Mediaspace scheduled maintenance: Aug 25, 2026 07:00 - 12:00 AM. During this time, videos will be temporarily unavailable. Check status updates.

Lecture

Advanced Spectroscopy Techniques

In course

PHYS-407: Frontiers in nanosciences

The course covers relevant experimental and theoretical concepts in nanoscale science, from fundamental aspects like quantum tunneling and quantum size effects, to hot topics like quantum transport and nanoscale magnetism. ...

Description

This lecture delves into advanced spectroscopy techniques such as XAS, XPS, XMCD, and EXAFS, showcasing how they provide detailed information about the electronic, chemical, and magnetic properties of materials. Through detailed explanations and examples, the instructor explores how these techniques can reveal structural and chemical information, as well as magnetic properties, offering insights into various applications, from nanoscience to catalysis.

Instructors (4)

Marina Pivetta

Klaus Kern

Klaus Kern is Professor of Physics at EPFL and Director and Scientific Member at the Max-Planck-Institute for Solid State Research in Stuttgart, Germany. He also is Honorary Professor at the University of Konstanz, Germany. His present research interests are in nanoscale science, quantum technology and in microscopy at the atomic limits of space and time. He holds a chemistry degree and PhD from the University of Bonn and a honorary doctors degree from the University of Aalborg. After his doctoral studies he was staff scientist at the Research Center Jülich and visiting scientist at Bell Laboratories, Murray Hill before joining the Faculty of EPFL in 1991 and the Max-Planck-Society in 1998. Professor Kern has authored and coauthored close to 700 scientific publications, which have received nearly 60‘000 citations. He has served frequently on advisory committees to universities, professional societies and institutions and has received numerous scientific awards and honors, including the 2008 Gottfried-Wilhelm-Leibniz Prize and the 2016 Van‘t Hoff Prize. Prof. Kern has also educated a large number of leading scientists in nanoscale physics and chemistry. During the past twenty-five years he has supervised one hundred PhD students and sixty postdoctoral fellows. Today, more than fifty of his former students and postdocs hold prominent faculty positions at Universities around the world.

Magalí Alejandra Lingenfelder

Magalí Lingenfelder is currently leading the Max Planck-EPFL Laboratory for Molecular Nanoscience. Her vision is to create atomically tailored interfaces for applications in two distinct areas of urgent technological and societal relevance: energy conversion and smart antimicrobial interfaces. To access the nanoscale, her group uses a combination of state-of-the-art scanning probe microscopy and solid state spectroscopy, allowing the study of kinetic processes in-situ under liquid flow and potential control conditions (operando electrocatalysis). She made seminal contributions to the field of metal-organic coordination networks on solid surfaces, and received the Otto Hahn medal in 2008 for the microscopic understanding of the chiral recognition process with submolecular resolution. She is a committed mentor, and since her relocation from the Lawrence Berkeley National Laboratory, USA to EPFL in 2013, she directed 3 MSc. theses, 4 PhD theses and 4 postdocs. She advocates for problem-oriented interdisciplinary research: she led 5 international research consortiums, delivered over 40 invited presentations and organized 9 conferences and 4 doctoral schools. In 2018, the Royal Society of Chemistry included her work in the first collection “Celebrating Excellence in Research: 100 Women of Chemistry”.

Official source

Ontological neighbourhood

Chemistry

Physical chemistry: Spectroscopy

Related concepts (32)

Spectroscopy

Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).

Infrared spectroscopy

Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum.

Crystal structure

In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure.

Absorption spectroscopy

Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.

Atomic absorption spectroscopy

Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elements by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions. In analytical chemistry the technique is used for determining the concentration of a particular element (the analyte) in a sample to be analyzed.

Related lectures (34)

Introduction to X-rays and X-ray Sources: Part 3

Explores synchrotron radiation, X-ray sources, scientific achievements, and recent highlights in synchrotron science.

Analytical Chemistry: Instrumental Analysis

Covers the principles of instrumental analysis in analytical chemistry for the living world.

Molecular Energy Levels

Delves into molecular energy levels, electronic transitions, and applications in photomedicine.

