD in solid state physics (1978) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) and a post-doc at Oak Ridge National Laboratory, Michel Rappaz joined the Institute of Materials of EPFL in 1981. After two years in an engineering company, he came back to EPFL in 1984 where he was nominated Adjunct Professor in 1990 and Full Professor in 2003. He retired from EPFL in 2015 and is now Emeritus Professor and independent consultant for several industries and research centres. His main interests are in phase transformations and solidification, in particular the coupling of macroscopic aspects of heat and mass transfer with microscopic aspects of microstructure and defect formation. Among his diverse achievements, one can mention in particular the development of cellular automata for grain structure predictions and of granular models for hot tearing formation in castings, the coupling of Finite Element method with microscopic models of nucleation and growth, the application of the phase field method to the understanding of various microstructures, the discovery of quasicrystal mediated-nucleation in alloys, and many other studies both fundamental at the microstructure-defect level and more applied at the level of processes. Some of the software developments have been commercialized by a spin-off company founded by his group in 1991 (Calcom SA), now part of the French company ESI. Michel Rappaz initiated in 1992 an annual postgraduate course on solidification which has been attended by more than 900 participants from all over the world. He is presently collaborating closely with another spin-off company started from his group, Novamet SàrL. Michel Rappaz has received several awards, in particular the Mathewson co-author award (1994) and author award (1997) of the American Mineral, Metals and Materials Society (TMS), the Koerber foundation award jointly with Profs Y. Bréchet and M. Asbby (1996), the Sainte-Claire Deville Medal (1996) and the Grand Medal (2011) from the French Materials Society, the Bruce Chalmers Award of TMS (2002), the Mc Donald Memorial Lecture award of Canada (2005), the FEMS European Materials Gold Medal (2013) and the Brimacombe Prize of TMS (2015). He is a highly-cited author of ISI, a fellow of ASM, IOP and TMS, and has co-authored more than 200 publications and two books.

Arianna Marchioro

Education PhD Thesis | Interfacial Charge Transfer Dynamics in Solid-State Hybrid Organic-Inorganic Solar Cells 2010 – 2014 EPFL Directed by Prof. J.-E. Moser and Prof. M. Grätzel MSc in Molecular and Biological Chemistry | 2008 – 2010 EPFL and Imperial College London (exchange program) BSc in Chemistry | 2005 – 2008 EPFL Professionals experiences Postdoctoral Research Associate 2014–2016 University of Washington, Seatt

Official source

Ontological neighbourhood

Chemistry

Organic chemistry: Organometallic chemistry

Related concepts (32)

Chemical bond

A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of electrons as in covalent bonds. The strength of chemical bonds varies considerably; there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding.

Crystal structure

In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure.

Chemical polarity

In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms. Molecules containing polar bonds have no molecular polarity if the bond dipoles cancel each other out by symmetry. Polar molecules interact through dipole-dipole intermolecular forces and hydrogen bonds.

Coordinate covalent bond

In coordination chemistry, a coordinate covalent bond, also known as a dative bond, dipolar bond, or coordinate bond is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. This type of interaction is central to Lewis acid–base theory. Coordinate bonds are commonly found in coordination compounds. Coordinate covalent bonding is ubiquitous.

Amorphous solid

In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo a glass transition. Examples of amorphous solids include glasses, metallic glasses, and certain types of plastics and polymers. The term comes from the Greek a ("without"), and morphé ("shape, form").

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Fabien Sorin

Sep 2002-Oct 2007 Ph.D., Department of Materials Science and Engineering, MIT, USA. Supervisor: Prof. Yoel Fink; Thesis: Multi-material, Multifunctional Fiber Devices. After graduating with an engineering degree and a Master of Science in Physics from the Ecole Polytechnique in Palaiseau, France, Prof. Sorin joined the department of Materials Science and Engineering at the Massachusetts Institute of Technology (MIT) in Cambridge, USA for his graduate studies. He worked as a research assistant in the Photonic Bandgap Fibers and Devices Group of Professor Yoel Fink and graduated with a PhD in 2008. His PhD thesis led to the development of a new class of fiber material and devices and he was a pioneer of the field of multi-material fibers. Mar 2008-Oct 2010 Postdoctoral Associate and Research Scientist, Research Laboratory of Electronics, MIT. He then joined the Research Laboratory of Electronics at MIT as a Postdoctoral Associate, and continued as a Research Scientist associate, where he conducted independent research in the emerging field of multi-material fibers and was involved and led a variety of projects in fundamental research as well as in collaborations with local start-ups. Apr 2011 Feb 2013 Research Engineer, Saint-Gobain Recherche, Aubervilliers, France. Surface du Verre et interface Group In 2011, prof. Sorin returned to Europe and joined the company Saint-Gobain in the Saint-Gobain Recherche center, its biggest research center located near Paris in France. As a research engineer, he developed a new research thrust investigating new photonic materials and nanostructures for the energy and building industries. In particular, he and colleagues developed innovative processing approaches to deploy photonic nanostructures for light management over large area substrates, for applications in energy harvesting and saving, and for building materials and windows. Mar 2013 Present Assistant Professor tenure-track, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. Head of the Photonic materials and fibre devices laboratory (FIMAP) Since March 2013, he is in the department of Materials Science (IMX) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) as an assistant professor tenure-track. He is starting a research group on photonic materials and fiber devices (FIMAP), continuing on developing innovative materials processing approaches and photonic device architectures to develop new solutions in energy harvesting, saving and storage, in sensing and monitoring, health care and smart fabrics.

Related concepts (32)

Chemical bond

Crystal structure

Chemical polarity

Coordinate covalent bond

Amorphous solid