Lecture

Thermal Decomposition of Solids

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In course

MSE-326: Ceramic and colloidal processing

The course covers the production of ceramics and colloids from the basic scientific concepts and theories needed to understand the forming processes to the mechanisms and methods of sintering (firing) ceramics. Including the scientific principles behind th ...

Description

This lecture covers the thermal decomposition of solids, focusing on solid reagents and various reaction methods such as solid-solid and solid-vapor reactions. It explains the importance of factors like thermodynamics and kinetics in powder synthesis. The lecture delves into the detailed mechanisms of reactions, including the structure of clays and the synthesis of materials like porcelain and silicon carbide. It also discusses the kinetics of reactions, the effects of size and mixing degree, and the limitations of solid-solid reactions. Additionally, it explores the Acheson method for synthesizing silicon carbide and the mechanisms and rates of solid-vapor reactions.

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Instructors (2)

Paul Bowen

Dr. P. Bowen after gaining his BSc in Physics at Imperial College (UK), he obtained his Ph.D. in Physical Chemistry in the field of catalysis from the University of Cambridge, UK, in 1982, He then worked at the BP Research Centre, Sunbury, UK, for 4 years in applied surface sciences before moving to Switzerland and EPFL in 1987. He has been at the Powder Technology Laboratory, in the Materials Institute since its conception in 1988. He has over 190 publications and has written an undergraduate book on ceramic synthesis and processing. Education: 1976-1979 Imperial College of Science and Technology, University of London. B.Sc. Honours in Physics. 1979-1982 Department of Physical Chemistry, University of Cambridge. Certificate of Postgraduate Studies in Chemistry. Thesis: A Mössbauer Study of Some Clay Minerals and their Surfaces. Ph.D. in Physical Chemistry. Thesis: An Iron-57 and Tin-119 Mössbauer Spectroscopic Study of Some Graphite Intercalation Compounds and Carbon Supported Iron Catalysts. Professional Experience: 1983-1986 Research Scientist (Physical Chemist), New Technology Division, British Petroleum Company plc, BP Research Centre, Sunbury on Thames, Middlesex TW16 7LN, England. 1987-1988 Engineer, Ceramics Laboratory, Département des Matériaux, Ecole Polytechnique Fédérale de Lausanne, CH - 1015 Lausanne, Switzerland. 1988-2008 Research Associate/lecturer, Powder Technology Laboratory (Present) Institute des Matériaux, Ecole Polytechnique Fédérale de Lausanne, CH - 1015 Lausanne, Switzerland. 1988- 2015 Maitre DEnsiegnement et Recherche (Lecturer & Researcher), Powder Technology Laboratory, Institute des Matériaux, Ecole Polytechnique Fédérale de Lausanne,CH - 1015 Lausanne, Switzerland 2015 – present Adjunct Professor (Professeur Titulaire), Powder Technology Laboratory (LTP), Materials Institute, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH - 1015 Lausanne, Switzerland

Andrea Testino

Expertise Ceramics synthesis and Processing; Nanomaterial synthesis; Nanomaterial characterization; Thermodynamic - Kinetic modeling; Powder synthesis scale-up. MER Dr. Andrea Testino received his master’s degree in Industrial Chemistry and PhD in Material Science from the University of Genoa (Italy). He did post-doctoral studies at EPFL (CH), University College London (UK), and University of Milan (I) working on nanoparticles synthesis and characterization. In 2007 he joined the company TDK-EPC (A) as Seni

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Related concepts (32)

Reaction mechanism

In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases. The conjectured mechanism is chosen because it is thermodynamically feasible and has experimental support in isolated intermediates (see next section) or other quantitative and qualitative characteristics of the reaction.

Silicon carbide

Silicon carbide (SiC), also known as carborundum (ˌkɑrbəˈrʌndəm), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal since 1893 for use as an abrasive. Grains of silicon carbide can be bonded together by sintering to form very hard ceramics that are widely used in applications requiring high endurance, such as car brakes, car clutches and ceramic plates in bulletproof vests.

Enzyme kinetics

Enzyme kinetics is the study of the rates of enzyme-catalysed chemical reactions. In enzyme kinetics, the reaction rate is measured and the effects of varying the conditions of the reaction are investigated. Studying an enzyme's kinetics in this way can reveal the catalytic mechanism of this enzyme, its role in metabolism, how its activity is controlled, and how a drug or a modifier (inhibitor or activator) might affect the rate. An enzyme (E) is typically a protein molecule that promotes a reaction of another molecule, its substrate (S).

Grignard reagent

A Grignard reagent or Grignard compound is a chemical compound with the general formula , where X is a halogen and R is an organic group, normally an alkyl or aryl. Two typical examples are methylmagnesium chloride and phenylmagnesium bromide . They are a subclass of the organomagnesium compounds. Grignard compounds are popular reagents in organic synthesis for creating new carbon-carbon bonds. For example, when reacted with another halogenated compound in the presence of a suitable catalyst, they typically yield and the magnesium halide as a byproduct; and the latter is insoluble in the solvents normally used.

Chemical kinetics

Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction.

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