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Lecture

Group Representations: Matrices and Symmetry

In course

CH-250: Mathematical methods in chemistry

This course consists of two parts. The first part covers basic concepts of molecular symmetry and the application of group theory to describe it. The second part introduces Laplace transforms and Fourier series and their use for solving ordinary and partia ...

Description

This lecture covers the concept of group representations using matrices, focusing on isomorphic representations, reducible vs. irreducible representations, and block-diagonalization. It also discusses bases of representations and the Great Orthogonality Theorem.

Instructors (2)

Jiri Vanicek

Ulrich Lorenz

Official source

Ontological neighbourhood

Mathematics

Algebra: Representation theory

Related concepts (32)

Group representation

In the mathematical field of representation theory, group representations describe abstract groups in terms of bijective linear transformations of a vector space to itself (i.e. vector space automorphisms); in particular, they can be used to represent group elements as invertible matrices so that the group operation can be represented by matrix multiplication. In chemistry, a group representation can relate mathematical group elements to symmetric rotations and reflections of molecules.

Irreducible representation

In mathematics, specifically in the representation theory of groups and algebras, an irreducible representation or irrep of an algebraic structure is a nonzero representation that has no proper nontrivial subrepresentation , with closed under the action of . Every finite-dimensional unitary representation on a Hilbert space is the direct sum of irreducible representations. Irreducible representations are always indecomposable (i.e. cannot be decomposed further into a direct sum of representations), but the converse may not hold, e.

Representation theory of finite groups

The representation theory of groups is a part of mathematics which examines how groups act on given structures. Here the focus is in particular on operations of groups on vector spaces. Nevertheless, groups acting on other groups or on sets are also considered. For more details, please refer to the section on permutation representations. Other than a few marked exceptions, only finite groups will be considered in this article. We will also restrict ourselves to vector spaces over fields of characteristic zero.

Representation theory of the symmetric group

In mathematics, the representation theory of the symmetric group is a particular case of the representation theory of finite groups, for which a concrete and detailed theory can be obtained. This has a large area of potential applications, from symmetric function theory to quantum chemistry studies of atoms, molecules and solids. The symmetric group Sn has order n!. Its conjugacy classes are labeled by partitions of n.

Representation theory

Representation theory is a branch of mathematics that studies abstract algebraic structures by representing their elements as linear transformations of vector spaces, and studies modules over these abstract algebraic structures. In essence, a representation makes an abstract algebraic object more concrete by describing its elements by matrices and their algebraic operations (for example, matrix addition, matrix multiplication).

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