Analytical Electron Microscopy: Spectroscopy and Microanalysis

Explores Analytical Electron Microscopy techniques for chemical analysis using EELS and EDX.

Photochemistry I: Beer-Lambert Law

Explores the Beer-Lambert law, absorptance, and electronic excited states in photochemistry.

Stefano Rusponi

Education: • 1999 Doctoral degree in Physics obtained at the Physics Department, University of Genova PhD thesis title: “STM study of nanostructures induced by ion sputtering on noble metals”. • 1994 University degree in Physics achieved at the Physics Department, University of Genova. Final mark: 110/110 cum laude Diploma thesis title: “A project for a new method of EELS spectroscopy”. • 1988 High school at the Liceo Scientifico G. P. Vieusseux in Imperia. Final mark: 60/60. Research career plan: • 2016 – present MER: Ecole Polytechnique Fédérale de Lausanne (EPFL) in the group of Prof. Harald Brune • 2003 – 2016: 1er. Assistant: Ecole Polytechnique Fédérale de Lausanne (EPFL) in the group of Prof. Harald Brune • 2000-2003: Assistant: Ecole Polytechnique Fédérale de Lausanne (EPFL) under the direction of Prof. Harald Brune • 1999-2000: Research associate: Max-Planck-Institut of Stuttgart under the direction of Prof. Klaus Kern Miscellaneous of professional activities: a) Review panel • Member of the Elettra proposal review panel • Member of the committee of the EDPY doctoral school in Physics at the EPFL b) Co-worker in the building of the X-Treme beamline: c) Referee for scientific journals: • Nat. Commun., Phys. Rev. Lett., Phys. Rev. B, J. Appl. Phys., Surf. Sci., J. Magn. Magn. Mater. Funding record a) Funding awarded • Quantum Properties of Nanostructures at Surfaces, FNS 200020-157081/1; (01/10/2014 – 31/09/2017); total amount attributed: 832'558 CHF; co-applicant • Controlling magnetic anisotropy by interfacial coupling, FNS 200021_146715/1; (01/01/2014 – 31/12/2016); total amount attributed: 367'800 CHF; co-applicant • Self-assembled bi-metallic magnetic pillar superlattices with enhanced blocking temperature, SER C10.0135; (01/08/2011 – 01/08/2013); total amount attributed: 170'000 CHF; co-applicant • Magnetic and Catalytic Properties of Surface Supported Metallic Nanostructures, FNS 200020-120493/1; (01/04/2008 – 31/03/2010); total amount attributed: 402'669 CHF; co-applicant • Magnetic and Catalytic Properties of Surface Supported Metallic Nanostructures, FNS 200020-112322/1; (01/04/2006 – 31/03/2008); total amount attributed: 347'633 CHF; co-applicant b) Approved proposals for the allocation of beamtime Swiss Light Source (SLS): main proposer: 9 co-proposer: 4 Elettra: main proposer: 5 co-proposer: 1 European Synchrotron Radiation Facility (ESRF): main proposer: 2 co-proposer: 11 Student supervisor • Co-director of PhD thesis: 4 PhD students

Dimitris Mousadakos: Seeking the smallest room temperature magnets; (in progress)
Romana Baltic: Controlling single atom magnetic anisotropy by interfacial coupling; (in progress)
Alberto Cavallin: Growth and magnetism of nanostructures investigated by STM, MOKE, and XMCD; (Oct. 2013), Thèse N°5941
Sergio Vlaic: Magnetism and atomic scale structure of bimetallic nanostructures at surfaces; (Dec. 2012), Thèse N° 5625

• Supervisor of PhD thesis (without co-direction): 4 PhD students

Anne Lehnert: Magnetism of individual adatoms and of epitaxial monolayers; (Jun. 2009), Thèse N° 4411
Geraud Moulas: Growth and magnetism of 2D bimetallic nanostructures; (Dec. 2008), Thèse N° 4231
Philipp Buluschek: Submonolayer growth of cobalt on metallic and insulating surfaces studied by scanning tunneling microscopy and kinetic Monte-Carlo simulations; (Nov. 2007), Thèse N° 3944
Nicolas Weiss: Propriétés magnétiques de nanostructures de Co adsorbées; (Apr. 2004), Thèse N° 2980