Lecture

Gas-Particle Partitioning of Inorganic Compounds

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In course

ENV-400: Air pollution and climate change

A survey course describing the origins of air pollution and climate change ...

Description

This lecture discusses the mechanisms of gas/particle partitioning of inorganic compounds, including reactions forming condensible products. It covers examples of reactions among inorganic compounds and their condensible products, such as NH3(g) + HCl(g) = NH4Cl(s). The lecture also explores the framework of gas/particle partitioning of organic compounds, oxidation of reactive organic gases forming condensible products, and the formation of secondary organic particulate matter. It delves into the concepts of aerosol water content, photochemical production of OH, and nitrate aerosols. The lecture further examines the dynamics of mass transfer in aqueous and gas phases, conditions for phase equilibria, chemical potential as a driving force, excess Gibbs free energy, and activity coefficients in electrolyte solutions.

Instructors (2)

Satoshi Takahama

Curriculum Vitae (pdf)

Julia Schmale

Expertise atmospheric science, aerosol-cloud interactions, climate change in polar regions Mission Extreme environments are particularly sensitive to climate change and are transforming at accelerated rates. This can have important global repercussions. EERL aims to create integrated process understanding by investigating interactions between the atmosphere, cryosphere, biosphere, ocean, land and anthroposphere. The goal is to characterize climate-change relevant and vertically-resolved processes that are d

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Gibbs free energy

In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure-volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy is expressed as where p is pressure, T is the temperature, U is the internal energy, V is volume, H is the enthalpy, and S is the entropy.

Chemical potential

In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system.

Organic compound

In chemistry, many authors consider an organic compound to be any chemical compound that contains carbon-hydrogen or carbon-carbon bonds, however, some authors consider an organic compound to be any chemical compound that contains carbon. The definition of "organic" versus "inorganic" varies from author to author, and is a topic of debate. For example, methane () is considered organic, but whether some other carbon-containing compounds are organic or inorganic varies from author to author, for example halides of carbon without carbon-hydrogen and carbon-carbon bonds (e.

Thermodynamic free energy

In thermodynamics, the thermodynamic free energy is one of the state functions of a thermodynamic system (the others being internal energy, enthalpy, entropy, etc.). The change in the free energy is the maximum amount of work that the system can perform in a process at constant temperature, and its sign indicates whether the process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point.

Partition function (statistical mechanics)

In physics, a partition function describes the statistical properties of a system in thermodynamic equilibrium. Partition functions are functions of the thermodynamic state variables, such as the temperature and volume. Most of the aggregate thermodynamic variables of the system, such as the total energy, free energy, entropy, and pressure, can be expressed in terms of the partition function or its derivatives. The partition function is dimensionless.

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