Lecture

Visualizing NMR: Basics and Techniques

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In course

CH-401: Advanced nuclear magnetic resonance

Principles of Magnetic Resonance Imaging (MRI) and applications to medical imaging. Principles of modern multi-dimensional NMR in liquids and solids. Structure determination of proteins & materials. Measurement of molecular dynamics. Principles of Hyperpol ...

Description

This lecture covers the fundamental concepts of visualizing NMR, including spin states, precession, RF pulses, nutation, and resonance. The instructor explains how magnetization coefficients change with orientation, the precession of magnetization around the magnetic field, and the effects of RF pulses on spin. Various scenarios of resonance, both on and off, are discussed in detail.

Instructor

David Lyndon Emsley

Current Work Our research centres on the development of new NMR spectroscopy experiments to determine the atomic-level structure and dynamics of complex materials and molecular systems, to solve a range of problems across disciplines. Teaching & PhD PhD Students Ray Cowen, Ümmügülsüm Günes, Máté Visegrádi, Ruben Rodriguez Madrid Past EPFL PhD Students Dominik Józef Kubicki, Arthur César Pinon, Albert Hofstetter, Federico Maria Paruzzo, Baptiste Busi, Snaedis Björgvinsdóttir, Martins Balodis, Aditya Mishra

Official source

Related concepts (18)

Resonance

Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillating force is applied at a resonant frequency of a dynamic system, the system will oscillate at a higher amplitude than when the same force is applied at other, non-resonant frequencies. Frequencies at which the response amplitude is a relative maximum are also known as resonant frequencies or resonance frequencies of the system.

Nuclear magnetic resonance spectroscopy

Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei. This spectroscopy is based on the measurement of absorption of electromagnetic radiations in the radio frequency region from roughly 4 to 900 MHz. Absorption of radio waves in the presence of magnetic field is accompanied by a special type of nuclear transition, and for this reason, such type of spectroscopy is known as Nuclear Magnetic Resonance Spectroscopy.

Sympathetic resonance

Sympathetic resonance or sympathetic vibration is a harmonic phenomenon wherein a passive string or vibratory body responds to external vibrations to which it has a harmonic likeness. The classic example is demonstrated with two similarly-tuned tuning forks. When one fork is struck and held near the other, vibrations are induced in the unstruck fork, even though there is no physical contact between them. In similar fashion, strings will respond to the vibrations of a tuning fork when sufficient harmonic relations exist between them.

Apsidal precession

In celestial mechanics, apsidal precession (or apsidal advance) is the precession (gradual rotation) of the line connecting the apsides (line of apsides) of an astronomical body's orbit. The apsides are the orbital points farthest (apoapsis) and closest (periapsis) from its primary body (therefore it can be also called after any of the apsides). The apsidal precession is the first time derivative of the argument of periapsis, one of the six main orbital elements of an orbit.

Acoustic resonance

Acoustic resonance is a phenomenon in which an acoustic system amplifies sound waves whose frequency matches one of its own natural frequencies of vibration (its resonance frequencies). The term "acoustic resonance" is sometimes used to narrow mechanical resonance to the frequency range of human hearing, but since acoustics is defined in general terms concerning vibrational waves in matter, acoustic resonance can occur at frequencies outside the range of human hearing.

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