Lecture

Chloride Ingress and Corrosion

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Description

This lecture discusses the impact of chloride ingress on concrete structures, focusing on the causes and consequences of this issue. It covers topics such as the importance of chloride ingress, chemical and physical binding mechanisms, reactive transport processes, and factors influencing chloride penetration. The instructor also explores the significance of pore structure, diffusion coefficient, porosity, tortuosity, saturation, and binding capacities of different compounds in the corrosion process.

In MOOC

Sorption and transport in cementitious materials

In the MOOC: “Cement chemistry and sustainable cementitious materials”; you learned how to create more sustainable cementitious materials. But concrete is not an inert rock. It is a dynamic porous material, which can exchange water, gas and ions with its environment. Through physical and chemical interactions, these exchanges can have dramatic consequences: cracks due to shrinkage, reinforcement bars corrosion, spalling, … For a true sustainability, the durability of cementitious materials should not be f

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Related concepts (12)

Reinforced concrete

Reinforced concrete, also called ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ductility. The reinforcement is usually, though not necessarily, steel bars (rebar) and is usually embedded passively in the concrete before the concrete sets. However, post-tensioning is also employed as a technique to reinforce the concrete. In terms of volume used annually, it is one of the most common engineering materials.

Corrosion

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. In the most common use of the word, this means electrochemical oxidation of metal in reaction with an oxidant such as oxygen, hydrogen or hydroxide. Rusting, the formation of iron oxides, is a well-known example of electrochemical corrosion.

Corrosion inhibitor

In chemistry, a corrosion inhibitor or anti-corrosive is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy, that comes into contact with the fluid. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a lubricant and sometimes a penetrating oil.

Concrete

Concrete is a composite material composed of aggregate bonded together with a fluid cement that cures over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminium combined. When aggregate is mixed with dry Portland cement and water, the mixture forms a fluid slurry that is easily poured and molded into shape.

Galvanic corrosion

Galvanic corrosion (also called bimetallic corrosion or dissimilar metal corrosion) is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another, in the presence of an electrolyte. A similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices. This phenomenon is named after Italian physician Luigi Galvani (1737-1798).

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